The DOI matches its Crossref record; 300 of the 300 references it cites were found in a registry or an index.
An Overview of Low-Temperature Fischer–Tropsch Synthesis: Market Conditions, Raw Materials, Reactors, Scale-Up, Process Intensification, Mechanisms, and Outlook
Abstract
The Fischer–Tropsch technology has allowed, since its emergence a century ago, the production of stable liquid fuels from different raw materials in different geographic scenarios that do not necessarily have oil reserves. Some of these raw materials can generate high-quality fuels with a lower content of sulfur, aromatic, and heterocyclic compounds. The scaling and intensification of the reactors are essential factors in this context, and important challenges such as energy transfer due to the highly exothermic reaction, hydrodynamics due to limited information on pilot-scale in a reasonable range of conditions, or reducing CH 4 selectivity while maintaining high conversion through catalyst design, must be considered. This perspective provides an overview of recent developments in industrial-scale low-temperature Fischer–Tropsch reactors, with a focus on the significance of microchannel reactors in the scale-up process. The advancement in the Fischer–Tropsch synthesis is discussed, with an emphasis on the carbide and CO insertion mechanisms, as well as the socio-political-economic factors that continue to impact the development of this technology.
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“For instance, the F-T synthesis converts syngas (a mixture of H 2 and CO, often derived from CO 2 via the reverse water-gas shift reaction) into liquid hydrocarbons using metal catalysts, typically iron (Fe) or cobalt (Co), at elevated temperatures (e.g., 200-350 • C) and pressures (e.g., 10-30 atm) [282][283][284].”
From Biofuels, E-Fuels, and Waste-Derived Fuels: Advances, Challenges, and Future Directions (2025) · cites this paper as [284]
In the citing paper
“Fe-and Co-based catalysts are favored for these procedures given their established activity, selectivity, and cost-effectiveness [282,284].”
From Biofuels, E-Fuels, and Waste-Derived Fuels: Advances, Challenges, and Future Directions (2025) · cites this paper as [284]
Citations
Cites
Handbook of Heterogeneous Catalysis
(1997) · Wiley eBooks · doi:10.1002/9783527619474 · Cited by 2,418
Khodakov, A. Y., Chu, W., & Fongarland, P. (2007) · Chemical Reviews · doi:10.1021/cr050972v · Cited by 2,377
The Fischer-Tropsch process: 1950-2000
Dry, M. E. (2002) · Catalysis Today · doi:10.1016/s0920-5861(01)00453-9 · Cited by 2,061
Oxidations carried out by means of vanadium oxide catalysts
Mars, P. H., & Krevelen, D. W. V. (1954) · Chemical Engineering Science · doi:10.1016/s0009-2509(54)80005-4 · Cited by 2,031
An overview of second generation biofuel technologies
Sims, R. E. H., Mabee, W., Saddler, J. N., & Taylor, M. (2010) · Bioresource Technology · doi:10.1016/j.biortech.2009.11.046 · Cited by 1,497
Flow of gases through porous media
Eisenklam, P. (1957) · Combustion and Flame · doi:10.1016/0010-2180(57)90038-x · Cited by 1,369
Kinetics and Selectivity of the Fischer–Tropsch Synthesis: A Literature Review
LAAN, G. P. V. D., & Beenackers, A. A. C. M. (1999) · Catalysis Reviews · doi:10.1081/cr-100101170 · Cited by 1,313
Chemistry in Microstructured Reactors
Jähnisch, K., Hessel, V., Löwe, H., & Baerns, M. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200300577 · Cited by 1,288
Molecular Size Distribution in Linear Condensation Polymers 1
Flory, P. J. (1936) · Journal of the American Chemical Society · doi:10.1021/ja01301a016 · Cited by 1,010
Dry reforming of methane: Influence of process parameters—A review
Usman, M., Daud, W. M. A. W., & Abbas, H. F. (2015) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2015.02.026 · Cited by 960
Research works printed but not linked: 20
- Hakes J., 2008, Journal of Energy Security, 35
- Bordoff J., 2015, Horizons: Journal of international relations and sustainable development, 190
- Suppes G. J., 2015, Sustainable Power Technologies and Infrastructure: Energy Sustainability and Prosperity in a Time of Climate Change
- OPEC, 2021, World oil outlook
- Mokhatab S., 2018, Handbook of natural gas transmission and processing: principles and practices
- 2021, BP, BP statistical review of world energy
- Thackeray F., 2002, Petroleum Economist, 69, 10
- Van Dyk, J.; Keyser, M.; Van Zyl, J. Suitability of feedstocks for the Sasol-Lurgi fixed bed dry bottom gasification process. Gasification Technologies Conference ; Gasification Technologies Council: Arlington, VA, Paper; 2001; p 10-8.
- 10.1016/j.coal.2005.05.007 · DOI
- Wirth K., 2010, VDI Heat Atlas, 1106
- Ergun S., 1952, Chem. Eng. Prog., 48, 89
- Kozeny J., 1927, Sitzungsber Akad. Wiss., Wien, 136, 271
- Carman P. C., 1938, J. Soc. Chemical Industries, 57, 225
- Darcy H., 1856, Les fontaines publiques de la ville de Dijon: exposition et application···par Henry Darcy
- Eigenberger G., 1992, Fixed bed reactors
- LeViness S., 2011, Velocys, 1
- Anderson R. B., 1956, Catalysis, 4, 29
- Herington E. F., 1946, Chemical Industry (London)
- Fischer F., 1926, Brennstoff-Chemie, 7, 97
- Pichler H., 1970, Chem. Ing. Tech, 12, 1160
Cited by
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Heterogeneous catalysis for the environment
Liu, J., Burciaga, R., Tang, S., Ding, S., Ran, H., Zhao, W. J., Wang, G., Zhuang, Z., Xie, L., Lyu, Z., et al. (2024) · The Innovation Materials · doi:10.59717/j.xinn-mater.2024.100090 · Cited by 102
Evans, M. J., & Jones, C. (2024) · Chemical Society Reviews · doi:10.1039/d4cs00097h · Cited by 56
A century of evolution: Progress and milestones in fischer-tropsch synthesis
Yohannes, A. G., & Gates, I. D. (2025) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2025.217096 · Cited by 53
Biofuels, E-Fuels, and Waste-Derived Fuels: Advances, Challenges, and Future Directions
Yılbaşı, Z. (2025) · Sustainability · doi:10.3390/su17136145 · Cited by 41
CO 2 conversion to CO by reverse water gas shift and dry reforming using chemical looping
Kang, K., Sampei, H., & Sekine, Y. (2025) · RSC Sustainability · doi:10.1039/d4su00395k · Cited by 27
Metadata
- Authors
- Apolinar-Hernández, J. E., Bertoli, S. L., Riella, H. G., Soares, C., & Padoin, N.
- Affiliations
- Universidade Federal de Santa Catarina (BR)
- Universidade Regional de Blumenau (BR)
- Corresponding author
- Soares, Cíntia
- Padoin, Natan
- ORCID
- Venue
- Energy & Fuels
- Publisher
- American Chemical Society (ACS)
- Published
- 2023-12-18
- Volume
- 38
- Issue
- 1
- Pages
- 1-28
- ISSN
- 0887-0624 (ISSN-L)
- 1520-5029
- OpenAlex
- W4389869983
- Cited by
- 46
- References
- 300
- Citations by year
- 2026: 15 · 2025: 21 · 2024: 10
- FWCI
- 2.16
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- Energy & Fuels (publishedVersion)
- Funders
- Universidade Federal de Santa Catarina
- Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico (312247/2022-2, 102072/2022-1, 313202/2021-4)
- Ag?ncia Nacional do Petr?leo, G?s Natural e Biocombust?veis
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
- Physical Sciences › Energy › Fuel Technology › Mining and Gasification Technologies
- Keywords
- liquid fuels, microreactors, reactor scale-up, process intensification, methane selectivity, catalyst design, hydrodynamics, raw materials, market conditions
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