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Series d–f Heteronuclear Metal–Organic Frameworks: Color Tunability and Luminescent Probe with Switchable Properties

Feng, Xun, Feng, Yuquan, Guo, Nan, Sun, Yiling, Zhang, Tian, Ma, Lufang, Wang, Liya·2017·Inorganic Chemistry

Abstract

A series of five unique d–f heteronuclear luminescent metal–organic frameworks (MOFs) in an entangled polyrotaxane array and the light-harvesting block homonuclear zinc compound have been isolated successfully and characterized. The series of isostructural polymers feature 3,4-connected (4.8 2 )(4.8 3 .9 2 )(6.8.9) 2 (6.9 2 )(8 3 ) topology and high stability, exhibiting diverse void spaces. By taking advantage of the isostructural MOFs 2 and 3, the intensities of red and green emissions can be modulated by adjusting the ratios of Eu III and Tb III ions correspondingly, and white-light emission can be generated by a combination of different doped Tb III and Eu III concentrations. The Tb–Zn-based framework {[Tb 3 Zn 6 (bipy 2 ) 2 (Hmimda) 7 (H 2 O) 3 ]·5H 2 O} n ( 3; H 3 mimda = 2-methyl-1- H -imidazole-4,5-dicarboxylic acid and bipy = 4,4′-bipyridine) can detect trace Mg II ion with relatively high sensitivity and selectivity. Dehydrated MOF 3a shows a remarkable emission quenching effect through the introduction of I 2 solids. Further investigation indicates that it exhibits turn on/off switchable properties for small solvent molecules or heavy-metal ions. Steady/transient-state near-IR luminescence properties for MOFs 1, 4, and 5 were investigated under visible-light excitation.

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Metadata

Authors
Feng, X., Feng, Y., Guo, N., Sun, Y., Zhang, T., Ma, L., & Wang, L.
Venue
Inorganic Chemistry
Published
2017-01-17
Volume
56
Issue
3
Pages
1713-1721
ISSN
  • 0020-1669 (ISSN-L)
  • 1520-510X
OpenAlex
W2579053075
Cited by
287
References
23
FWCI
21.20
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Series d–f Heteronuclear Metal–Organic Frameworks: Color Tunability and Luminescent Probe with Switchable Properties. https://app.cochat.ai/papers/10.1021/acs.inorgchem.6b02851
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Feng, X., Feng, Y., Guo, N., Sun, Y., Zhang, T., Ma, L., & Wang, L. (2017). Series d–f Heteronuclear Metal–Organic Frameworks: Color Tunability and Luminescent Probe with Switchable Properties. Inorganic Chemistry. https://doi.org/10.1021/acs.inorgchem.6b02851

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