The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Selective Electrochemical Generation of Hydrogen Peroxide from Water Oxidation
Open accessAbstract
Water is a life-giving source, fundamental to human existence, yet over a billion people lack access to clean drinking water. The present techniques for water treatment such as piped, treated water rely on time and resource intensive centralized solutions. In this work, we propose a decentralized device concept that can utilize sunlight to split water into hydrogen and hydrogen peroxide. The hydrogen peroxide can oxidize organics while the hydrogen bubbles out. In enabling this device, we require an electrocatalyst that can oxidize water while suppressing the thermodynamically favored oxygen evolution and form hydrogen peroxide. Using density functional theory calculations, we show that the free energy of adsorbed OH* can be used to determine selectivity trends between the 2e(-) water oxidation to H2O2 and the 4e(-) oxidation to O2. We show that materials which bind oxygen intermediates sufficiently weakly, such as SnO2, can activate hydrogen peroxide evolution. We present a rational design principle for the selectivity in electrochemical water oxidation and identify new material candidates that could perform H2O2 evolution selectively.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
Self-citationUniversality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Self-citationComputational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Self-citationSunscreens as a Source of Hydrogen Peroxide Production in Coastal Waters
Sánchez-Quiles, D., & Tovar-Sánchez, A. (2014) · Environmental Science & Technology · doi:10.1021/es5020696 · Cited by 122
Cited by
Hydrogen Peroxide: A Key Chemical for Today's Sustainable Development
Ciriminna, R., Albanese, L., Meneguzzo, F., & Pagliaro, M. (2016) · ChemSusChem · doi:10.1002/cssc.201600895 · Cited by 665
Measurement Techniques for the Study of Thin Film Heterogeneous Water Oxidation Electrocatalysts
Stevens, M. B., Enman, L. J., Batchellor, A. S., Cosby, M. R., Vise, A. E., Trang, C. D. M., & Boettcher, S. W. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02796 · Cited by 586
Siahrostami, S., Villegas, S. J., Bagherzadeh Mostaghimi, A. H., Back, S., Farimani, A. B., Wang, H., Persson, K. A., & Montoya, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01641 · Cited by 503
One- or Two-Electron Water Oxidation, Hydroxyl Radical, or H2O2 Evolution
Siahrostami, S., Li, G.-L., Viswanathan, V., & Nørskov, J. K. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02924 · Cited by 384
Self-citationZnO As an Active and Selective Catalyst for Electrochemical Water Oxidation to Hydrogen Peroxide
Kelly, S. R., Shi, X., Back, S., Vallez, L., Park, S. Y., Siahrostami, S., Zheng, X., & Nørskov, J. K. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04873 · Cited by 298
Self-citation
Metadata
- Authors
- Viswanathan, V., Hansen, H. A., & Nørskov, J. K.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-10-12
- Volume
- 6
- Issue
- 21
- Pages
- 4224-4228
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2102600510
- Cited by
- 199
- References
- 4
- FWCI
- 2.54
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
