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MOFabric: Electrospun Nanofiber Mats from PVDF/UiO-66-NH2 for Chemical Protection and Decontamination

Lu, Annie Xi, McEntee, Monica, Browe, Matthew A., Hall, Morgan G., DeCoste, Jared B., Peterson, Gregory W.·2017·ACS Applied Materials & Interfaces

Abstract

Textiles capable of capture and detoxification of toxic chemicals, such as chemical-warfare agents (CWAs), are of high interest. Some metal–organic frameworks (MOFs) exhibit superior reactivity toward CWAs. However, it remains a challenge to integrate powder MOFs into engineered materials like textiles, while retaining functionalities like crystallinity, adsorptivity, and reactivity. Here, we present a simple method of electrospinning UiO-66-NH 2, a zirconium MOF, with polyvinylidene fluoride (PVDF). The electrospun composite, which we refer to as “MOFabric”, exhibits comparable crystal patterns, surface area, chlorine uptake, and simulant hydrolysis to powder UiO-66-NH 2 . The MOFabric is also capable of breaking down GD ( O -pinacolyl methylphosphonofluoridae) faster than powder UiO-66-NH 2. Half-life of GD monitored by solid-state NMR for MOFabric is 131 min versus 315 min on powder UiO-66-NH 2 .

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Metadata

Authors
Lu, A. X., McEntee, M., Browe, M. A., Hall, M. G., DeCoste, J. B., & Peterson, G. W.
Venue
ACS Applied Materials & Interfaces
Published
2017-04-05
Volume
9
Issue
15
Pages
13632-13636
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2600235025
Cited by
251
References
0
FWCI
9.23
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: MOFabric: Electrospun Nanofiber Mats from PVDF/UiO-66-NH2 for Chemical Protection and Decontamination. https://app.cochat.ai/papers/10.1021/acsami.7b01621
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Lu, A. X., McEntee, M., Browe, M. A., Hall, M. G., DeCoste, J. B., & Peterson, G. W. (2017). MOFabric: Electrospun Nanofiber Mats from PVDF/UiO-66-NH2 for Chemical Protection and Decontamination. ACS Applied Materials & Interfaces. https://doi.org/10.1021/acsami.7b01621

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