The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
Large-Scale Self-Assembly of 3D Flower-like Hierarchical Ni/Co-LDHs Microspheres for High-Performance Flexible Asymmetric Supercapacitors
Abstract
In this study, a facile and inexpensive and self-assembled strategy to massively fabricate Ni/Co layered double hydroxides (LDHs) is developed under mild reaction conditions (55 °C). The resulting composite material displays a special three-dimensional hierarchical microsphere structure with well-defined flower-like configuration. The fabrication mechanism can be ascribed to stepwise and regular reaction process of nanoparticles and nanosheets gradually growing to nanopetals and then assembling into flower-like microspheres, based on the systematically investigation of various reaction factors including the Ni:Co feeding ratio, the reaction time and the initial pH-value. Because of its large surface, ultrathin feature and synergetic results of this Ni/Co LDHs nanosheets (20 nm), these Ni/Co-LDHs microspheres deliver an excellent capacitance value about 2228 F·g(-1) (1 A·g(-1)). An all-solid-state flexible asymmetric supercapacitor is designed and assembled by exploiting this Ni/Co-LDHs as the positive materials, which exhibits energy density of 165.51 Wh·kg(1-) at 1.53 KW·kg(1-). It may have vast potential significance in personal wearable equipment. Moreover, this monolithic design provides a promising approach for large scale fabrication of other LDHs materials.
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Metadata
- Authors
- Li, T., Li, G. H., Li, L. H., Liu, L., Xu, Y., Ding, H. Y., & Zhang, T.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-01-21
- Volume
- 8
- Issue
- 4
- Pages
- 2562-2572
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2239711857
- Cited by
- 284
- References
- 36
- FWCI
- 11.55
- Type
- journal article
- Language
- en
- Open access
- closed
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