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Co3O4–CeO2/C as a Highly Active Electrocatalyst for Oxygen Reduction Reaction in Al–Air Batteries

Liu, Kun, Huang, Xiaobing, Wang, Haiyan, Li, Fuzhi, Tang, Yougen, Li, Jingsha, Shao, Minhua·2016·ACS Applied Materials & Interfaces

Abstract

Developing high-performance and low-cost electrocatalysts for oxygen reduction reaction (ORR) is still a great challenge for Al–air batteries. Herein, CeO 2, a unique ORR promoter, was incorporated into ketjenblack (KB) supported Co 3 O 4 catalyst. We developed a facile two-step hydrothermal approach to fabricate Co 3 O 4 –CeO 2 /KB as a high-performance ORR catalyst for Al–air batteries. The ORR activity of Co 3 O 4 /KB was significantly increased by mixing with CeO 2 nanoparticles. In addition, the Co 3 O 4 –CeO 2 /KB showed a better electrocatalytic performance and stability than 20 wt % Pt/C in alkaline electrolytes, making it a good candidate for highly active ORR catalysts. Co 3 O 4 –CeO 2 /KB favored a four-electron pathway in ORR due to the synergistic interactions between CeO 2 and Co 3 O 4 . In full cell tests, the Co 3 O 4 –CeO 2 /KB exhibited a higher discharge voltage plateau than CeO 2 /KB and Co 3 O 4 /KB when used in cathode in Al–air batteries.

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Metadata

Authors
Liu, K., Huang, X., Wang, H., Li, F., Tang, Y., Li, J., & Shao, M.
Venue
ACS Applied Materials & Interfaces
Published
2016-12-08
Volume
8
Issue
50
Pages
34422-34430
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2557985720
Cited by
185
References
2
FWCI
5.36
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Co3O4–CeO2/C as a Highly Active Electrocatalyst for Oxygen Reduction Reaction in Al–Air Batteries. https://app.cochat.ai/papers/10.1021/acsami.6b12294
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Liu, K., Huang, X., Wang, H., Li, F., Tang, Y., Li, J., & Shao, M. (2016). Co3O4–CeO2/C as a Highly Active Electrocatalyst for Oxygen Reduction Reaction in Al–Air Batteries. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b12294

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