The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
MOF-Derived Formation of Ni2P–CoP Bimetallic Phosphides with Strong Interfacial Effect toward Electrocatalytic Water Splitting
Abstract
Bimetallic phosphides have attracted research interest for their synergistic effect and superior electrocatalytic activities for electrocatalytic water splitting. Herein, a MOF-derived phosphorization approach was developed to produce Ni 2 P–CoP bimetallic phosphides as bifunctional electrocatalysts for both hydrogen and oxygen evolution reactions (HER and OER). Ni 2 P–CoP shows superior electrocatalytic activities to both pure Ni 2 P and CoP toward HER and OER, revealing a strong synergistic effect. High-resolution transmission electron microscopy and energy dispersive X-ray spectroscopy elemental mapping analysis show that, in the sample Ni 2 P–CoP, the Ni 2 P and CoP nanoparticles with an average particle size 10–20 nm were mixed closely on the nanoscale, creating numerous Ni 2 P/CoP interfaces. By comparison with the sample Ni 2 P+CoP, in which seldom Ni 2 P/CoP interfaces exist, we documented that the Ni 2 P/CoP interface is an essential prerequisite to realize the synergistic effect and to achieve the enhanced electrocatalytic activities in Ni 2 P–CoP bimetallic phosphides. This finding is meaningful for designing and developing bicomponent and even multicomponent electrocatalysts.
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Cited by
Riyajuddin, S., Azmi, K., Pahuja, M., Kumar, S., Maruyama, T., Bera, C., & Ghosh, K. (2021) · ACS Nano · doi:10.1021/acsnano.1c00647 · Cited by 353
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Recent advances in cobalt based heterogeneous catalysts for oxygen evolution reaction
Badruzzaman, A., Yuda, A., Ashok, A., & Kumar, A. (2020) · Inorganica Chimica Acta · doi:10.1016/j.ica.2020.119854 · Cited by 105
In-situ synthesis of porous Ni2P nanosheets for efficient and stable hydrogen evolution reaction
Jin, X., Li, J., Cui, Y., Liu, X., Wang, K., Zhou, Y., Yang, W., Zhang, X., Zhang, C., Jiang, X., et al. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.01.042 · Cited by 69
Wei, Q., Qiu, S., Yin, C., Liu, J., Xia, Y., Wen, X., Zou, Y., Xu, F., Sun, L., & Chu, H. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.166207 · Cited by 55
Metadata
- Authors
- Liang, X., Zheng, B., Chen, L., Zhang, J., Zhuang, Z., & Chen, B.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-06-26
- Volume
- 9
- Issue
- 27
- Pages
- 23222-23229
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W2626292333
- Cited by
- 328
- References
- 32
- FWCI
- 9.61
- Type
- journal article
- Language
- en
- Open access
- closed
- Funders
- National Natural Science Foundation of China (21476012, 21571012, 91534201)
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- Liang, X., Zheng, B., Chen, L., Zhang, J., Zhuang, Z., & Chen, B. (2017). MOF-Derived Formation of Ni2P–CoP Bimetallic Phosphides with Strong Interfacial Effect toward Electrocatalytic Water Splitting. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.7b06152
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