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Black Phosphorus Quantum Dots for Hole Extraction of Typical Planar Hybrid Perovskite Solar Cells

Chen, Wei, Li, Kaiwen, Wang, Yao, Feng, Xiyuan, Liao, Zhenwu, Su, Qicong, Lin, Xinnan, He, Zhubing·2017·The Journal of Physical Chemistry Letters

Abstract

Black phosphorus, famous as two-dimensional (2D) materials, shows such excellent properties for optoelectronic devices such as tunable direct band gap, extremely high hole mobility (300–1000 cm 2 /(V s)), and so forth. In this Letter, facile processed black phosphorus quantum dots (BPQDs) were successfully applied to enhance hole extraction at the anode side of the typical p–i–n planar hybrid perovskite solar cells, which remarkably improved the performance of devices with photon conversion efficiency ramping up from 14.10 to 16.69%. Moreover, more detailed investigations by c-AFM, SKPM, SEM, hole-only devices, and photon physics measurements discover further the hole extraction effect and work mechanism of the BPQDs, such as nucleation assistance for the growth of large grain size perovskite crystals, fast hole extraction, more efficient hole transfer, and suppression of energy-loss recombination at the anode interface. This work definitely paves the way for discovering more and more 2D materials with high electronic properties to be used in photovoltaics and optoelectronics.

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Metadata

Authors
Chen, W., Li, K., Wang, Y., Feng, X., Liao, Z., Su, Q., Lin, X., & He, Z.
Venue
The Journal of Physical Chemistry Letters
Published
2017-01-18
Volume
8
Issue
3
Pages
591-598
ISSN
1948-7185 (ISSN-L)
OpenAlex
W2575882604
Cited by
224
References
1
FWCI
10.96
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Black Phosphorus Quantum Dots for Hole Extraction of Typical Planar Hybrid Perovskite Solar Cells. https://app.cochat.ai/papers/10.1021/acs.jpclett.6b02843
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Chen, W., Li, K., Wang, Y., Feng, X., Liao, Z., Su, Q., Lin, X., & He, Z. (2017). Black Phosphorus Quantum Dots for Hole Extraction of Typical Planar Hybrid Perovskite Solar Cells. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/acs.jpclett.6b02843

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