Self-Assembly for Two Types of J-Aggregates: cis-Isomers of Dye on the Carbon Nanotube Surface and Free Aggregates of Dye trans-Isomers
Open accessAbstract
Development of novel nanoscale devices requires unique functional nanomaterials. Furthermore, chemical design of different nanoparticles in one unit is a complex task, particularly the application of self-assembly J-aggregates, which can substantially advance the nanomaterial’s properties due to resonant delocalization of excitons. Here, we have demonstrated for the first time formation of resonantly coherent J-aggregates on carbon nanotubes with highly efficient energy transfer from the aggregates to the nanotubes. All the energy of photons absorbed by the aggregates is conveyed to the nanotubes, completely quenching the J-band emission and photosensitizing the nanotubes. Overall, we discovered formation of two types of J-aggregates, where one type is related to self-assembly of cis -isomers on the nanotube surface and the second type is associated to self-organizing trans -isomers into free J-aggregates without the nanotubes. Importantly, the J-aggregates on carbon nanotubes with strong energy transfer peaks of photoluminescence in the near infrared range are of high interest for practical applications on biomedical imaging and nanoscale optoelectronic and nanophotonic devices.
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High durability of hybrid organic-inorganic nanocomposite systems has been demonstrated in J-aggregate-based photosensibilization and photoluminescence amplification in SWNTs and NIR emitting PbS quantum dots.
“The high durability of such systems has been demonstrated in J-aggregate-based photosensibilization and photoluminescence amplification in SWNTs and NIR emitting PbS quantum dots,228,229 organic dye-coated RENPs providing a tunable excitation, and increased SWIR luminescence with up to 40-fold enhancement.230,231”
From The Pursuit of Shortwave Infrared-Emitting Nanoparticles with Bright Fluorescence through Molecular Design and Excited-State Engineering of Molecular Aggregates (2022) · cites this paper as [229]
The Results and Discussion (page unavailable) report J-aggregate sensitization of SWNT emission and roughly 3.8–4.5-fold photoluminescence enhancement. The cited paper does not demonstrate high durability or address NIR-emitting PbS quantum dots; the latter may be covered by the other citation attached to the sentence. (LLM, conf=0.84)
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- Authors
- Lutsyk, P., Piryatinski, Y., Shandura, M., AlAraimi, M., Tesa, M., Arnaoutakis, G. E., Melvin, A. A., Kachkovsky, O., Verbitsky, A., & Rozhin, A.
- Affiliations
- National Academy of Sciences of Ukraine (UA)
- Institute of Physics, National Academy of Sciences of Ukraine, 46, prospekt Nauky, 03680 Kyiv, Ukraine
- Nanoscience Research Group & Aston Institute of Photonic Technologies, School of Engineering & Applied Science, Aston University, Aston Triangle, B4 7ET Birmingham, U.K.
- Edinburgh Instruments (United Kingdom) (GB)
- Ben-Gurion University of the Negev (IL)
- Aston University (GB)
- Corresponding author
- Lutsyk, Petro
- ORCID
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-07-22
- Volume
- 123
- Issue
- 32
- Pages
- 19903-19911
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2963425018
- Cited by
- 21
- References
- 32
- Citations by year
- 2026: 1 · 2025: 3 · 2024: 7 · 2023: 2 · 2022: 5 · 2021: 2 · 2020: 1
- FWCI
- 1.32
- Type
- journal article
- Language
- en
- Open access
- Licence
- Locations
- The Journal of Physical Chemistry C (publishedVersion)
- Aston Publications Explorer (Aston University) (submittedVersion)
- Funders
- Royal Academy of Engineering (LTSRF1617/13/57)
- Leverhulme Trust (LTSRF1617/13/57)
- Jacob Blaustein Center for Scientific Cooperation
- Horizon 2020 Framework Programme (690945, 654733)
- Topics
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Photochemistry and Electron Transfer Studies
- Physical Sciences › Materials Science › Materials Chemistry › Luminescence and Fluorescent Materials
- Physical Sciences › Materials Science › Materials Chemistry › Carbon Nanotubes in Composites
- Keywords
- J-aggregates, carbon nanotubes, cis-trans isomers, dye self-assembly, exciton delocalization, energy transfer, photosensitization, near-infrared emission, nanophotonic devices, biomedical imaging
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