The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.
Cobalt/Peracetic Acid: Advanced Oxidation of Aromatic Organic Compounds by Acetylperoxyl Radicals
Abstract
Peracetic acid (PAA) is increasingly used as an alternative disinfectant and its advanced oxidation processes (AOPs) could be useful for pollutant degradation. Co(II) or Co(III) can activate PAA to produce acetyloxyl (CH 3 C(O)O • ) and acetylperoxyl (CH 3 C(O)OO • ) radicals with little • OH radical formation, and Co(II)/Co(III) is cycled. For the first time, this study determined the reaction rates of PAA with Co(II) ( k PAA,Co(II) = 1.70 × 10 1 to 6.67 × 10 2 M –1 ·s –1 ) and Co(III) ( k PAA,Co(III) = 3.91 × 10 0 to 4.57 × 10 2 M –1 ·s –1 ) ions over the initial pH 3.0–8.2 and evaluated 30 different aromatic organic compounds for degradation by Co/PAA. In-depth investigation confirmed that CH 3 C(O)OO • is the key reactive species under Co/PAA for compound degradation. Assessing the structure–activity relationship between compounds’ molecular descriptors and pseudo-first-order degradation rate constants ( k ′ PAA • in s –1 ) by Co/PAA showed the number of ring atoms, E HOMO, softness, and ionization potential to be the most influential, strongly suggesting the electron transfer mechanism from aromatic compounds to the acetylperoxyl radical. The radical production and compound degradation in Co/PAA are most efficient in the intermediate pH range and can be influenced by water matrix constituents of bicarbonate, phosphate, and humic acids. These results significantly improve the knowledge regarding the acetylperoxyl radical from PAA and will be useful for further development and applications of PAA-based AOPs.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555805 · Cited by 12,332
Radical Generation by the Interaction of Transition Metals with Common Oxidants
Anipsitakis, G. P., & Dionysiou, D. D. (2004) · Environmental Science & Technology · doi:10.1021/es035121o · Cited by 3,098
Hu, P., & Long, M. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2015.07.024 · Cited by 2,184
Reactivity of HO2/O− 2 radicals in aqueous solution
Bielski, B. H. J., Cabelli, D. E., Arudi, R. L., & Ross, A. B. (1985) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555739 · Cited by 2,169
Anipsitakis, G. P., Dionysiou, D. D., & Gonzalez, M. A. (2006) · Environmental Science & Technology · doi:10.1021/es050634b · Cited by 910
Rate constants and mechanism of reaction of sulfate radical anion with aromatic compounds
Neta, P., Madhavan, V., Zemel, H., & Fessenden, R. W. (1977) · Journal of the American Chemical Society · doi:10.1021/ja00443a030 · Cited by 896
Disinfection of wastewater with peracetic acid: a review
Kitis, M. (2004) · Environment International · doi:10.1016/s0160-4120(03)00147-8 · Cited by 846
Advanced Oxidation Process with Peracetic Acid and Fe(II) for Contaminant Degradation
Kim, J., Zhang, T., Liu, W., Du, P., Dobson, J. T., & Huang, C.-H. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.9b02991 · Cited by 590
Self-citationWang, Z., Wang, J., Xiong, B., Bai, F., Wang, S., Wan, Y., Zhang, L., Xie, P., & Wiesner, M. R. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.9b04528 · Cited by 578
UV/Peracetic Acid for Degradation of Pharmaceuticals and Reactive Species Evaluation
Cai, M., Sun, P., Zhang, L., & Huang, C.-H. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.7b04694 · Cited by 506
Self-citationFang, G.-D., Dionysiou, D. D., Wang, Y., Al-Abed, S. R., & Zhou, D.-M. (2012) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2012.05.074 · Cited by 448
Ingold, K. U. (1969) · Accounts of Chemical Research · doi:10.1021/ar50013a001 · Cited by 436
Gramatica, P., & Sangion, A. (2016) · Journal of Chemical Information and Modeling · doi:10.1021/acs.jcim.6b00088 · Cited by 420
Luo, S., Wei, Z., Dionysiou, D. D., Spinney, R., Hu, W.-P., Chai, L., Yang, Z., Ye, T., & Xiao, R. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.06.179 · Cited by 418
Rate Constants for Reactions of Peroxyl Radicals in Fluid Solutions
Neta, P., Huie, R. E., & Ross, A. B. (1990) · Journal of Physical and Chemical Reference Data · doi:10.1063/1.555854 · Cited by 414
Chen, S., Cai, M., Liu, Y., Zhang, L., & Feng, L. (2019) · Water Research · doi:10.1016/j.watres.2018.11.044 · Cited by 406
Lee, Y., & von Gunten, U. (2012) · Water Research · doi:10.1016/j.watres.2012.06.006 · Cited by 397
Peracids in water treatment: A critical review
Luukkonen, T., & Pehkonen, S. O. (2017) · Critical Reviews in Environmental Science and Technology · doi:10.1080/10643389.2016.1272343 · Cited by 374
Xiao, R., Ye, T., Wei, Z., Luo, S., Yang, Z., & Spinney, R. (2015) · Environmental Science & Technology · doi:10.1021/acs.est.5b03078 · Cited by 321
Oxidative degradation of dyes in water using Co2+/H2O2 and Co2+/peroxymonosulfate
Ling, S. K., Wang, S., & Peng, Y. (2010) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2010.01.091 · Cited by 305
Minakata, D., Li, K., Westerhoff, P., & Crittenden, J. (2009) · Environmental Science & Technology · doi:10.1021/es900956c · Cited by 264
Zhou, F., Lu, C., Yao, Y., Sun, L., Gong, F., Li, D., Pei, K., Lu, W., & Chen, W. (2015) · Chemical Engineering Journal · doi:10.1016/j.cej.2015.07.034 · Cited by 199
Grosjean, D., & Williams, E. L. (1992) · Atmospheric Environment Part A General Topics · doi:10.1016/0960-1686(92)90124-4 · Cited by 172
Domínguez Henao, L., Turolla, A., & Antonelli, M. (2018) · Chemosphere · doi:10.1016/j.chemosphere.2018.09.005 · Cited by 172
Rokhina, E. V., Makarova, K., Golovina, E. A., Van As, H., & Virkutyte, J. (2010) · Environmental Science & Technology · doi:10.1021/es1009136 · Cited by 164
Wastewater disinfection with PAA and UV combined treatment: a pilot plant study
Caretti, C., & Lubello, C. (2003) · Water Research · doi:10.1016/s0043-1354(03)00025-3 · Cited by 162
Luo, S., Wei, Z., Spinney, R., Villamena, F. A., Dionysiou, D. D., Chen, D., Tang, C., Chai, L., & Xiao, R. (2017) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2017.09.024 · Cited by 158
Disinfection by-products formation during wastewater disinfection with peracetic acid
Dell’Erba, A., Falsanisi, D., Liberti, L., Notarnicola, M., & Santoro, D. (2007) · Desalination · doi:10.1016/j.desal.2006.08.021 · Cited by 155
Rizzo, L., Agovino, T., Nahim–Granados, S., Castro-Alférez, M., Fernández‐Ibañez, P., & Polo-López, M. I. (2018) · Water Research · doi:10.1016/j.watres.2018.11.031 · Cited by 151
Sudhakaran, S., & Amy, G. L. (2012) · Water Research · doi:10.1016/j.watres.2012.11.033 · Cited by 140
Schuchmann, M. N., & von Sonntag, C. (1988) · Journal of the American Chemical Society · doi:10.1021/ja00225a019 · Cited by 138
Bandala, E. R., Peláez, M. A., Dionysiou, D. D., et al. (2006) · Journal of Photochemistry and Photobiology A Chemistry · doi:10.1016/j.jphotochem.2006.09.005 · Cited by 135
One- and two-electron reduction potentials of peroxyl radicals and related species
Merényi, G., Lind, J. U., & Engman, L. (1994) · Journal of the Chemical Society Perkin Transactions 2 · doi:10.1039/p29940002551 · Cited by 108
Lee, W.-N., & Huang, C.-H. (2018) · Food Chemistry X · doi:10.1016/j.fochx.2018.100003 · Cited by 104
Self-citationYe, T., Wei, Z., Spinney, R., Dionysiou, D. D., Luo, S., Chai, L., Yang, Z., & Xiao, R. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.02.061 · Cited by 93
Rothbart, S., Ember, E., & van Eldik, R. (2011) · New Journal of Chemistry · doi:10.1039/c2nj20852k · Cited by 92
3D QSPR models for the removal of trace organic contaminants by ozone and free chlorine
Lei, H., & Snyder, S. A. (2007) · Water Research · doi:10.1016/j.watres.2007.05.010 · Cited by 91
Kamath, D., Mezyk, S. P., & Minakata, D. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b00582 · Cited by 89
Öberg, T. (2005) · Atmospheric Environment · doi:10.1016/j.atmosenv.2005.01.007 · Cited by 82
El‐Agamey, A., & McGarvey, D. J. (2003) · Journal of the American Chemical Society · doi:10.1021/ja027986s · Cited by 80
Intermediate free radicals in the oxidation of wastewaters
Bianchini, R., Calucci, L., Lubello, C., & Pinzino, C. (2002) · Research on Chemical Intermediates · doi:10.1163/156856702320267154 · Cited by 75
Peracetic Acid in Disinfection of Fruits and Vegetables
Zoellner, C., Aguayo-Acosta, A., Siddiqui, M. W., & Dávila-Aviña, J. (2018) · Elsevier eBooks · doi:10.1016/b978-0-12-812698-1.00002-9 · Cited by 71
Postharvest control of Monilinia laxa and Rhizopus stolonifer in stone fruit by peracetic acid
Mari, M., Grégori, R., & Donati, I. (2004) · Postharvest Biology and Technology · doi:10.1016/j.postharvbio.2004.02.011 · Cited by 70
Yao, Y., Xie, Y., Zhao, B., Zhou, L., Shi, Y., Wang, Y., Sheng, Y., Zhao, H., Sun, J., & Cao, H. (2019) · Chemical Engineering Journal · doi:10.1016/j.cej.2019.122708 · Cited by 69
Self-citationLi, X., Zhao, W., Li, J., et al. (2013) · Chemosphere · doi:10.1016/j.chemosphere.2013.03.040 · Cited by 56
Mortensen, A. (2001) · Journal of Photochemistry and Photobiology B Biology · doi:10.1016/s1011-1344(01)00146-4 · Cited by 40
Kampf, G. (2018) · Springer eBooks · doi:10.1007/978-3-319-98785-9_5 · Cited by 4
Metadata
- Authors
- Kim, J., Du, P., Liu, W., Luo, C., Zhao, H., & Huang, C.-H.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-03-18
- Volume
- 54
- Issue
- 8
- Pages
- 5268-5278
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W3011365398
- Cited by
- 452
- References
- 47
- FWCI
- 13.40
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
