The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Series d–f Heteronuclear Metal–Organic Frameworks: Color Tunability and Luminescent Probe with Switchable Properties
Abstract
A series of five unique d–f heteronuclear luminescent metal–organic frameworks (MOFs) in an entangled polyrotaxane array and the light-harvesting block homonuclear zinc compound have been isolated successfully and characterized. The series of isostructural polymers feature 3,4-connected (4.8 2 )(4.8 3 .9 2 )(6.8.9) 2 (6.9 2 )(8 3 ) topology and high stability, exhibiting diverse void spaces. By taking advantage of the isostructural MOFs 2 and 3, the intensities of red and green emissions can be modulated by adjusting the ratios of Eu III and Tb III ions correspondingly, and white-light emission can be generated by a combination of different doped Tb III and Eu III concentrations. The Tb–Zn-based framework {[Tb 3 Zn 6 (bipy 2 ) 2 (Hmimda) 7 (H 2 O) 3 ]·5H 2 O} n ( 3; H 3 mimda = 2-methyl-1- H -imidazole-4,5-dicarboxylic acid and bipy = 4,4′-bipyridine) can detect trace Mg II ion with relatively high sensitivity and selectivity. Dehydrated MOF 3a shows a remarkable emission quenching effect through the introduction of I 2 solids. Further investigation indicates that it exhibits turn on/off switchable properties for small solvent molecules or heavy-metal ions. Steady/transient-state near-IR luminescence properties for MOFs 1, 4, and 5 were investigated under visible-light excitation.
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Cites
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Cited by
Liu, J.-Q., Luo, Z.-D., Pan, Y., Kumar Singh, A., Trivedi, M., & Kumar, A. (2020) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213145 · Cited by 508
Current status and prospects of metal-organic frameworks for bone therapy and bone repair
Li, M., Yin, S., Lin, M., Chen, X., Pan, Y., Peng, Y., Sun, J., Kumar, A., & Liu, J. (2022) · Journal of Materials Chemistry B · doi:10.1039/d2tb00742h · Cited by 156
Metadata
- Authors
- Feng, X., Feng, Y., Guo, N., Sun, Y., Zhang, T., Ma, L., & Wang, L.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-01-17
- Volume
- 56
- Issue
- 3
- Pages
- 1713-1721
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2579053075
- Cited by
- 287
- References
- 23
- FWCI
- 21.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- Feng, X., Feng, Y., Guo, N., Sun, Y., Zhang, T., Ma, L., & Wang, L. (2017). Series d–f Heteronuclear Metal–Organic Frameworks: Color Tunability and Luminescent Probe with Switchable Properties. Inorganic Chemistry. https://doi.org/10.1021/acs.inorgchem.6b02851
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