Cited by 99Supercapacitor Materials and FabricationConducting polymers and applicationsAerogels and thermal insulation

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Biomass-Based Mechanically Strong and Electrically Conductive Polymer Aerogels and Their Application for Supercapacitors

Zhao, Hai-Bo, Yuan, Lei, Fu, Zhi-Bing, Wang, Chao-Yang, Yang, Xi, Zhu, Jia-Yi, Qu, Jing, Chen, Hong-Bing, Schiraldi, David A.·2016·ACS Applied Materials & Interfaces

Abstract

A novel biomass-based mechanically strong and electrically conductive polymer aerogel was fabricated from aniline and biodegradable pectin. The strong hydrogen bonding interactions between polyaniline (PANI) and pectin resulted in a defined structure and enhanced properties of the aerogel. All the resultant aerogels exhibited self-surppoted 3D nanoporous network structures with high surface areas (207-331m(2)/g) and hierarchical pores. The results from electrical conductivity measurements and compressive tests revealed that these aerogels also had favorable conductivities (0.002-0.1 S/m) and good compressive modulus (1.2-1.4 MPa). The aerogel further used as electrode for supercapacitors showed enhanced capacitive performance (184 F/g at 0.5 A/g). Over 74% of the initial capacitance was maintained after repeating 1000 cycles of the cylic voltammetry test, while the capacitance retention of PANI was only 57%. The improved electrochemical performance may be attributed to the combinative properties of good electrical conductivity, BET surface areas, and stable nanoporous structure of the aerogel. Thus, this aerogel shows great potential as electrode materials for supercapacitors.

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Metadata

Authors
Zhao, H.-B., Yuan, L., Fu, Z.-B., Wang, C.-Y., Yang, X., Zhu, J.-Y., Qu, J., Chen, H.-B., & Schiraldi, D. A.
Affiliations
  • Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang, Sichuan, 621000, China
  • China Academy of Engineering Physics (CN)
  • Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang, Sichuan, 621000, China
  • Case Western Reserve University (US)
Corresponding author
Schiraldi, David A.
Venue
ACS Applied Materials & Interfaces
Published
2016-04-08
Volume
8
Issue
15
Pages
9917-9924
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2317426766
Cited by
99
References
1
Citations by year
2026: 6 · 2025: 11 · 2024: 9 · 2023: 7 · 2022: 11 · 2021: 6 · 2020: 12 · 2019: 13 · 2018: 11 · 2017: 11 · 2016: 2
FWCI
3.87
Type
journal article
Language
en
Open access
closed
Locations
  • ACS Applied Materials & Interfaces (publishedVersion)
  • PubMed (publishedVersion)
Funders
  • Ministry of Science and Technology of the People's Republic of China (2013AA050905)
  • National Natural Science Foundation of China (51403192, 51502274, 51503191)
  • China Academy of Engineering Physics (2013CX04)
Topics
  • Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
  • Physical Sciences › Materials Science › Polymers and Plastics › Conducting polymers and applications
  • Physical Sciences › Materials Science › Materials Chemistry › Aerogels and thermal insulation
Keywords
polymer aerogels, biomass-derived materials, polyaniline, pectin, supercapacitor electrodes, hydrogen bonding, electrical conductivity, compressive modulus, specific capacitance, cycling stability, biodegradable electrodes

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CoChat. (2026). Citation check: Biomass-Based Mechanically Strong and Electrically Conductive Polymer Aerogels and Their Application for Supercapacitors. https://app.cochat.ai/papers/10.1021/acsami.6b00510
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Zhao, H.-B., Yuan, L., Fu, Z.-B., Wang, C.-Y., Yang, X., Zhu, J.-Y., Qu, J., Chen, H.-B., & Schiraldi, D. A. (2016). Biomass-Based Mechanically Strong and Electrically Conductive Polymer Aerogels and Their Application for Supercapacitors. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b00510