The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
In Situ Electrochemically Derived Nanoporous Oxides from Transition Metal Dichalcogenides for Active Oxygen Evolution Catalysts
Abstract
Transition metal dichalcogenides have been widely studied as active electrocatalysts for hydrogen evolution reactions. However, their properties as oxygen evolution reaction catalysts have not been fully explored. In this study, we systematically investigate a family of transition metal dichalcogenides (MX, M = Co, Ni, Fe; X = S, Se, Te) as candidates for water oxidation. It reveals that the transition metal dichalcogenides are easily oxidized in strong alkaline media via an in situ electrochemical oxidation process, producing nanoporous transition metal oxides toward much enhanced water oxidation activity due to their increased surface area and more exposed electroactive sites. The optimal cobalt nickel iron oxides that derived from their sulfides and selenides demonstrate a low overpotential of 232 mV at current density of 10 mA cm –2, a small Tafel slope of 35 mV per decade, and negligible degradation of electrochemical activity over 200 h of electrolysis. This study represents the discovery of nanoporous transition metal oxides deriving from their chalcogenides as outstanding electrocatalysts for water oxidation.
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Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
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MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
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Self-citationKibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
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Synthesis of MoS 2 and MoSe 2 Films with Vertically Aligned Layers
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Self-citationThe Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
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Two-dimensional transition metal dichalcogenide nanosheet-based composites
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Du, W., Shi, Y., Zhou, W., Yu, Y., & Zhang, B. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202015723 · Cited by 512
Huang, J., Li, Y., Zhang, Y., Rao, G., Wu, C., Hu, Y., Wang, X., Lu, R., Li, Y., & Xiong, J. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201910716 · Cited by 444
Self-citationLiu, X., Meng, J., Zhu, J., Huang, M., Wen, B., Guo, R., & Mai, L. (2021) · Advanced Materials · doi:10.1002/adma.202007344 · Cited by 438
Wygant, B. R., Kawashima, K., & Mullins, C. B. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01774 · Cited by 435
Karimi-Maleh, H., Yola, M. L., Atar, N., Orooji, Y., Karimi, F., Senthil Kumar, P., Rouhi, J., & Baghayeri, M. (2021) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2021.02.066 · Cited by 404
Metadata
- Authors
- Chen, W., Liu, Y., Li, Y., Sun, J., Qiu, Y., Liu, C., Zhou, G., & Cui, Y.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-01
- Volume
- 16
- Issue
- 12
- Pages
- 7588-7596
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2558970450
- Cited by
- 231
- References
- 17
- FWCI
- 7.87
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chen, W., Liu, Y., Li, Y., Sun, J., Qiu, Y., Liu, C., Zhou, G., & Cui, Y. (2016). In Situ Electrochemically Derived Nanoporous Oxides from Transition Metal Dichalcogenides for Active Oxygen Evolution Catalysts. Nano Letters. https://doi.org/10.1021/acs.nanolett.6b03458
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