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Self-Extinguishing Lithium Ion Batteries Based on Internally Embedded Fire-Extinguishing Microcapsules with Temperature-Responsiveness
Abstract
User safety is one of the most critical issues for the successful implementation of lithium ion batteries (LIBs) in electric vehicles and their further expansion in large-scale energy storage systems. Herein, we propose a novel approach to realize self-extinguishing capability of LIBs for effective safety improvement by integrating temperature-responsive microcapsules containing a fire-extinguishing agent. The microcapsules are designed to release an extinguisher agent upon increased internal temperature of an LIB, resulting in rapid heat absorption through an in situ endothermic reaction and suppression of further temperature rise and undesirable thermal runaway. In a standard nail penetration test, the temperature rise is reduced by 74% without compromising electrochemical performances. It is anticipated that on the strengths of excellent scalability, simplicity, and cost-effectiveness, this novel strategy can be extensively applied to various high energy-density devices to ensure human safety.
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Cites
Hydrogels for biomedical applications
Hoffman, A. S. (2002) · Advanced Drug Delivery Reviews · doi:10.1016/s0169-409x(01)00239-3 · Cited by 4,864
Cited by
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Materials for lithium-ion battery safety
Liu, K., Liu, Y., Lin, D., Pei, A., & Cui, Y. (2018) · Science Advances · doi:10.1126/sciadv.aas9820 · Cited by 1,625
Progress of enhancing the safety of lithium ion battery from the electrolyte aspect
Wang, Q., Jiang, L., Yu, Y., & Sun, J. (2019) · Nano Energy · doi:10.1016/j.nanoen.2018.10.035 · Cited by 915
Building Safe Lithium-Ion Batteries for Electric Vehicles: A Review
Duan, J., Tang, X., Dai, H., Yang, Y., Wu, W., Wei, X., & Huang, Y. (2020) · Electrochemical Energy Reviews · doi:10.1007/s41918-019-00060-4 · Cited by 893
Multifunctional Energy Storage and Conversion Devices
Huang, Y., Zhu, M., Huang, Y., Pei, Z., Li, H., Wang, Z., Xue, Q., & Zhi, C. (2016) · Advanced Materials · doi:10.1002/adma.201601928 · Cited by 544
Metadata
- Authors
- Yim, T., Park, M.-S., Woo, S.-G., Kwon, H.-K., Yoo, J.-K., Jung, Y. S., Kim, K. J., Yu, J.-S., & Kim, Y.-J.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-07-20
- Volume
- 15
- Issue
- 8
- Pages
- 5059-5067
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2279026311
- Cited by
- 162
- References
- 1
- FWCI
- 8.54
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Self-Extinguishing Lithium Ion Batteries Based on Internally Embedded Fire-Extinguishing Microcapsules with Temperature-Responsiveness. https://app.cochat.ai/papers/10.1021/acs.nanolett.5b01167
- The paper
- Yim, T., Park, M.-S., Woo, S.-G., Kwon, H.-K., Yoo, J.-K., Jung, Y. S., Kim, K. J., Yu, J.-S., & Kim, Y.-J. (2015). Self-Extinguishing Lithium Ion Batteries Based on Internally Embedded Fire-Extinguishing Microcapsules with Temperature-Responsiveness. Nano Letters. https://doi.org/10.1021/acs.nanolett.5b01167
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