The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
A Robust Luminescent Tb(III)-MOF with Lewis Basic Pyridyl Sites for the Highly Sensitive Detection of Metal Ions and Small Molecules
Abstract
A new luminescent terbium-metal-organic framework [Tb3(L)2(HCOO)(H2O)5]·DMF·4H2O (1) (H4L = 4,4'-(pyridine-3,5-diyl)diisophthalic acid) has been successfully assembled by Tb(3+) ions and an undeveloped pyridyl-tetracarboxylate. Compound 1 exhibits a 3D porous (3,8)-connected (4.5(2))2(4(2).5(12).6(6).7(5).8(3)) topological framework with fascinating 1D open hydrophilic channels decorated by uncoordinated Lewis basic pyridyl nitrogen atoms. In particular, the Tb-MOF (1) can detect Cu(2+) ions with high selectivity and sensitivity, and its luminescence is nearly entirely quenched in N,N-dimethylformamide (DMF) solution and biological system. In addition, 1 still has high detection for the trace content of nitromethane with 70 ppm, which suggests that 1 is a promising example of dual functional materials with sensing copper ions and nitromethane.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Metalloproteins and metal sensing
Waldron, K. J., Rutherford, J. C., Ford, D., & Robinson, N. J. (2009) · Nature · doi:10.1038/nature08300 · Cited by 1,269
Cited by
Luminescent sensors based on metal-organic frameworks
Zhang, Y., Yuan, S., Day, G., Wang, X., Yang, X., & Zhou, H.-C. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.06.007 · Cited by 1,255
Recent progress in metal-organic frameworks-based hydrogels and aerogels and their applications
Wang, L., Xu, H., Gao, J., Yao, J., & Zhang, Q. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213016 · Cited by 594
Self-citationLiu, W., Dai, X., Bai, Z., Wang, Y., Yang, Z., Zhang, L., Xu, L., Chen, L., Li, Y., Gui, D., et al. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.6b06305 · Cited by 420
Self-citationLuminescent rare-earth-based MOFs as optical sensors
Mahata, P., Mondal, S. K., Singha, D. K., & Majee, P. (2017) · Dalton Transactions · doi:10.1039/c6dt03419e · Cited by 292
Metadata
- Authors
- Zhao, J., Wang, Y.-N., Dong, W.-W., Wu, Y.-P., Li, D.-S., & Zhang, Q.-C.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-03-11
- Volume
- 55
- Issue
- 7
- Pages
- 3265-3271
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2296376547
- Cited by
- 564
- References
- 1
- FWCI
- 35.30
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: A Robust Luminescent Tb(III)-MOF with Lewis Basic Pyridyl Sites for the Highly Sensitive Detection of Metal Ions and Small Molecules. https://app.cochat.ai/papers/10.1021/acs.inorgchem.5b02294
- The paper
- Zhao, J., Wang, Y.-N., Dong, W.-W., Wu, Y.-P., Li, D.-S., & Zhang, Q.-C. (2016). A Robust Luminescent Tb(III)-MOF with Lewis Basic Pyridyl Sites for the Highly Sensitive Detection of Metal Ions and Small Molecules. Inorganic Chemistry. https://doi.org/10.1021/acs.inorgchem.5b02294
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
