Aluminum–air battery based on an ionic liquid electrolyte
Abstract
This study presents a novel non-aqueous Al–air battery utilizing 1-ethyl-3-methylimidazolium oligo-fluoro-hydrogenate room temperature ionic liquid. The Al–air-RTIL system can sustain current densities up to 1.5 mA cm −2 , producing capacities above 140 mA h cm −2 , thus utilizing above 70% of the theoretical Al capacity.
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Aluminum-air batteries reach very large energy densities, attaining 6.2 kWh/L, which allows high autonomies up to 1600 km.
“Their main advantage is that this type of battery reaches very large energy densities, attaining 6.2 kWh/L [103], which allows obtaining a high autonomies (up to 1600 km) [104].”
From A Review on Electric Vehicles: Technologies and Challenges (2021) · cites this paper as [103]
Cites
Ionic-liquid materials for the electrochemical challenges of the future
Armand, M. B., Endres, F., MacFarlane, D. R., Ohno, H., & Scrosati, B. (2009) · Nature Materials · doi:10.1038/nmat2448 · Cited by 4,616 · see citing works
Lithium−Air Battery: Promise and Challenges
Girishkumar, G., McCloskey, B. D., Luntz, A. C., Swanson, S. A., & Wilcke, W. W. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1005384 · Cited by 2,528 · see citing works
The rechargeable aluminum-ion battery
Jayaprakash, N., Das, S. K., & Archer, L. A. (2011) · Chemical Communications · doi:10.1039/c1cc15779e · Cited by 750 · see citing works
Aluminum as anode for energy storage and conversion: a review
Li, Q., & Bjerrum, N. J. (2002) · Journal of Power Sources · doi:10.1016/s0378-7753(01)01014-x · Cited by 675 · see citing works
Review on Li–air batteries—Opportunities, limitations and perspective
Kraytsberg, A., & Ein‐Eli, Y. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2010.09.031 · Cited by 574 · see citing works
Self-citationAluminum as anode for energy storage and conversion: a review
(2003) · Fuel and Energy Abstracts · doi:10.1016/s0140-6701(03)82893-x · Cited by 479 · see citing works
Polymer electrolytes: Present, past and future
Noto, V. D., Lavina, S., Giffin, G. A., et al. (2011) · Electrochimica Acta · doi:10.1016/j.electacta.2011.08.048 · Cited by 475 · see citing works
Developments in electrode materials and electrolytes for aluminium–air batteries
Egan, D. R. P., de León, C. P., Wood, R. J. K., Jones, R. L., Stokes, K. R., & Walsh, F. C. (2013) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.01.141 · Cited by 466 · see citing works
Lithium-air batteries using hydrophobic room temperature ionic liquid electrolyte
Kuboki, T., Okuyama, T., Ohsaki, T., & Takami, N. (2005) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.03.082 · Cited by 445 · see citing works
Jiang, T., Brym, M. J. C., Dubé, G., et al. (2006) · Surface and Coatings Technology · doi:10.1016/j.surfcoat.2005.10.046 · Cited by 364 · see citing works
Metal–Organic Frameworks as Cathode Materials for Li–O 2 Batteries
Wu, D., Guo, Z., Yin, X., Pang, Q., Tu, B., Zhang, L., Wang, Y., & Li, Q. (2014) · Advanced Materials · doi:10.1002/adma.201305492 · Cited by 336 · see citing works
Wang, W. A., Jiang, B., Xiong, W., Sun, H., Lin, Z., Hu, L., Tu, J., Hou, J., Zhu, H., & Jiao, S. (2013) · Scientific Reports · doi:10.1038/srep03383 · Cited by 336 · see citing works
Design and analysis of aluminum/air battery system for electric vehicles
Yang, S. (2002) · Journal of Power Sources · doi:10.1016/s0378-7753(02)00370-1 · Cited by 303 · see citing works
Fluorinated Natural Graphite Cathode for Rechargeable Ionic Liquid Based Aluminum–Ion Battery
Rani, J. V., Kanakaiah, V., Dadmal, T. L., et al. (2013) · Journal of The Electrochemical Society · doi:10.1149/2.072310jes · Cited by 234 · see citing works
Abedin, S. Z. E., Moustafa, E. B., Hempelmann, R., Natter, H., & Endres, F. (2006) · ChemPhysChem · doi:10.1002/cphc.200600095 · Cited by 223 · see citing works
Zhao, Y., & VanderNoot, T. J. (1997) · Electrochimica Acta · doi:10.1016/0013-4686(96)00080-1 · Cited by 220 · see citing works
Choi, R., Jung, J., Kim, G., et al. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43437k · Cited by 214 · see citing works
A Highly Conductive Room Temperature Molten Fluoride: EMIF⋅2.3HF
Hagiwara, R., Hirashige, T., Tsuda, T., & Ito, Y. (2002) · Journal of The Electrochemical Society · doi:10.1149/1.1421606 · Cited by 169 · see citing works
Li, F., Chen, Y., Tang, D., et al. (2014) · Energy & Environmental Science · doi:10.1039/c3ee44043e · Cited by 166 · see citing works
Electrochemical behaviour of aluminium in concentrated NaOH solutions
Doche, M., Rameau, J. J., Durand, R., et al. (1999) · Corrosion Science · doi:10.1016/s0010-938x(98)00107-3 · Cited by 148 · see citing works
Li‐O2 Battery Based on Highly Efficient Sb‐Doped Tin Oxide Supported Ru Nanoparticles
Li, F., Tang, D., Jian, Z., et al. (2014) · Advanced Materials · doi:10.1002/adma.201400162 · Cited by 139 · see citing works
A Fluorohydrogenate Ionic Liquid Fuel Cell Operating Without Humidification
Hagiwara, R., Nohira, T., Matsumoto, K., & Tamba, Y. (2005) · Electrochemical and Solid-State Letters · doi:10.1149/1.1870672 · Cited by 105 · see citing works
Cohn, G., Starosvetsky, D., Hagiwara, R., et al. (2009) · Electrochemistry Communications · doi:10.1016/j.elecom.2009.08.015 · Cited by 95 · see citing works
Copper corrosion mitigation by binary inhibitor compositions of potassium sorbate and benzotriazole
Gelman, D. M., Starosvetsky, D., & Ein‐Eli, Y. (2014) · Corrosion Science · doi:10.1016/j.corsci.2014.01.028 · Cited by 85 · see citing works
Self-citationStudy and development of non-aqueous silicon-air battery
Cohn, G., & Ein‐Eli, Y. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2010.02.070 · Cited by 77 · see citing works
Self-citationNoto, V. D., Piga, M., Giffin, G. A., et al. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp204242q · Cited by 58 · see citing works
Remarkable Impact of Water on the Discharge Performance of a Silicon–Air Battery
Cohn, G., Macdonald, D. D., & Ein‐Eli, Y. (2011) · ChemSusChem · doi:10.1002/cssc.201100169 · Cited by 44 · see citing works
Self-citationCorrosion and electrochemical behaviors of pure aluminum in novel KOH‐ionic liquid‐water solutions
Wang, J. M., Wang, J. M., Wang, J. B., et al. (2009) · Materials and Corrosion · doi:10.1002/maco.200905238 · Cited by 34 · see citing works
Noto, V. D., Piga, M., Giffin, G. A., et al. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp204241y · Cited by 34 · see citing works
中性化ナフィオン117,トリエチルアンモニウムメタンスルホン酸,およびトリエチルアンモニウムペルフルオロブタンスルホン酸に基づくプロトン導電膜に及ぼすアニオンの影響,2 電気特性
Vito, D. N., Matteo, P., Guinevere, A. G., et al. (2012) · The Journal of Physical Chemistry C · Cited by 33 · see citing works
Enhanced Inhibition of Zinc Corrosion in Alkaline Solutions Containing Carboxylic Acid Modified PEG
Auinat, M., & Ein‐Eli, Y. (2005) · Journal of The Electrochemical Society · doi:10.1149/1.1900963 · Cited by 28 · see citing works
Self-citationThe effect of water on the anodic dissolution of aluminum in non-aqueous electrolytes
Licht, S. L., Levitin, G., Tel‐Vered, R., et al. (2000) · Electrochemistry Communications · doi:10.1016/s1388-2481(00)00034-5 · Cited by 24 · see citing works
Chemistry in heterocyclic ammonium fluorohydrogenate room-temperature ionic liquid
Tsuda, T., & Hagiwara, R. (2007) · Journal of Fluorine Chemistry · doi:10.1016/j.jfluchem.2007.10.004 · Cited by 23 · see citing works
Shvartsev, B., Cohn, G., Shasha, H., et al. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp52661e · Cited by 18 · see citing works
Self-citationPolarization Admittance Study of Lithium Corrosion in Propylene Carbonate Solutions
Cessna, J. C. (1971) · CORROSION · doi:10.5006/0010-9312-27.6.244 · Cited by 11 · see citing works
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A Review on Electric Vehicles: Technologies and Challenges
Sanguesa, J. A., Torres-Sanz, V., Garrido, P., Martinez, F. J., & Marquez-Barja, J. M. (2021) · Smart Cities · doi:10.3390/smartcities4010022 · Cited by 1,367 · see citing works
- Authors
- Gelman, D., Shvartsev, B., & Ein-Eli, Y.
- Affiliations
- Technion – Israel Institute of Technology (IL)
- The Nancy and Stephen Grand Technion Energy Program
- Venue
- J. Mater. Chem. A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 2
- Issue
- 47
- Pages
- 20237-20242
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W2136385640
- Cited by
- 164
- References
- 35
- Citations by year
- 2026: 9 · 2025: 11 · 2024: 18 · 2023: 14 · 2022: 13 · 2021: 18 · 2020: 20 · 2019: 12 · 2018: 18 · 2017: 13 · 2016: 14 · 2015: 4
- FWCI
- 5.49
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry A (publishedVersion)
- Funders
- Nancy and Stephen Grand Technion Energy Program
- Israel Science Foundation
- Technion-Israel Institute of Technology
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced battery technologies research
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Keywords
- aluminum-air batteries, ionic liquid electrolyte, room temperature ionic liquids, 1-ethyl-3-methylimidazolium, non-aqueous electrolytes, current density, energy density
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