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Cited by 239

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Two-Dimensional Titanium Carbide MXene As a Cathode Material for Hybrid Magnesium/Lithium-Ion Batteries

Byeon, Ayeong, Zhao, Meng-Qiang, Ren, Chang E., Halim, Joseph, Kota, Sankalp, Urbankowski, Patrick, Anasori, Babak, Barsoum, Michel W., Gogotsi, Yury·2017·ACS Applied Materials & Interfaces

Abstract

As an alternative to pure lithium-ion, Li +, systems, a hybrid magnesium, Mg 2+, and Li + battery can potentially combine the high capacity, high voltage, and fast Li + intercalation of Li-ion battery cathodes and the high capacity, low cost, and dendrite-free Mg metal anodes. Herein, we report on the use of two-dimensional titanium carbide, Ti 3 C 2 T x (MXene), as a cathode in hybrid Mg 2+ /Li + batteries, coupled with a Mg metal anode. Free-standing and flexible Ti 3 C 2 T x /carbon nanotube composite “paper” delivered ∼100 mAh g –1 at 0.1 C and ∼50 mAh g –1 at 10 C . At 1 C the capacity was maintained for >500 cycles at 80 mAh g –1 . The Mo 2 CT x MXene also demonstrated good performance as a cathode material in this hybrid battery. Considering the variety of available MXenes, this work opens the door for exploring a new large family of 2D materials with high electrical conductivity and large intercalation capacity as cathodes for hybrid Mg 2+ /Li + batteries.

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Crossref · 10.1021/acsami.6b04198

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Metadata

Authors
Byeon, A., Zhao, M.-Q., Ren, C. E., Halim, J., Kota, S., Urbankowski, P., Anasori, B., Barsoum, M. W., & Gogotsi, Y.
Venue
ACS Applied Materials & Interfaces
Published
2016-06-08
Volume
9
Issue
5
Pages
4296-4300
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2417108421
Cited by
239
References
2
FWCI
10.19
Type
journal article
Language
en
Open access
closed

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