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Cited by 336

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Deterministic Two-Dimensional Polymorphism Growth of Hexagonal n-Type SnS2 and Orthorhombic p-Type SnS Crystals

Ahn, Ji-Hoon, Lee, Myoung-Jae, Heo, Hoseok, Sung, Ji Ho, Kim, Kyungwook, Hwang, Hyein, Jo, Moon-Ho·2015·Nano Letters

Abstract

van der Waals layered materials have large crystal anisotropy and crystallize spontaneously into two-dimensional (2D) morphologies. Two-dimensional materials with hexagonal lattices are emerging 2D confined electronic systems at the limit of one or three atom thickness. Often these 2D lattices also form orthorhombic symmetries, but these materials have not been extensively investigated, mainly due to thermodynamic instability during crystal growth. Here, we show controlled polymorphic growth of 2D tin-sulfide crystals of either hexagonal SnS2 or orthorhombic SnS. Addition of H2 during the growth reaction enables selective determination of either n-type SnS2 or p-type SnS 2D crystal of dissimilar energy band gap of 2.77 eV (SnS2) or 1.26 eV (SnS) as a final product. Based on this synthetic 2D polymorphism of p-n crystals, we also demonstrate p-n heterojunctions for rectifiers and photovoltaic cells, and complementary inverters.

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Metadata

Authors
Ahn, J.-H., Lee, M.-J., Heo, H., Sung, J. H., Kim, K., Hwang, H., & Jo, M.-H.
Venue
Nano Letters
Published
2015-05-06
Volume
15
Issue
6
Pages
3703-3708
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W1984790205
Cited by
336
References
3
FWCI
14.12
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Deterministic Two-Dimensional Polymorphism Growth of Hexagonal n-Type SnS2 and Orthorhombic p-Type SnS Crystals. https://app.cochat.ai/papers/10.1021/acs.nanolett.5b00079
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Ahn, J.-H., Lee, M.-J., Heo, H., Sung, J. H., Kim, K., Hwang, H., & Jo, M.-H. (2015). Deterministic Two-Dimensional Polymorphism Growth of Hexagonal n-Type SnS2 and Orthorhombic p-Type SnS Crystals. Nano Letters. https://doi.org/10.1021/acs.nanolett.5b00079

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