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Magnesium as Novel Material for Active Plasmonics in the Visible Wavelength Range
Abstract
Investigating new materials plays an important role for advancing the field of nanoplasmonics. In this work, we fabricate nanodisks from magnesium and demonstrate tuning of their plasmon resonance throughout the whole visible wavelength range by changing the disk diameter. Furthermore, we employ a catalytic palladium cap layer to transform the metallic Mg particles into dielectric MgH2 particles when exposed to hydrogen gas. We prove that this transition can be reversed in the presence of oxygen. This yields plasmonic nanostructures with an extinction spectrum that can be repeatedly switched on or off or kept at any intermediate state, offering new perspectives for active plasmonic metamaterials.
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“However, similar to Mg, Al suffers from the formation of an oxide layer several nanometers thick that limits the UV plasmonic performance.”
From Nanoparticles Engineering by Pulsed Laser Ablation in Liquids: Concepts and Applications (2020) · cites this paper as [196]
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Self-citation
Metadata
- Authors
- Sterl, F., Strohfeldt, N., Walter, R., Griessen, R., Tittl, A., & Giessen, H.
- Affiliations
- University of Stuttgart (DE)
- Vrije Universiteit Amsterdam (NL)
- Corresponding author
- Sterl, Florian
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-08-31
- Volume
- 15
- Issue
- 12
- Pages
- 7949-7955
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2409978143
- Cited by
- 188
- References
- 56
- Citations by year
- 2026: 7 · 2025: 8 · 2024: 5 · 2023: 16 · 2022: 19 · 2021: 21 · 2020: 21 · 2019: 33 · 2018: 23 · 2017: 19 · 2016: 14 · 2015: 2
- FWCI
- 9.62
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Nano Letters (publishedVersion)
- PubMed (publishedVersion)
- VU Research Portal (publishedVersion)
- Data Archiving and Networked Services (DANS) (submittedVersion)
- Funders
- Bundesministerium für Bildung und Forschung
- Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg
- Deutsche Forschungsgemeinschaft (SPP1391, SPP1839)
- Baden-Württemberg Stiftung
- European Commission (COMPLEXPLAS)
- Max-Planck-Institut für Festkörperforschung
- Topics
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Plasmonic and Surface Plasmon Research
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Gold and Silver Nanoparticles Synthesis and Applications
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Metamaterials and Metasurfaces Applications
- Keywords
- plasmon resonance tuning, magnesium hydride, palladium catalysis, molecular hydrogen, oxygen exposure, plasmonic metamaterials, active plasmonics
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