Single-Crystal Growth and Room-Temperature Magnetocaloric Effect of X-Type Hexaferrite Sr2Co2Fe28O46
Open accessAbstract
X-type hexaferrites have been receiving considerable attention due to their promising applications in many magnetic-electronic fields. However, the growth of single-crystal X-type hexaferrite is still a challenge. Herein we reported, for the first time, the preparation of single crystal X-type hexaferrite Sr 2 Co 2 Fe 28 O 46 (Sr 2 Co 2 X) with high-quality and large size using floating-zone method with laser as the heating source. The crystals show rhombohedral symmetry with space group of R -3 m (No. 166, a = 5.8935(1) Å and c = 83.7438(17) Å). Co 2+ and Fe 3+ oxidation states were confirmed by the X-ray absorption near-edge spectroscopy. The prepared Sr 2 Co 2 X exhibits a spin reorientation transition from easy-cone to easy-axis at T 2 of 343 K and a ferrimagnetism–paramagnetism transition at Curie temperature ( T C ) of ∼743 K. The spin reorientation transition was accompanied by magnetocaloric effect (MCE). Both conventional and inverse MCEs were observed near T 2 with a magnetic field applied along the c -axis. The maximum value of the magnetic entropy change along the c -axis was evaluated to be 1.1 J/kg·K for a magnetic field change of 5 T.
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- Authors
- Wu, M., Zhou, X., Croft, M., Ehrlich, S., Khalid, S., Wen, W., Lapidus, S. H., Xu, X., Li, M.-R., Liu, Z., & Cheong, S.-W.
- Affiliations
- Rutgers, The State University of New Jersey (US)
- Guangxi University of Science and Technology (CN)
- Brookhaven National Laboratory (US)
- Chinese Academy of Sciences (CN)
- Argonne National Laboratory (US)
- Sun Yat-sen University (CN)
- South China University of Technology (CN)
- Corresponding author
- Li, Man-Rong
- Liu, Zhongwu
- ORCID
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-05-04
- Volume
- 59
- Issue
- 10
- Pages
- 6755-6762
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W3022346518
- Cited by
- 23
- References
- 45
- Citations by year
- 2026: 2 · 2025: 5 · 2024: 8 · 2023: 4 · 2022: 2 · 2021: 2
- FWCI
- 0.78
- Type
- journal article
- Language
- en
- Open access
- green
- www.osti.gov
- Licence
- Locations
- Inorganic Chemistry (publishedVersion)
- PubMed (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Rutgers University Community Repository (Rutgers University) (submittedVersion)
- Funders
- Ministry of Science and Technology of the People's Republic of China (2017YFA0402800)
- China Postdoctoral Science Foundation (2018M633222)
- U.S. Department of Energy (DE-FG02-07ER46382)
- National Natural Science Foundation of China (11804404, 21875287, U1732121, U1932201)
- Natural Science Foundation of Guangdong Province (c18140500000854)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Magnetic Properties and Synthesis of Ferrites
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Magnetic and transport properties of perovskites and related materials
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Multiferroics and related materials
- Keywords
- single crystal growth, floating zone crystal growth, laser heating, magnetocaloric effect, spin reorientation, ferrimagnetism, Curie temperature, magnetic entropy change, rhombohedral structure
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