The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Suppressing the Phase Transition of the Layered Ni-Rich Oxide Cathode during High-Voltage Cycling by Introducing Low-Content Li2MnO3
Abstract
The layered Ni-rich oxide cathode (LiNi0.8Co0.1Mn0.1O2) suffers from a tremendous structural degradation during high-voltage cycling (4.8 V), causing the drastic rise of electrode impedance and deterioration of the capacity retention. Here, we develop an effective strategy to overcome these problems of the Ni-rich cathode material through doping low-content Li2MnO3 as an excellent structure stabilizer. Cyclic voltammogram and ex-situ X-ray diffraction measurements have reveled that Li2MnO3 could display a remarkable suppression effect on the phase transition of LiNi0.8Co0.1Mn0.1O2. The electrochemical tests showed that Li2MnO3-stabilized LiNi0.8Co0.1Mn0.1O2 could realize the large reversible capacity, stable discharge voltage and excellent cycling life during high-voltage cycling, which could be benefited from the enhanced structural stability of the modified Ni-rich cathode. The Li2MnO3 could sufficiently suppress the phase transition between two hexagonal phase (H2 and H3) with distinctly different lattice parameters, significantly reducing variation of unit-cell volume, which facilitates stabilization of the original layered structure of LiNi0.8Co0.1Mn0.1O2 cathode during high-voltage cycling.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Challenges for Rechargeable Li Batteries
Goodenough, J. B., & Kim, Y. (2010) · Chemistry of Materials · doi:10.1021/cm901452z · Cited by 10,943
Thackeray, M. M., Wolverton, C., & Isaacs, E. D. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21892e · Cited by 2,515
Noh, H.-J., Youn, S., Yoon, C. S., & Sun, Y.-K. (2013) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.01.063 · Cited by 2,302
Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries
Thackeray, M. M., Kang, S.-H., Johnson, C. S., Vaughey, J. T., Benedek, R., & Hackney, S. A. (2007) · Journal of Materials Chemistry · doi:10.1039/b702425h · Cited by 2,039
Lin, F., Markus, I. M., Nordlund, D., Weng, T.-C., Asta, M. D., Xin, H. L., & Doeff, M. M. (2014) · Nature Communications · doi:10.1038/ncomms4529 · Cited by 1,481
Electrochemistry and Structural Chemistry of LiNiO2 (R3m) for 4 Volt Secondary Lithium Cells
Ohzuku, T., Ueda, A., & Nagayama, M. (1993) · Journal of The Electrochemical Society · doi:10.1149/1.2220730 · Cited by 1,384
Jung, S., Gwon, H., Hong, J., Park, K., Seo, D., Kim, H., Hyun, J., Yang, W., & Kang, K. (2014) · Advanced Energy Materials · doi:10.1002/aenm.201300787 · Cited by 1,124
Bak, S.-M., Hu, E., Zhou, Y., Yu, X., Senanayake, S. D., Cho, S.-J., Kim, K.-B., Chung, K. Y., Yang, X.-Q., & Nam, K.-W. (2014) · ACS Applied Materials & Interfaces · doi:10.1021/am506712c · Cited by 1,010
Novel lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for advanced lithium-ion batteries
Yabuuchi, N., & Ohzuku, T. (2003) · Journal of Power Sources · doi:10.1016/s0378-7753(03)00173-3 · Cited by 870
In situ x-ray diffraction and electrochemical studies of Li1−xNiO2
LI, W., Reimers, J. N., & Dahn, J. R. (1993) · Solid State Ionics · doi:10.1016/0167-2738(93)90317-v · Cited by 745
Nam, K., Bak, S., Hu, E., Yu, X., Zhou, Y., Wang, X., Wu, L., Zhu, Y., Chung, K. Y., & Yang, X. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201200693 · Cited by 594
Mohanty, D., Kalnaus, S., Meisner, R. A., Rhodes, K. J., Li, J., Payzant, E. A., Wood, D. L., & Daniel, C. (2012) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.11.144 · Cited by 531
Kim, H., Kim, M. G., Jeong, H. Y., Nam, H., & Cho, J. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b00045 · Cited by 526
Cho, Y., Oh, P., & Cho, J. (2013) · Nano Letters · doi:10.1021/nl304558t · Cited by 501
Structural and Chemical Evolution of Li- and Mn-Rich Layered Cathode Material
Zheng, J., Xu, P., Gu, M., Xiao, J., Browning, N. D., Yan, P., Wang, C., & Zhang, J.-G. (2015) · Chemistry of Materials · doi:10.1021/cm5045978 · Cited by 405
Bak, S.-M., Nam, K.-W., Chang, W., Yu, X., Hu, E., Hwang, S., Stach, E. A., Kim, K.-B., Chung, K. Y., & Yang, X.-Q. (2013) · Chemistry of Materials · doi:10.1021/cm303096e · Cited by 390
Yabuuchi, N., Makimura, Y., & Ohzuku, T. (2007) · Journal of The Electrochemical Society · doi:10.1149/1.2455585 · Cited by 387
Hwang, S., Chang, W., Kim, S. M., Su, D., Kim, D. H., Lee, J. Y., Chung, K. Y., & Stach, E. A. (2014) · Chemistry of Materials · doi:10.1021/cm403332s · Cited by 346
Wu, L., Nam, K.-W., Wang, X., Zhou, Y., Zheng, J.-C., Yang, X.-Q., & Zhu, Y. (2011) · Chemistry of Materials · doi:10.1021/cm201452q · Cited by 245
Wang, Y., Jiang, J., & Dahn, J. R. (2007) · Electrochemistry Communications · doi:10.1016/j.elecom.2007.07.033 · Cited by 231
Capacity-Fading Mechanisms of LiNiO[sub 2]-Based Lithium-Ion Batteries
Muto, S., Sasano, Y., Tatsumi, K., Sasaki, T., Horibuchi, K., Takeuchi, Y., & Ukyo, Y. (2009) · Journal of The Electrochemical Society · doi:10.1149/1.3076137 · Cited by 212
On electrochemical impedance measurements of LixCo0.2Ni0.8O2 and LixNiO2 intercalation electrodes
Levi, M. D., Gamolsky, K., Aurbach, D., et al. (2000) · Electrochimica Acta · doi:10.1016/s0013-4686(99)00402-8 · Cited by 209
Comparison of the chemical stability of the high energy density cathodes of lithium-ion batteries
Chebiam, R. V., Kannan, A. M., Prado, F., & Manthiram, A. (2001) · Electrochemistry Communications · doi:10.1016/s1388-2481(01)00232-6 · Cited by 181
Liu, J., Hou, M., Jin, Y., Guo, S., Wang, C., & Xia, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee41664j · Cited by 151
Self-citationMyung, S., Komaba, S., Hosoya, K., Hirosaki, N., Miura, Y., & Kumagai, N. (2005) · Chemistry of Materials · doi:10.1021/cm050033j · Cited by 88
Konishi, H., Yuasa, T., & Yoshikawa, M. (2011) · Journal of Power Sources · doi:10.1016/j.jpowsour.2011.01.016 · Cited by 87
Cited by
Maleki Kheimeh Sari, H., & Li, X. (2019) · Advanced Energy Materials · doi:10.1002/aenm.201901597 · Cited by 403
Holoubek, J., Yu, M., Yu, S., Li, M., Wu, Z., Xia, D., Bhaladhare, P., Gonzalez, M. S., Pascal, T. A., Liu, P., et al. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c00643 · Cited by 351
Advances in Structure and Property Optimizations of Battery Electrode Materials
Meng, J., Guo, H., Niu, C., Zhao, Y., Xu, L., Li, Q., & Mai, L. (2017) · Joule · doi:10.1016/j.joule.2017.08.001 · Cited by 312
Dixit, M., Markovsky, B., Schipper, F., Aurbach, D., & Major, D. T. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b06122 · Cited by 309
Metadata
- Authors
- Yang, J., & Xia, Y.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-01-05
- Volume
- 8
- Issue
- 2
- Pages
- 1297-1308
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2337376462
- Cited by
- 334
- References
- 27
- FWCI
- 8.98
- Type
- journal article
- Language
- en
- Open access
- closed
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