The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Visible Light Mediated Controlled Radical Polymerization in the Absence of Exogenous Radical Sources or Catalysts
Abstract
The application of external stimuli such as light to induce controlled radical polymerization reactions has important implications in the field of materials science. In this study, the photoactivation of trithiocarbonates (TTCs) (i.e., conventional RAFT agents) by visible light (∼460 nm) is investigated, and the ability of TTCs to control radical polymerization under visible light in the complete absence of exogenous photoinitiators or catalysts is demonstrated for the first time. By selectively exciting the spin-forbidden n → π* electronic transition, polyacrylates and polyacrylamides of low dispersity and high end group fidelity were obtained. In addition, this approach allows for the efficient synthesis of well-defined linear, (multi)block, and network (co)polymers. This study demonstrates the versatility of our strategy to generate polymers with controllable properties by visible light, which may be highly useful for applications such as surface patterning.
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Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622
Kato, M., Kamigaito, M., Sawamoto, M., & Higashimura, T. (1995) · Macromolecules · doi:10.1021/ma00109a056 · Cited by 3,046
Peppas, N. A. (1997) · Current Opinion in Colloid & Interface Science · doi:10.1016/s1359-0294(97)80103-3 · Cited by 454
Cited by
Xu, J., Shanmugam, S., Fu, C., Aguey-Zinsou, K.-F., & Boyer, C. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b12408 · Cited by 313
Ultra-High Molecular Weights via Aqueous Reversible-Deactivation Radical Polymerization
Carmean, R. N., Becker, T. E., Sims, M. B., & Sumerlin, B. S. (2017) · Chem · doi:10.1016/j.chempr.2016.12.007 · Cited by 292
McKenzie, T. G., Fu, Q., Uchiyama, M., Satoh, K., Xu, J., Boyer, C., Kamigaito, M., & Qiao, G. G. (2016) · Advanced Science · doi:10.1002/advs.201500394 · Cited by 283
Self-citationPolymerization techniques in polymerization-induced self-assembly (PISA)
Liu, C., Hong, C.-Y., & Pan, C.-Y. (2020) · Polymer Chemistry · doi:10.1039/d0py00455c · Cited by 282
Yeow, J., Xu, J., & Boyer, C. (2015) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00523 · Cited by 266
Metadata
- Authors
- McKenzie, T. G., Fu, Q., Wong, E. H. H., Dunstan, D. E., & Qiao, G. G.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-15
- Volume
- 48
- Issue
- 12
- Pages
- 3864-3872
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2290956822
- Cited by
- 320
- References
- 4
- FWCI
- 16.63
- Type
- journal article
- Language
- en
- Open access
- closed
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