The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands
Open accessAbstract
The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with respect to "traditional" precious metal catalyzed transformations. The introduction of functional pincer ligands that can store protons and/or electrons as expressed by metal-ligand cooperativity and ligand redox-activity strongly stimulated this development as a conceptual starting point for rational catalyst design. This review aims at providing a comprehensive picture of the utilization of functional pincer ligands in first-row transition metal hydrogenation and dehydrogenation catalysis and related synthetic concepts relying on these such as the hydrogen borrowing methodology. Particular emphasis is put on the implementation and relevance of cooperating and redox-active pincer ligands within the mechanistic scenarios.
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Cites
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Proton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst
Boddien, A., Mellmann, D., Gärtner, F., Jackstell, R., Junge, H., Dyson, P. J., Laurenczy, G., Ludwig, R., & Beller, M. (2011) · Science · doi:10.1126/science.1206613 · Cited by 832
Ortuño, M. A., Dereli, B., Chiaie, K. R. D., Biernesser, A. B., Qi, M., Byers, J. A., & Cramer, C. J. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b02964 · Cited by 35
Metadata
- Authors
- Alig, L., Fritz, M., & Schneider, S.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-12-31
- Volume
- 119
- Issue
- 4
- Pages
- 2681-2751
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2907318745
- Cited by
- 887
- References
- 4
- FWCI
- 1.83
- Type
- journal article
- Language
- en
- Open access
- green
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