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Mixed Sn–Ge Perovskite for Enhanced Perovskite Solar Cell Performance in Air
Open accessAbstract
Lead-based perovskite solar cells have gained ground in recent years, showing efficiency as high as 20%, which is on par with that of silicon solar cells. However, the toxicity of lead makes it a nonideal candidate for use in solar cells. Alternatively, tin-based perovskites have been proposed because of their nontoxic nature and abundance. Unfortunately, these solar cells suffer from low efficiency and stability. Here, we propose a new type of perovskite material based on mixed tin and germanium. The material showed a band gap around 1.4-1.5 eV as measured from photoacoustic spectroscopy, which is ideal from the perspective of solar cells. In a solar cell device with inverted planar structure, pure tin perovskite solar cell showed a moderate efficiency of 3.31%. With 5% doping of germanium into the perovskite, the efficiency improved up to 4.48% (6.90% after 72 h) when measured in air without encapsulation.
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Cites
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Cited by
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Tin-Based Defects and Passivation Strategies in Tin-Related Perovskite Solar Cells
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Metadata
- Authors
- Ito, N., Kamarudin, M. A., Hirotani, D., Zhang, Y., Shen, Q., Ogomi, Y., Iikubo, S., Minemoto, T., Yoshino, K., & Hayase, S.
- Venue
- The Journal of Physical Chemistry Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-03-14
- Volume
- 9
- Issue
- 7
- Pages
- 1682-1688
- ISSN
- 1948-7185 (ISSN-L)
- OpenAlex
- W2791950121
- Cited by
- 299
- References
- 28
- FWCI
- 12.23
- Type
- journal article
- Language
- en
- Open access
- green
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- Ito, N., Kamarudin, M. A., Hirotani, D., Zhang, Y., Shen, Q., Ogomi, Y., Iikubo, S., Minemoto, T., Yoshino, K., & Hayase, S. (2018). Mixed Sn–Ge Perovskite for Enhanced Perovskite Solar Cell Performance in Air. The Journal of Physical Chemistry Letters. https://doi.org/10.1021/acs.jpclett.8b00275
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