Cited by 253MXene and MAX Phase MaterialsSupercapacitor Materials and FabricationElectrocatalysts for Energy Conversion

The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.

Synthesis of Ultrathin MnO 2 Nanowire-Intercalated 2D-MXenes for High-Performance Hybrid Supercapacitors

Mahmood, Majid, Rasheed, Aamir, Ayman, Imtisal, Rasheed, Tabinda, Munir, Sana, Ajmal, Sara, Agboola, Philips O., Warsi, Muhammad Farooq, Shahid, Muhammad·2021·Energy & Fuels

DOI 10.1021/acs.energyfuels.0c03939

Open this paper in CoChat — free account

Abstract

Recently, the MXene itself and its composites with various metal oxides have shown excellent electrochemical performance due to the presence of multiple oxidation states. However, the restacking of MXene layers and poor electrical conductivity of metal oxides are major bottlenecks in their effective electrochemical transport, when they are applied individually. Herein, we report a novel manganese oxide/MXene (MnO 2 /MXene) composite material to overcome these critical issues. Sub-50 nm-thick MnO 2 nanowires (NWRs) were introduced inside the MXene to effectively stop the restacking as well as to increase the surface area of the supercapacitor (SC) electrode material. The special control on the thickness of NWRs is not only providing an opportunity to adjust them inside the MXene layers but also giving a high surface area. Electrochemical studies suggested that the MnO 2 /MXene composite behaves as an excellent electrode material for hybrid SCs, as compared to individual MXene and MnO 2 . Maximum specific capacitance ( C sp ) of MXene, MnO 2 NWRs, and MnO 2 /MXene composite was observed to be about 527.8, 337.5, and 611.5 F/g, respectively. The calculated specific capacity of the MnO 2 /MXene composite was about 489.5 C/g at 1 A/g, which shows better performance as an electrode material for energy storage devices. The synthesized electrode material demonstrated excellent capacitance retention of about 96% up to 1000 cycles.

Integrity signals

Registry

Crossref · 10.1021/acs.energyfuels.0c03939

Cites

52 of 52 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti 3 C 2 T x MXene)
Alhabeb, M., Maleski, K., Anasori, B., Lelyukh, P., Clark, L., Sin, S., & Gogotsi, Y. G. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.7b02847 · Cited by 5,128
Effect of Synthesis on Quality, Electronic Properties and Environmental Stability of Individual Monolayer Ti 3 C 2 MXene Flakes
Lipatov, A., Alhabeb, M., Lukatskaya, M. R., Boson, A., Gogotsi, Y. G., & Sinitskii, A. S. (2016) · Advanced Electronic Materials · doi:10.1002/aelm.201600255 · Cited by 1,760
Metallic Ti3C2T x MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio
Kim, S. J., Koh, H.-J., Ren, C. E., Kwon, O., Maleski, K., Cho, S.-Y., Anasori, B., Kim, C.-K., Choi, Y.-K., Kim, J., et al. (2018) · ACS Nano · doi:10.1021/acsnano.7b07460 · Cited by 1,699
High-Energy MnO 2 Nanowire/Graphene and Graphene Asymmetric Electrochemical Capacitors
Wu, Z., Ren, W., Wang, D., Li, F., Liu, B., & Cheng, H. (2010) · ACS Nano · doi:10.1021/nn101754k · Cited by 1,526
Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution
Seh, Z. W., Fredrickson, K. D., Anasori, B., Kibsgaard, J., Strickler, A. L., Lukatskaya, M. R., Gogotsi, Y., Jaramillo, T. F., & Vojvodic, A. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00247 · Cited by 1,482
Synthesis and Characterization of 2D Molybdenum Carbide (MXene)
Halim, J., Kota, S. S., Lukatskaya, M. R., Naguib, M., Zhao, M., Moon, E. J., Pitock, J., Nanda, J., May, S. J., Gogotsi, Y. G., et al. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201505328 · Cited by 1,458
Pseudocapacitive Electrodes Produced by Oxidant‐Free Polymerization of Pyrrole between the Layers of 2D Titanium Carbide (MXene)
Boota, M., Anasori, B., Voigt, C. A., Zhao, M., Barsoum, M. W., & Gogotsi, Y. G. (2015) · Advanced Materials · doi:10.1002/adma.201504705 · Cited by 1,118
All Pseudocapacitive MXene‐RuO 2 Asymmetric Supercapacitors
Jiang, Q. M., Kurra, N., Alhabeb, M., Gogotsi, Y. G., & Alshareef, H. N. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201703043 · Cited by 1,036
Effect of Postetch Annealing Gas Composition on the Structural and Electrochemical Properties of Ti2CTx MXene Electrodes for Supercapacitor Applications
Rakhi, R. B., Ahmed, B., Hedhili, M., Anjum, D., & Alshareef, H. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b01623 · Cited by 890
One-step synthesis of nanocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes
Naguib, M., Mashtalir, O., Lukatskaya, M. R., Dyatkin, B., Zhang, C. J., Presser, V., Gogotsi, Y. G., & Barsoum, M. W. (2014) · Chemical Communications · doi:10.1039/c4cc01646g · Cited by 800
Recent progress in layered transition metal carbides and/or nitrides (MXenes) and their composites: synthesis and applications
Ng, V. M. H., Huang, H., Zhou, K., Lee, P. S., Que, W., Xu, Z. J., & Kong, L. B. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta06772g · Cited by 794
Highly Flexible, Freestanding Supercapacitor Electrode with Enhanced Performance Obtained by Hybridizing Polypyrrole Chains with MXene
Zhu, M., Huang, Y., Deng, Q., Zhou, J., Pei, Z., Xue, Q., Huang, Y., Wang, Z., Li, H., Huang, Q., et al. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600969 · Cited by 732
MXene: An emerging material for sensing and biosensing
Sinha, A., Dhanjai, D., Zhao, H., Huang, Y., Lu, X., Chen, J., & Jain, R. (2018) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2018.05.021 · Cited by 730
MXene-based materials for electrochemical energy storage
Zhang, X., Zhang, Z., & Zhou, Z. (2018) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2017.08.004 · Cited by 667
Pseudocapacitive Electrodes Produced By Oxidant-Free Polymerization of Pyrrole Between the Layers of 2D Titanium Carbide (MXene)
Boota, M., Anasori, B., Voigt, C. A., Zhao, M., Barsoum, M. W., & Gogotsi, Y. G. (2016) · ECS Meeting Abstracts · doi:10.1149/ma2016-01/26/1306 · Cited by 550
Two-Dimensional Tantalum Carbide (MXenes) Composite Nanosheets for Multiple Imaging-Guided Photothermal Tumor Ablation
Dai, C., Chen, Y., Jing, X., Xiang, L., Yang, D., Lin, H., Liu, Z., Han, X., & WU, R. T. (2017) · ACS Nano · doi:10.1021/acsnano.7b07241 · Cited by 524
Recent progress in metal-organic framework-based supercapacitor electrode materials
Xu, B., Zhang, H., Mei, H., & Sun, D. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2020.213438 · Cited by 484
All-MXene-Based Integrated Electrode Constructed by Ti3C2 Nanoribbon Framework Host and Nanosheet Interlayer for High-Energy-Density Li–S Batteries
Dong, Y., Zheng, S., Qin, J., Zhao, X., Shi, H., Wang, X., Chen, J., & Wu, Z. (2018) · ACS Nano · doi:10.1021/acsnano.7b07672 · Cited by 445
Direct Chemical Synthesis of MnO 2 Nanowhiskers on Transition-Metal Carbide Surfaces for Supercapacitor Applications
Rakhi, R. B., Ahmed, B., Anjum, D. H., & Alshareef, H. N. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b04481 · Cited by 442
Controlled Hydrolysis of Metal–Organic Frameworks: Hierarchical Ni/Co-Layered Double Hydroxide Microspheres for High-Performance Supercapacitors
Xiao, Z., Mei, Y., Yuan, S., Mei, H., Xu, B., Bao, Y., Fan, L., Kang, W., Dai, F., Wang, R., et al. (2019) · ACS Nano · doi:10.1021/acsnano.9b02106 · Cited by 416
Facile preparation of in situ coated Ti 3 C 2 T x /Ni 0.5 Zn 0.5 Fe 2 O 4 composites and their electromagnetic performance
Li, Y., Zhou, X., Wang, J., Deng, Q., Li, M., Du, S., Han, Y., Lee, J., & Huang, Q. (2017) · RSC Advances · doi:10.1039/c7ra03402d · Cited by 383
MXene‐Based Composites: Synthesis and Applications in Rechargeable Batteries and Supercapacitors
Yang, J. H., Bao, W., Jaumaux, P., Zhang, S., Wang, C., & Wang, G. (2019) · Advanced Materials Interfaces · doi:10.1002/admi.201802004 · Cited by 334
Three-dimensional porous MXene/layered double hydroxide composite for high performance supercapacitors
Wang, Y., Dou, H., Wang, J., Ding, B., Xu, Y., Chang, Z., & Hao, X. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2016.07.062 · Cited by 333
Metal−organic frameworks-derived MnO2/Mn3O4 microcuboids with hierarchically ordered nanosheets and Ti3C2 MXene/Au NPs composites for electrochemical pesticide detection
Song, D., Jiang, X., Li, Y., Lu, X., Luan, S., Wang, Y., Li, Y., & Gao, F. (2019) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2019.03.083 · Cited by 333
Ti 3 C 2 MXene: a promising microwave absorbing material
Feng, W., Luo, H., Wang, Y., Zeng, S., Deng, L., Zhou, X., Zhang, H., & Peng, S. (2018) · RSC Advances · doi:10.1039/c7ra12616f · Cited by 295
Solid–liquid reaction synthesis of layered machinable Ti3AlC2 ceramic
Wang, X., & Zhou, Y. (2002) · Journal of Materials Chemistry · doi:10.1039/b108685e · Cited by 267
Recent Advances in 2D-MoS 2 and its Composite Nanostructures for Supercapacitor Electrode Application
Joseph, N., Shafi, P. M., & Bose, A. C. (2020) · Energy & Fuels · doi:10.1021/acs.energyfuels.0c00430 · Cited by 257
A novel MnO2/Ti3C2Tx MXene nanocomposite as high performance electrode materials for flexible supercapacitors
Jiang, H., Wang, Z., Yang, Q., Hanif, M., Wang, Z., Dong, L., & Dong, M. (2018) · Electrochimica Acta · doi:10.1016/j.electacta.2018.08.096 · Cited by 219
Titanium carbide (Ti3C2Tx) MXene: A novel precursor to amphiphilic carbide-derived graphene quantum dots for fluorescent ink, light-emitting composite and bioimaging
Zhou, L., Wu, F., Yu, J., Deng, Q., Zhang, F., & Wang, G. (2017) · Carbon · doi:10.1016/j.carbon.2017.03.023 · Cited by 207
Enhanced electrochemical energy storage properties of carbon coated Co3O4 nanoparticles-reduced graphene oxide ternary nano-hybrids
Aadil, M., Zulfiqar, S., Sabeeh, H., Warsi, M. F., Shahid, M., Alsafari, I. A., & Shakir, I. (2020) · Ceramics International · doi:10.1016/j.ceramint.2020.04.090 · Cited by 186
Self-citation
MnO2 nanorods/MXene/CC composite electrode for flexible supercapacitors with enhanced electrochemical performance
Zhou, H., Lu, Y., Wu, F., Fang, L., Luo, H., Zhang, Y., & Zhou, M. (2019) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2019.06.173 · Cited by 170
CoFe2O4 Nanoparticle-Decorated 2D MXene: A Novel Hybrid Material for Supercapacitor Applications
Ayman, I., Rasheed, A., Ajmal, S., Rehman, A., Ali, A., Shakir, I., & Warsi, M. (2020) · Energy & Fuels · doi:10.1021/acs.energyfuels.0c00959 · Cited by 169
Self-citation
Two-dimensional transition metal carbide (Ti 3 C 2 T x ) as an efficient adsorbent to remove cesium (Cs + )
Khan, A. R., Husnain, S. M., Shahzad, F., Hassan, S. M. U., Mehmood, M., Ahmad, J., Mehran, M. T., & Rahman, S. (2019) · Dalton Transactions · doi:10.1039/c9dt01965k · Cited by 161
Ti3C2Tx (MXene)–polyacrylamide nanocomposite films
Naguib, M., Saito, T., Lai, S., Rager, M. S., Aytug, T., Paranthaman, M., Zhao, M.-Q., & Gogotsi, Y. (2016) · RSC Advances · doi:10.1039/c6ra10384g · Cited by 160
Enhanced supercapacitive performance of manganese oxides doped two-dimensional titanium carbide nanocomposite in alkaline electrolyte
Tang, Y., Zhu, J., Yang, C., & Wang, F. (2016) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2016.05.221 · Cited by 155
Study on the magnetic properties of differently functionalized multilayered Ti3C2Tx MXenes and Ti-Al-C carbides
Scheibe, B., Tadyszak, K., Jarek, M., Michalak, N., Kempiǹski, M., Lewandowski, M., Peplińska, B., & Chybczyńska, K. (2019) · Applied Surface Science · doi:10.1016/j.apsusc.2019.02.055 · Cited by 134
Manganese oxide-based heterogeneous electrocatalysts for water oxidation
Park, S., Lee, Y. H., Choi, S., Seo, H., Lee, M. Y., Balamurugan, M., & Nam, K. T. (2020) · Energy & Environmental Science · doi:10.1039/d0ee00815j · Cited by 134
A novel MnO 2 /MXene composite prepared by electrostatic self-assembly and its use as an electrode for enhanced supercapacitive performance
Chen, S., Xiang, Y., Xu, W., & Peng, C. (2018) · Inorganic Chemistry Frontiers · doi:10.1039/c8qi00957k · Cited by 113
Transport properties of a highly conductive 2D Ti3C2Tx MXene/graphene composite
Aïssa, B., Ali, A., Mahmoud, K. A., Haddad, T., & Nedil, M. (2016) · Applied Physics Letters · doi:10.1063/1.4960155 · Cited by 112
Facile synthesis of α-MnO2 nanorods for high-performance alkaline batteries
Tang, N., Tian, X., Yang, C., Pi, Z., & Han, Q. (2010) · Journal of Physics and Chemistry of Solids · doi:10.1016/j.jpcs.2009.11.016 · Cited by 102
NiSe2/Ni(OH)2 Heterojunction Composite through Epitaxial-like Strategy as High-Rate Battery-Type Electrode Material
Mei, H., Huang, Z., Xu, B., Xiao, Z., Mei, Y., Zhang, H., Zhang, S., Li, D., Kang, W., & Sun, D. F. (2020) · Nano-Micro Letters · doi:10.1007/s40820-020-0392-8 · Cited by 97
Binder-Free Two-Dimensional MXene/Acid Activated Carbon for High-Performance Supercapacitors and Methylene Blue Adsorption
Li, Y., Pan, C., Kamdem, P. D., & Jin, X. (2020) · Energy & Fuels · doi:10.1021/acs.energyfuels.0c01352 · Cited by 97
Textural and capacitive characteristics of MnO2 nanocrystals derived from a novel solid-reaction route
Yuan, A., Wang, X., Wang, Y., & Hu, J. (2009) · Electrochimica Acta · doi:10.1016/j.electacta.2008.08.057 · Cited by 97
Flexible Supercapacitor-Type Rectifier-free Self-Charging Power Unit Based on a Multifunctional Polyvinylidene Fluoride–ZnO–rGO Piezoelectric Matrix
Rasheed, A., He, W. T., Qian, Y., Park, H., & Kang, D. J. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b22362 · Cited by 88
Self-citation
Synthesis of MnO 2 nanoparticles and their effective utilization as UV protectors for outdoor high voltage polymeric insulators used in power transmission lines
Ghosh, D., Bhandari, S., & Khastgir, D. K. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp06611a · Cited by 73
3D NiO nanowires@NiO nanosheets core-shell structures grown on nickel foam for high performance supercapacitor electrode
Ali, A., Ammar, M., Mukhtar, A., Ahmed, T., Ali, M., Waqas, M., Amin, M. N., & Rasheed, A. (2019) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2019.113710 · Cited by 68
Self-citation
Electrochemically grown MnO 2 nanowires for supercapacitor and electrocatalysis applications
Raut, S. D., Mane, H. R., Shinde, N. M., Lee, D., Shaikh, S. F., Kim, K. H., Kim, H., Al‐Enizi, A. M., & Mane, R. S. (2020) · New Journal of Chemistry · doi:10.1039/d0nj03792c · Cited by 54
Morphology-controlled MnO 2 –graphene oxide–diatomaceous earth 3-dimensional (3D) composites for high-performance supercapacitors
Wen, Z. Q., Li, M., Li, F., Zhu, S., Liu, X., Zhang, Y., Kumeria, T., Lošić, D., Gao, Y., Zhang, W., et al. (2015) · Dalton Transactions · doi:10.1039/c5dt04082e · Cited by 49
Spinel ferrite magnetic nanostructures at the surface of graphene sheets for visible light photocatalysis applications
Mahmood, M. F., Yousuf, M., Baig, M. M., Imran, M., Suleman, M., Shahid, M., Khan, M. A., & Warsi, M. F. (2018) · Physica B Condensed Matter · doi:10.1016/j.physb.2018.08.043 · Cited by 49
Self-citation
Facile synthesis of MXene/MnO2 composite with high specific capacitance
Wang, Q., Zhang, Z., Zhang, Z., Zhou, X., & Ma, G. (2018) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-018-4143-4 · Cited by 47
Structural units distribution, phase separation and properties of PbO–TiO2–B2O3 glasses
Doweidar, H., El-Egili, K., Ramadan, R., & Al-Zaibani, M. (2017) · Journal of Non-Crystalline Solids · doi:10.1016/j.jnoncrysol.2017.03.040 · Cited by 43
Synthesis of Solid Acid Catalysts Based on TiO2- SO42-and Pt/TiO2- SO42- Applied in n-Hexane Isomerization
Enríquez, J. M. H., Lajas, L. A. C., García-Alamilla, R., Martín, E. Á. S., García, P. Á., Handy, B. E., Cárdenas‐Galindo, M., & Serrano, L. A. G. (2013) · Open Journal of Metal · doi:10.4236/ojmetal.2013.33006 · Cited by 23

Sorted by citations

The Many Deaths of Supercapacitors: Degradation, Aging, and Performance Fading
Pameté, E., Köps, L., Kreth, F. A., Pohlmann, S., Varzi, A., Brousse, T., Balducci, A., & Presser, V. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202301008 · Cited by 342
MXene-Based Electrodes for Supercapacitor Energy Storage
Chen, Y., Yang, H., Han, Z., Bo, Z., Yan, J., Cen, K., & Ostrikov, K. (2022) · Energy & Fuels · doi:10.1021/acs.energyfuels.1c04104 · Cited by 245
2D MXene‐Based Biosensing: A Review
Amara, U., Hussain, I., Ahmad, M., Mahmood, K., & Zhang, K. (2022) · Small · doi:10.1002/smll.202205249 · Cited by 217
Nanoarchitectured transition metal oxides and their composites for supercapacitors
Kumar, A., Rathore, H. K., Sarkar, D., & Shukla, A. K. (2021) · Electrochemical Science Advances · doi:10.1002/elsa.202100187 · Cited by 186
Recent progress in the design of advanced MXene/metal oxides-hybrid materials for energy storage devices
Javed, M. S., Mateen, A., Hussain, I., Ahmad, A., Mubashir, M., Khan, S., Assiri, M. A., Eldin, S. M., Shah, S. S. A., & Han, W. (2022) · Energy storage materials · doi:10.1016/j.ensm.2022.10.005 · Cited by 161

See all 253

Authors: Mahmood, M., Rasheed, A., Ayman, I., Rasheed, T., Munir, S., Ajmal, S., Agboola, P. O., Warsi, M. F., & Shahid, M.
Affiliations: Islamia University of Bahawalpur (PK)
King Saud University (SA)
University of Hafr Al-Batin (SA)
Corresponding author: Warsi, Muhammad Farooq
Shahid, Muhammad
ORCID: Mahmood, Majid
Rasheed, Aamir
Munir, Sana
Ajmal, Sara
Agboola, Philips O.
Warsi, Muhammad Farooq
Shahid, Muhammad
Venue: Energy & Fuels
Publisher: American Chemical Society (ACS)
Published: 2021-01-26
Volume: 35
Issue: 4
Pages: 3469-3478
ISSN: 0887-0624 (ISSN-L)
1520-5029
DOI: 10.1021/acs.energyfuels.0c03939
OpenAlex: W3122549511
Cited by: 253
References: 52
Citations by year: 2026: 40 · 2025: 50 · 2024: 83 · 2023: 45 · 2022: 25 · 2021: 10
FWCI: 12.38
Type: journal article
Language: en
Open access: closed
Licence: doi.org/10.15223/policy-029 (stm-asf)
doi.org/10.15223/policy-037 (stm-asf)
doi.org/10.15223/policy-045 (stm-asf)
Locations: Energy & Fuels (publishedVersion)
Funders: Higher Education Commision, Pakistan (6276/Punjab/NRPU/R&D/HEC)
King Saud University (RSP 2020/163)
Topics: Physical Sciences › Materials Science › Materials Chemistry › MXene and MAX Phase Materials
Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Keywords: MXene, MnO2 nanowires, hybrid supercapacitors, specific capacitance, cycling stability, electrode materials, energy storage, ultrathin nanowires

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Synthesis of Ultrathin MnO 2 Nanowire-Intercalated 2D-MXenes for High-Performance Hybrid Supercapacitors

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cites

Cited by

Related

Metadata

Record

About these checks