Solid State Luminescence Enhancement in π-Conjugated Materials: Unraveling the Mechanism beyond the Framework of AIE/AIEE
Abstract
Solid state luminescence enhancement (SLE) of conjugated organic materials has had a great impact in materials science, but a deep understanding has been rather limited to date. Here, we investigate a prototype example of SLE materials, cyano-substituted distyrylbenzene (DCS), by varying systematically and subtly the substitution pattern ( inter alia of the position of the cyano-substituent) to give largely different photoresponse in fluid and solid solution as well in the crystalline state. The combination of quantitative (ultra)fast optical spectroscopic techniques, appropriate quantum-chemical methods, and structural (X-ray) data allows us to elucidate and rationalize all details of the SLE process, including steric versus electronic factors, radiative versus nonradiative decay channels, and intra- versus intermolecular contributions, providing a first holistic picture of SLE.
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The current paradigm in photochemistry points out that nonradiative deactivation from the excited-state molecules involves a conical intersection (CI).
“The current paradigm in photochemistry (unreasonably overlooked in the materials science community) points out that nonradiative deactivation from the excited-state molecules involves a conical intersection (CI).134−139”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [137]
The magnitude of vibronic interactions approaches infinity at the CI, where the S1 and S0 degenerate, from which the excitons decay nonradiatively.
“The magnitude of vibronic interactions approaches infinity at the CI, where the S1 and S0 degenerate, from which the excitons decay nonradiatively.”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [137]
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- Authors
- Shi, J., Aguilar Suarez, L. E., Yoon, S.-J., Varghese, S., Serpa, C., Park, S. Y., Lüer, L., Roca-Sanjuán, D., Milián-Medina, B., & Gierschner, J.
- Affiliations
- Madrid Institute for Advanced Studies (ES)
- Institute of Molecular Science, University of Valencia, P.O. Box 22085, ES-46071 Valencia, Spain
- Seoul National University (KR)
- University of Coimbra (PT)
- Madrid Institute for Advanced Studies, IMDEA Nanoscience, Calle Faraday 9, Campus Cantoblanco, 28049 Madrid, Spain
- Corresponding author
- Park, Soo Young
- Gierschner, Johannes
- ORCID
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-06
- Volume
- 121
- Issue
- 41
- Pages
- 23166-23183
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2758207712
- Cited by
- 217
- References
- 119
- Citations by year
- 2026: 14 · 2025: 21 · 2024: 18 · 2023: 20 · 2022: 25 · 2021: 30 · 2020: 42 · 2019: 26 · 2018: 19 · 2017: 2
- FWCI
- 10.28
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- The Journal of Physical Chemistry C (publishedVersion)
- Funders
- Consejo Superior de Investigaciones Cient?ficas
- European Regional Development Fund (CTQ2014-58801)
- Ministerio de Econom?a y Competitividad (CTQ2014-58801, RYC-2015-19234, SEV-2016-0686)
- National Research Foundation of Korea (2009-0081571)
- Universidad Aut?noma de Madrid
- European Cooperation in Science and Technology (MP1302)
- China Scholarship Council
- Comunidad de Madrid (S2013/MIT-284, S2013/MIT-3007)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
- Keywords
- aggregation-induced emission, aggregation-induced emission enhancement, π-conjugated organic materials, steric effects, electronic effects, crystalline state, photoresponse
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