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Inorganic–Organic Coating via Molecular Layer Deposition Enables Long Life Sodium Metal Anode
Abstract
Metallic Na anode is considered as a promising alternative candidate for Na ion batteries (NIBs) and Na metal batteries (NMBs) due to its high specific capacity, and low potential. However, the unstable solid electrolyte interphase layer caused by serious corrosion and reaction in electrolyte will lead to big challenges, including dendrite growth, low Coulombic efficiency and even safety issues. In this paper, we first demonstrate the inorganic–organic coating via advanced molecular layer deposition (alucone) as a protective layer for metallic Na anode. By protecting Na anode with controllable alucone layer, the dendrites and mossy Na formation have been effectively suppressed and the lifetime has been significantly improved. Moreover, the molecular layer deposition alucone coating shows better performances than the atomic layer deposition Al 2 O 3 coating. The novel design of molecular layer deposition protected Na metal anode may bring in new opportunities to the realization of the next-generation high energy-density NIBs and NMBs.
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Citations
Cited by
Liu, W., Liu, P., & Mitlin, D. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202002297 · Cited by 687
Na-k liquid alloy: A review on wettability enhancement and ionic carrier selection mechanism
Li, X., Liu, J., Chen, C., Yang, J., Xu, Z., Wu, M., Wang, Y., & Karim, Z. (2021) · Chinese Chemical Letters · doi:10.1016/j.cclet.2020.09.018 · Cited by 12
Metadata
- Authors
- Zhao, Y., Goncharova, L. V., Zhang, Q., Kaghazchi, P., Sun, Q., Lushington, A., Wang, B., Li, R., & Sun, X.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-08-25
- Volume
- 17
- Issue
- 9
- Pages
- 5653-5659
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2750324830
- Cited by
- 284
- References
- 0
- FWCI
- 14.88
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Inorganic–Organic Coating via Molecular Layer Deposition Enables Long Life Sodium Metal Anode. https://app.cochat.ai/papers/10.1021/acs.nanolett.7b02464
- The paper
- Zhao, Y., Goncharova, L. V., Zhang, Q., Kaghazchi, P., Sun, Q., Lushington, A., Wang, B., Li, R., & Sun, X. (2017). Inorganic–Organic Coating via Molecular Layer Deposition Enables Long Life Sodium Metal Anode. Nano Letters. https://doi.org/10.1021/acs.nanolett.7b02464
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