The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
A Thermally Conductive Separator for Stable Li Metal Anodes
Abstract
Li metal anodes have attracted considerable research interest due to their low redox potential (-3.04 V vs standard hydrogen electrode) and high theoretical gravimetric capacity of 3861 mAh/g. Battery technologies using Li metal anodes have shown much higher energy density than current Li-ion batteries (LIBs) such as Li-O2 and Li-S systems. However, issues related to dendritic Li formation and low Coulombic efficiency have prevented the use of Li metal anode technology in many practical applications. In this paper, a thermally conductive separator coated with boron-nitride (BN) nanosheets has been developed to improve the stability of the Li metal anodes. It is found that using the BN-coated separator in a conventional organic carbonate-based electrolyte results in the Coulombic efficiency stabilizing at 92% over 100 cycles at a current rate of 0.5 mA/cm(2) and 88% at 1.0 mA/cm(2). The improved Coulombic efficiency and reliability of the Li metal anodes is due to the more homogeneous thermal distribution resulting from the thermally conductive BN coating and to the smaller surface area of initial Li deposition.
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Citations
Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Cited by
Energy storage: The future enabled by nanomaterials
Pomerantseva, E., Bonaccorso, F., Feng, X., Cui, Y., & Gogotsi, Y. (2019) · Science · doi:10.1126/science.aan8285 · Cited by 1,927
Review on High‐Loading and High‐Energy Lithium–Sulfur Batteries
Peng, H., Huang, J., Cheng, X., & Zhang, Q. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700260 · Cited by 1,746
Chemical Dealloying Derived 3D Porous Current Collector for Li Metal Anodes
Yun, Q., He, Y., Lv, W., Zhao, Y., Li, B., Kang, F., & Yang, Q. (2016) · Advanced Materials · doi:10.1002/adma.201601409 · Cited by 870
Advanced Micro/Nanostructures for Lithium Metal Anodes
Zhang, R., Li, N., Cheng, X., Yin, Y., Zhang, Q., & Guo, Y. (2017) · Advanced Science · doi:10.1002/advs.201600445 · Cited by 549
Lithium metal anodes: Present and future
Wang, R., Cui, W., Chu, F., & Wu, F. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2019.12.024 · Cited by 544
Metadata
- Authors
- Luo, W., Zhou, L., Fu, K., Yang, Z., Wan, J., Manno, M., Yao, Y., Zhu, H., Yang, B., & Hu, L.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-08-10
- Volume
- 15
- Issue
- 9
- Pages
- 6149-6154
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2422073305
- Cited by
- 356
- References
- 1
- FWCI
- 16.84
- Type
- journal article
- Language
- en
- Open access
- closed
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- Luo, W., Zhou, L., Fu, K., Yang, Z., Wan, J., Manno, M., Yao, Y., Zhu, H., Yang, B., & Hu, L. (2015). A Thermally Conductive Separator for Stable Li Metal Anodes. Nano Letters. https://doi.org/10.1021/acs.nanolett.5b02432
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