High Temperature Thermoplastic Elastomers Synthesized by Living Anionic Polymerization in Hydrocarbon Solvent at Room Temperature
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We present the synthesis and characterization of a new class of high temperature thermoplastic elastomers composed of polybenzofulvene–polyisoprene–polybenzofulvene (FIF) triblock copolymers. All copolymers were prepared by living anionic polymerization in benzene at room temperature. Homopolymerization and effects of additives on the glass transition temperature ( T g ) of polybenzofulvene (PBF) were also investigated. Among all triblock copolymers studied, FIF with 14 vol % of PBF exhibited a maximum stress of 14.3 ± 1.3 MPa and strain at break of 1390 ± 66% from tensile tests. The stress–strain curves of FIF-10 and 14 were analyzed by a statistical molecular approach using a nonaffine tube model to estimate the thermoplastic elastomer behavior. Dynamic mechanical analysis showed that the softening temperature of PBF in FIF was 145 °C, much higher than that of thermoplastic elastomers with polystyrene hard blocks. Microphase separation of FIF triblock copolymers was observed by small-angle X-ray scattering, even though long-range order was not achieved under the annealing conditions employed. In addition, the microphase separation of the resulting triblock copolymers was examined by atomic force microscopy.
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The softening temperature of PBF in FIF is much higher than that of thermoplastic elastomers with PS hard blocks.
“Dynamic mechanical analysis showed that the softening temperature of PBF in FIF was 145 °C, which is much higher than that of thermoplastic elastomers with PS hard blocks (Figure 15).”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [92]
The softening temperature of PBF in FIF was 145 °C.
“Dynamic mechanical analysis showed that the softening temperature of PBF in FIF was 145 °C, which is much higher than that of thermoplastic elastomers with PS hard blocks (Figure 15).”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [92]
FIF with 14 vol % of PBF exhibited a maximum stress of 14.3 ± 1.3 MPa from tensile tests.
“FIF with 14 vol % of PBF exhibited a maximum stress of 14.3 ± 1.3 MPa and strain at break of 1390 ± 66% from tensile tests [92].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [92]
FIF with 14 vol % of PBF exhibited a strain at break of 1390 ± 66% from tensile tests.
“FIF with 14 vol % of PBF exhibited a maximum stress of 14.3 ± 1.3 MPa and strain at break of 1390 ± 66% from tensile tests [92].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [92]
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Cites
SZWARC, M. (1956) · Nature · doi:10.1038/1781168a0 · Cited by 1,360 · see citing works
Polymers with Complex Architecture by Living Anionic Polymerization
Hadjichristidis, N., Pitsikalis, M., Pispas, S., & Iatrou, H. (2001) · Chemical Reviews · doi:10.1021/cr9901337 · Cited by 1,330 · see citing works
Anionic Polymerization: Principles and Practical Applications
Hsieh, H., & Quirk, R. P. (1996) · doi:10.1201/9780585139401 · Cited by 1,047 · see citing works
Szwarc, M., Levy, M., & Milkovich, R. (1956) · Journal of the American Chemical Society · doi:10.1021/ja01592a101 · Cited by 988 · see citing works
Heinrich, G., Klüppel, M., & Vilgis, T. A. (2002) · Current Opinion in Solid State and Materials Science · doi:10.1016/s1359-0286(02)00030-x · Cited by 668 · see citing works
Developments in block copolymers—1
Lewis, J. E. (1983) · Polymer Photochemistry · doi:10.1016/0144-2880(83)90103-3 · Cited by 414 · see citing works
Experimental techniques in high-vacuum anionic polymerization
Uhrig, D., & Mays, J. W. (2005) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.21016 · Cited by 293 · see citing works
Self-citationHirao, A., Goseki, R., & Ishizone, T. (2014) · Macromolecules · doi:10.1021/ma401175m · Cited by 288 · see citing works
Sustainable thermoplastic elastomers from terpene-derived monomers
Bolton, J. M., Hillmyer, M. A., & Hoye, T. R. (2014) · ACS Macro Letters · doi:10.1021/mz500339h · Cited by 186 · see citing works
Klüppel, M., & Schramm, J. (2000) · Macromolecular Theory and Simulations · doi:10.1002/1521-3919(20001201)9:9 · Cited by 173 · see citing works
Fetters, L. J., & Morton, M. (1969) · Macromolecules · doi:10.1021/ma60011a002 · Cited by 161 · see citing works
Iatrou, H., Mays, J. W., & Hadjichristidis, N. (1998) · Macromolecules · doi:10.1021/ma980738p · Cited by 132 · see citing works
Self-citationBeyer, F. L., Gido, S. P., Büschl, C., Iatrou, H., Uhrig, D. W., Mays, J. W., Chang, M. Y., Garetz, B. A., Balsara, N. P., Tan, N. C. B., et al. (2000) · Macromolecules · doi:10.1021/ma991141s · Cited by 113 · see citing works
Self-citationChadwick, S. T., Rennels, R. A., Rutherford, J. L., & Collum, D. B. (2000) · Journal of the American Chemical Society · doi:10.1021/ja001471o · Cited by 109 · see citing works
Holden, G. (2000) · Kirk-Othmer Encyclopedia of Chemical Technology · doi:10.1002/0471238961.2008051808151204.a01 · Cited by 108 · see citing works
Anionic polymerization to high vinyl polybutadiene
Halasa, A. F., Lohr, D. F., & Hall, J. E. (1981) · Journal of Polymer Science Polymer Chemistry Edition · doi:10.1002/pol.1981.170190608 · Cited by 99 · see citing works
Mosnáček, J., Yoon, J. A., Juhari, A., Koynov, K., & Matyjaszewski, K. A. (2009) · Polymer · doi:10.1016/j.polymer.2009.02.037 · Cited by 84 · see citing works
Natori, I., & Inoue, S. (1998) · Macromolecules · doi:10.1021/ma9718661 · Cited by 78 · see citing works
Baeurle, S. A., Hotta, A., & Gusev, A. A. (2004) · Polymer · doi:10.1016/j.polymer.2004.07.034 · Cited by 75 · see citing works
1,3-Cyclohexadiene Polymers. 1. Anionic Polymerization
Hong, K., & Mays, J. W. (2001) · Macromolecules · doi:10.1021/ma0015626 · Cited by 74 · see citing works
Self-citationJuhari, A., Mosnáček, J., Yoon, J. A., Nese, A., Koynov, K., Kowalewski, T., & Matyjaszewski, K. A. (2010) · Polymer · doi:10.1016/j.polymer.2010.08.017 · Cited by 70 · see citing works
Modelling of stress and strain amplification effects in filled polymer melts
Domurath, J., Saphiannikova, M., Ausias, G., & Heinrich, G. (2012) · Journal of Non-Newtonian Fluid Mechanics · doi:10.1016/j.jnnfm.2012.01.001 · Cited by 62 · see citing works
Yu, J. M., Dubois, P., & Jérôme, R. (1996) · Macromolecules · doi:10.1021/ma960710i · Cited by 58 · see citing works
Living Anionic Polymerization of Benzofulvene: Highly Reactive Fixed Transoid 1,3-Diene
Kosaka, Y., Kitazawa, K., Inomata, S., & Ishizone, T. (2013) · ACS Macro Letters · doi:10.1021/mz4000078 · Cited by 58 · see citing works
Li, D., & Faust, R. (1995) · Macromolecules · doi:10.1021/ma00118a015 · Cited by 48 · see citing works
Kobayashi, S., Kataoka, H., Ishizone, T., Kato, T., Ono, T., Kobukata, S., & Ogi, H. (2008) · Macromolecules · doi:10.1021/ma7028743 · Cited by 45 · see citing works
High Anionic Polymerizability of Benzofulvene: New Exo-Methylene Hydrocarbon Monomer
Kosaka, Y., Kawauchi, S., Goseki, R., & Ishizone, T. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00944 · Cited by 44 · see citing works
Yu, J. M., Dúbois, P., & Jérôme, R. (1996) · Macromolecules · doi:10.1021/ma960886k · Cited by 43 · see citing works
Puskas, J. E., Kaszás, G., Kennedy, J. P., & Hager, W. G. (1992) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.1992.080300105 · Cited by 40 · see citing works
Fetters, L. J., Firer, E. M., & Dafauti, M. (1977) · Macromolecules · doi:10.1021/ma60060a008 · Cited by 38 · see citing works
Synthesis and Characterization of Elastomeric Heptablock Terpolymers Structured by Crystallization
Alfonzo, C. G., Fleury, G., Chaffin, K. A., & Bates, F. S. (2010) · Macromolecules · doi:10.1021/ma100347k · Cited by 38 · see citing works
Applications of Anionic Polymerization Research
Quirk1, R. P. (1998) · ACS symposium series · doi:10.1021/bk-1998-0696 · Cited by 28 · see citing works
Yu, J. M., Dúbois, P., & Jérôme, R. (1997) · Macromolecules · doi:10.1021/ma961849w · Cited by 25 · see citing works
Londergan, T., Teng, C. J., & Weber, W. P. (1999) · Macromolecules · doi:10.1021/ma9816113 · Cited by 23 · see citing works
Imaeda, T., Hashimoto, T., Irie, S., Urushisaki, M., & Sakaguchi, T. (2013) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26561 · Cited by 18 · see citing works
Yu, Y., Dúbois, P., Teyssié, P., & Jérôme, R. (1997) · Macromolecules · doi:10.1021/ma961819t · Cited by 18 · see citing works
High-Strain-Induced Deformation Mechanisms in Block–Graft and Multigraft Copolymers
Schlegel, R., Duan, Y., Weidisch, R., Holzer, S., Schneider, K., Stamm, M., Uhrig, D. W., Mays, J. W., Heinrich, G., & Hadjichristidis, N. (2011) · Macromolecules · doi:10.1021/ma201353w · Cited by 17 · see citing works
Self-citationCunningham, R. E., Auerbach, M., & Floyd, W. J. (1972) · Journal of Applied Polymer Science · doi:10.1002/app.1972.070160115 · Cited by 15 · see citing works
Living Anionic Polymerization of Benzofulvene in Hydrocarbon Solvent
Kosaka, Y., Goseki, R., Kawauchi, S., & Ishizone, T. (2015) · Macromolecular Symposia · doi:10.1002/masy.201400024 · Cited by 14 · see citing works
Applications of Thermoplastic Elastomers Based on Styrenic Block Copolymers
Handlin, D. L., Trenor, S. R., & Wright, K. J. (2007) · doi:10.1002/9783527631421.ch48 · Cited by 13 · see citing works
Uhrig, D. W., Hong, K., Mays, J. W., Kilbey, S. M., & Britt, P. F. (2008) · Macromolecules · doi:10.1021/ma801852t · Cited by 12 · see citing works
Self-citationPolyisobutylene-containing block polymers by sequential monomer addition
Fodor, Z., & Kennedy, J. P. (1992) · Polymer Bulletin · doi:10.1007/bf01041157 · Cited by 11 · see citing works
Poshyachinda, S., Edwards, H. G. M., & Johnson, A. F. (1997) · Polymer · doi:10.1016/s0032-3861(96)00544-7 · Cited by 4 · see citing works
Drumright, R. E., Gruber, P. R., & Henton, D. E. (2000) · Advanced Materials · doi:10.1002/1521-4095(200012)12:23
Flagged first, then by citations
Research works printed but not linked: 28
- [1]1. a) Szwarc, M. Nature 1956, 178 , 1168; (
- [2]2. Szwarc, M.; Levy, M.; Milkovich, R. J. Am. Chem. Soc. 1956, 78, 2656.
- [3]3. Hadjichristidis, N.; Pitsikalis, M.; Pispas, S.; Iatrou, H. Chem. Rev. 2001, 101 , 3747.
- [4]4. Hirao, A.; Goseki, R.; Ishizone, T. Macromolecules 2014, 47, 1883.
- [10]10. Fetters, L. J.; Morton, M. Macromolecules 1969, 2, 453.
- [11]11. Bolton, J. M.; Hillmyer, M. A.; Hoye, T. R. ACS Macro Letters 2014, 3, 717.
- [12]12. Fetters, L. J.; Firer, E. M.; Dafauti, M. Macromolecules 1977, 10, 1200.
- [13]13. Kobayashi, S.; Kataoka, H.; Ishizone, T.; Kato, T.; Ono, T.; Kobukata, S.; Ogi, H. Macromolecules 2008, 41, 5502.
- [14]14. Alfonzo, C. G.; Fleury, G.; Chaffin, K. A.; Bates, F. S. Macromolecules 2010, 43, 5295.
- [15]15. Hucul, D. A.; Hahn, S. F. Adv. Mater. 2000, 12, 1855.
- [16]16. Yu, Y.; Dubois, P.; Teyssié, P.; Jérôme, R. Macromolecules 1997, 30, 4254.
- [17]17. Yu, J. M.; Dubois, P.; Jérôme, R. Macromolecules 1997, 30, 6536.
- [18]18. Yu, J. M.; Dubois, P.; Jérôme, R. Macromolecules 1996, 29, 8362.
- [19]19. Yu, J. M.; Dubois, P.; Jérôme, R. Macromolecules 1996, 29, 7316.
- [20]20. Fodor, Z.; Kennedy, J. P. Poly. Bull. 1992, 29, 697.
- [21]21. Puskas, J. E.; Kaszas, G.; Kennedy, J. P.; Hager, W. G. J. Polym. Sci., Part A: Polym. Chem. 1992, 30, 41.
- [22]22. Li, D.; Faust, R. Macromolecules 1995, 28, 4893.
- [24]24. Imaeda, T.; Hashimoto, T.; Irie, S.; Urushisaki, M.; Sakaguchi, T. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 1796.
- [25]25. Mosnáček, J.; Yoon, J. A.; Juhari, A.; Koynov, K.; Matyjaszewski, K. Polym. 2009, 50, 2087.
- [26]26. Juhari, A.; Mosnáček, J.; Yoon, J. A.; Nese, A.; Koynov, K.; Kowalewski, T.; Matyjaszewski, K. Polym. 2010, 51, 4806.
- [27]27. Kosaka, Y.; Kitazawa, K.; Inomata, S.; Ishizone, T. ACS Macro Letters 2013, 2, 164.
- [28]28. Kosaka, Y.; Goseki, R.; Kawauchi, S.; Ishizone, T. Macromol. Symp. 2015, 350, 55.
- [29]29. Kosaka, Y.; Kawauchi, S.; Goseki, R.; Ishizone, T. Macromolecules 2015, 48, 4421.
- [31]31. Uhrig, D.; Mays, J. W. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 6179.
- [32]32. Hsieh, H.; Quirk, R. P. Anionic Polymerization: Principles and Practical Applications; Marcel Dekker Inc.: New York, 1996; chapter 9, p197-235.
- [33]33. Natori, I.; Inoue, S. Macromolecules 1998, 31, 4687.
- [34]34. Hong, K.; Mays, J. W. Macromolecules 2001, 34, 782.
- [35]35. Klüppel, M.; Schramm, J. Macromol. Theory Simul. 2000, 9, 742.
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“3 MPa and strain at break of 1390 ± 66% from tensile tests [92].”
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Vishwanath, V., USDOE Office of Science (SC), Emani, M. K., Taylor, V., Foster, I., Habib, S., Papka, M., Babu, A., CHAN, H., Cherukara, M., et al. (2022) · doi:10.2172/2217141 · Cited by 1 · see citing works
Schlegel, R., Budde, H., Mahmood, N., Wendler, U., Bartke, M., & Beiner, M. (2023) · Macromolecular Chemistry and Physics · doi:10.1002/macp.202300142
Self-citationLi, Y., Lu, Y.-P., Yang, X.-H., Jie, T. W. J. T. W., Shen, P., Xia, C., & Ran, G. (2025) · Organic Letters · doi:10.1021/acs.orglett.5c00051
- Authors
- Wang, W., Schlegel, R., White, B. T., Williams, K., Voyloy, D., Steren, C. A., Goodwin, A., Coughlin, E. B., Gido, S., Beiner, M., Hong, K., Kang, N.-G., & Mays, J.
- Affiliations
- University of Tennessee at Knoxville (US)
- Fraunhofer Institute for Microstructure of Materials and Systems (DE)
- University of Massachusetts Amherst (US)
- Oak Ridge National Laboratory (US)
- Corresponding author
- Kang, Nam-Goo
- Mays, Jimmy
- ORCID
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-03-30
- Volume
- 49
- Issue
- 7
- Pages
- 2646-2655
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2327074625
- Cited by
- 49
- References
- 44
- Citations by year
- 2025: 3 · 2024: 8 · 2023: 1 · 2022: 3 · 2021: 8 · 2020: 4 · 2019: 7 · 2018: 4 · 2017: 10 · 2016: 1
- FWCI
- 3.27
- Type
- journal article
- Language
- en
- Open access
- green
- www.osti.gov
- Locations
- Macromolecules (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Fraunhofer-Publica (Fraunhofer-Gesellschaft) (submittedVersion)
- Funders
- Division of Industrial Innovation and Partnerships (1237787)
- Army Research Office (W911-NF-11-0417)
- Bill and Melinda Gates Foundation
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- thermoplastic elastomers, polyisoprene, triblock copolymers, living anionic polymerization, room-temperature polymerization, hydrocarbon solvents, glass transition temperature, microphase separation, tensile properties, softening point, long-range order
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