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Cited by 936

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Out-of-Plane Piezoelectricity and Ferroelectricity in Layered α-In2Se3 Nanoflakes

Open access
Zhou, Yu, Wu, Di, Zhu, Yihan, Cho, Yujin, He, Qing, Yang, Xiao, Herrera, Kevin, Chu, Zhaodong, Han, Yu, Downer, Michael C., Peng, Hailin, Lai, Keji·2017·Nano Letters

Abstract

Piezoelectric and ferroelectric properties in the two-dimensional (2D) limit are highly desired for nanoelectronic, electromechanical, and optoelectronic applications. Here we report the first experimental evidence of out-of-plane piezoelectricity and ferroelectricity in van der Waals layered α-In 2 Se 3 nanoflakes. The noncentrosymmetric R 3 m symmetry of the α-In 2 Se 3 samples is confirmed by scanning transmission electron microscopy, second-harmonic generation, and Raman spectroscopy measurements. Domains with opposite polarizations are visualized by piezo-response force microscopy. Single-point poling experiments suggest that the polarization is potentially switchable for α-In 2 Se 3 nanoflakes with thicknesses down to ∼10 nm. The piezotronic effect is demonstrated in two-terminal devices, where the Schottky barrier can be modulated by the strain-induced piezopotential. Our work on polar α-In 2 Se 3, one of the model 2D piezoelectrics and ferroelectrics with simple crystal structures, shows its great potential in electronic and photonic applications.

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Metadata

Authors
Zhou, Y., Wu, D., Zhu, Y., Cho, Y., He, Q., Yang, X., Herrera, K., Chu, Z., Han, Y., Downer, M. C., Peng, H., & Lai, K.
Venue
Nano Letters
Published
2017-08-30
Volume
17
Issue
9
Pages
5508-5513
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2747884380
Cited by
936
References
4
FWCI
19.31
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Out-of-Plane Piezoelectricity and Ferroelectricity in Layered α-In2Se3 Nanoflakes. https://app.cochat.ai/papers/10.1021/acs.nanolett.7b02198
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Zhou, Y., Wu, D., Zhu, Y., Cho, Y., He, Q., Yang, X., Herrera, K., Chu, Z., Han, Y., Downer, M. C., Peng, H., & Lai, K. (2017). Out-of-Plane Piezoelectricity and Ferroelectricity in Layered α-In2Se3 Nanoflakes. Nano Letters. https://doi.org/10.1021/acs.nanolett.7b02198

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