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Cited by 473

The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.

A Prussian Blue/Zinc Secondary Battery with a Bio-Ionic Liquid–Water Mixture as Electrolyte

Liu, Zhen, Pulletikurthi, Giridhar, Endres, Frank·2016·ACS Applied Materials & Interfaces

Abstract

The development of rechargeable zinc ion batteries with high capacity and high cycling stability is a great challenge in aqueous solution due to hydrogen evolution and dendritic growth of zinc. In this study, we present a zinc ion secondary battery, comprising a metallic zinc anode, a bio-ionic liquid-water electrolyte, and a nanostructured prussian blue analogue (PBA) cathode. Both the Zn anode and the PBA cathode exhibit good compatibility with the bio-ionic liquid-water electrolyte, which enables the electrochemical deposition/dissolution of zinc at the zinc anode, and reversible insertion/extraction of Zn(2+) ions at the PBA cathode. The cell exhibits a well-defined discharge voltage plateau of ∼1.1 V with a specific capacity of about 120 mAh g(-1) at a current of 10 mA g(-1) (∼0.1 C). The Zn anode shows great reversibility, and dendrite-free Zn deposits were obtained after 100 deposition/dissolution cycles. The integration of an environmentally friendly PBA cathode, a nontoxic and low-cost Zn anode, and a biodegradable ionic liquid-water electrolyte provides new perspective to develop rechargeable zinc ion batteries for various applications in electric energy storage.

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Metadata

Authors
Liu, Z., Pulletikurthi, G., & Endres, F.
Venue
ACS Applied Materials & Interfaces
Published
2016-05-04
Volume
8
Issue
19
Pages
12158-12164
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2343457385
Cited by
473
References
36
FWCI
16.77
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A Prussian Blue/Zinc Secondary Battery with a Bio-Ionic Liquid–Water Mixture as Electrolyte. https://app.cochat.ai/papers/10.1021/acsami.6b01592
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Liu, Z., Pulletikurthi, G., & Endres, F. (2016). A Prussian Blue/Zinc Secondary Battery with a Bio-Ionic Liquid–Water Mixture as Electrolyte. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b01592

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