The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
MOF-Derived Noble Metal Free Catalysts for Electrochemical Water Splitting
Abstract
Noble metal free electrocatalysts for water splitting are key to low-cost, sustainable hydrogen production. In this work, we demonstrate that metal–organic frameworks (MOFs) can be controllably converted into catalysts for the oxygen evolution reaction (OER) or the hydrogen evolution reaction (HER). The OER catalyst is composed of FeNi alloy nanoparticles encapsulated in N-doped carbon nanotubes, which is obtained by thermal decomposition of a trimetallic (Zn 2+, Fe 2+, and Ni 2+ ) zeolitic imidazolate framework (ZIF). It reaches 10 mA cm –2 at the overpotential of 300 mV with a low Tafel slope of 47.7 mV dec –1 . The HER catalyst consists of Ni nanoparticles coated with a thin layer of N-doped carbon. It is obtained by thermal decomposition of a Ni-MOF in NH 3 . It shows low overpotential of only 77 mV at 20 mA cm –2 with low Tafel slope of 68 mV dec –1 . The above noble metal free OER and HER electrocatalysts are applied in an alkaline electrolyzer driven by a commercial polycrystalline solar cell. It achieves electrolysis efficiency of 64.4% at 65 mA cm –2 under sun irradiation of 50 mW cm –2 . This practical application shows the promising prospect of low-cost and high-efficiency sustainable hydrogen production from combination of solar cells with high-performance noble metal free electrocatalysts.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
McCrory, C. C. L., Jung, S., Ferrer, I. M., Chatman, S. M., Peters, J. C., & Jaramillo, T. F. (2015) · Journal of the American Chemical Society · doi:10.1021/ja510442p · Cited by 4,145
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Sheng, W., Myint, M., Chen, J. G., & Yan, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00045a · Cited by 1,202
Zou, X., Huang, X., Goswami, A., Silva, R., Sathe, B. R., Mikmeková, E., & Asefa, T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201311111 · Cited by 979
Cui, X., Ren, P., Deng, D., Deng, J., & Bao, X. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03316k · Cited by 791
Electrocatalytic H 2 production from seawater over Co, N-codoped nanocarbons
Gao, S., Li, G.-D., Liu, Y., Chen, H., Feng, L.-L., Wang, Y., Yang, M., Wang, D., Wang, S., & Zou, X. (2015) · Nanoscale · doi:10.1039/c4nr04924a · Cited by 180
Cited by
Design Strategies toward Advanced MOF‐Derived Electrocatalysts for Energy‐Conversion Reactions
Liu, J., Zhu, D., Guo, C., Vasileff, A., & Qiao, S. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700518 · Cited by 668
Fe-Based Electrocatalysts for Oxygen Evolution Reaction: Progress and Perspectives
Feng, C., Faheem, M. B., Fu, J., Xiao, Y., Li, C., & Li, Y. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05445 · Cited by 587
Liang, X., Zheng, B., Chen, L., Zhang, J., Zhuang, Z., & Chen, B. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b06152 · Cited by 328
Metadata
- Authors
- Tao, Z., Wang, T., Wang, X., Zheng, J., & Li, X.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-14
- Volume
- 8
- Issue
- 51
- Pages
- 35390-35397
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2558691935
- Cited by
- 193
- References
- 9
- FWCI
- 4.20
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: MOF-Derived Noble Metal Free Catalysts for Electrochemical Water Splitting. https://app.cochat.ai/papers/10.1021/acsami.6b13411
- The paper
- Tao, Z., Wang, T., Wang, X., Zheng, J., & Li, X. (2016). MOF-Derived Noble Metal Free Catalysts for Electrochemical Water Splitting. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.6b13411
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
