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Conjugated Microporous Polymers Incorporating BODIPY Moieties as Light-Emitting Materials and Recyclable Visible-Light Photocatalysts
Abstract
Here we report the design and synthesis of a new conjugated microporous polymer based on a BODIPY dye (CMPBDP) which has shown excellent luminescence properties and an efficient heterogeneous photocatalytic activity. CMPBDP shows high thermal stability and high surface area with microporous size and efficiently catalyzes the selective oxidation of thioanisole into the corresponding sulfoxide via singlet oxygen under visible light (up to 500 nm). The photocatalytic rate of the heterogeneous materials is 4-fold faster that the corresponding soluble (used as reference) under the same reaction conditions and can be reused several times.
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Citations
Cites
BODIPY dyes in photodynamic therapy
Kamkaew, A., Lim, S. H., Lee, H. B., Kiew, L. V., Chung, L. Y., & Burgess, K. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35216h · Cited by 2,104
Cited by
Porous Organic Materials: Strategic Design and Structure–Function Correlation
Das, S., Heasman, P., Ben, T., & Qiu, S. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00439 · Cited by 1,286
Conjugated polymers for visible-light-driven photocatalysis
Dai, C., & Liu, B. (2020) · Energy & Environmental Science · doi:10.1039/c9ee01935a · Cited by 687
Conjugated porous polymers: incredibly versatile materials with far-reaching applications
Taylor, D., Dalgarno, S. J., Xu, Z., & Vilela, F. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00315k · Cited by 259
Metadata
- Authors
- Liras, M., Iglesias, M., & Sánchez, F.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-02-17
- Volume
- 49
- Issue
- 5
- Pages
- 1666-1673
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2285099420
- Cited by
- 171
- References
- 1
- FWCI
- 10.19
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liras, M., Iglesias, M., & Sánchez, F. (2016). Conjugated Microporous Polymers Incorporating BODIPY Moieties as Light-Emitting Materials and Recyclable Visible-Light Photocatalysts. Macromolecules. https://doi.org/10.1021/acs.macromol.5b02511
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.