The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
Dynamical Observation and Detailed Description of Catalysts under Strong Metal–Support Interaction
Open accessAbstract
Understanding the structures of catalysts under realistic conditions with atomic precision is crucial to design better materials for challenging transformations. Under reducing conditions, certain reducible supports migrate onto supported metallic particles and create strong metal-support states that drastically change the reactivity of the systems. The details of this process are still unclear and preclude its thorough exploitation. Here, we report an atomic description of a palladium/titania (Pd/TiO2) system by combining state-of-the-art in situ transmission electron microscopy and density functional theory (DFT) calculations with structurally defined materials, in which we visualize the formation of the overlayers at the atomic scale under atmospheric pressure and high temperature. We show that an amorphous reduced titania layer is formed at low temperatures, and that crystallization of the layer into either mono- or bilayer structures is dictated by the reaction environment and predicted by theory. Furthermore, it occurs in combination with a dramatic reshaping of the metallic surface facets.
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Cites
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
Giannozzi, P., Baroni, S., Bonini, N., Calandra, M., Car, R., Cavazzoni, C., Ceresoli, D., Chiarotti, G. L., Cococcioni, M., Dabo, I., et al. (2009) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/21/39/395502 · Cited by 29,281
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism
Vanderbilt, D. (1990) · Physical Review B · doi:10.1103/physrevb.41.7892 · Cited by 23,185
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
Tauster, S. J., Fung, S. C., & Garten, R. L. (1978) · Journal of the American Chemical Society · doi:10.1021/ja00469a029 · Cited by 3,188
Active Nonmetallic Au and Pt Species on Ceria-Based Water-Gas Shift Catalysts
Fu, Q., Saltsburg, H., & Flytzani-Stephanopoulos, M. (2003) · Science · doi:10.1126/science.1085721 · Cited by 2,954
The Active Site of Methanol Synthesis over Cu/ZnO/Al 2 O 3 Industrial Catalysts
Behrens, M., Studt, F., Kasatkin, I., Kühl, S., Hävecker, M., Abild-Pedersen, F., Zander, S., Girgsdies, F., Kurr, P., Kniep, B.-L., et al. (2012) · Science · doi:10.1126/science.1219831 · Cited by 2,670
Self-citationDipole correction for surface supercell calculations
Bengtsson, L. (1999) · Physical Review B · doi:10.1103/physrevb.59.12301 · Cited by 2,052
Surface studies of supported model catalysts
Henry, C. R. (1998) · Surface Science Reports · doi:10.1016/s0167-5729(98)00002-8 · Cited by 1,473
Strong metal-support interactions
Tauster, S. J. (1987) · Accounts of Chemical Research · doi:10.1021/ar00143a001 · Cited by 1,473
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts
Cargnello, M., Doan-Nguyen, V. V. T., Gordon, T. R., Diaz, R. E., Stach, E. A., Gorte, R. J., Fornasiero, P., & Murray, C. B. (2013) · Science · doi:10.1126/science.1240148 · Cited by 1,412
Self-citationStrong Interactions in Supported-Metal Catalysts
Tauster, S. J., Fung, S. C., Baker, R. T. K., & Horsley, J. A. (1981) · Science · doi:10.1126/science.211.4487.1121 · Cited by 1,343
Cited by
Electrocatalysts for the Oxygen Evolution Reaction: Mechanism, Innovative Strategies, and Beyond
Wen, N., Jiao, X., Xia, Y., & Chen, D. (2023) · Materials Chemistry Frontiers · doi:10.1039/d3qm00423f · Cited by 104
Metadata
- Authors
- Zhang, S., Plessow, P. N., Willis, J. J., Dai, S., Xu, M., Graham, G. W., Cargnello, M., Abild-Pedersen, F., & Pan, X.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-06-13
- Volume
- 16
- Issue
- 7
- Pages
- 4528-4534
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2410357802
- Cited by
- 312
- References
- 24
- FWCI
- 10.19
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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