Dinucleating Amino-Phenolate Platform for Zinc Catalysts: Impact on Lactide Polymerization

We report imine- and amine-based dinucleating ligands bearing a bisphenol backbone and explore their coordination chemistry with zinc to form zinc alkyl, alkoxide, acetate, and amide complexes. Full characterization of the complexes shows that this ligand framework can support dinuclear and trinu…