The DOI matches its Crossref record; 186 of the 186 references it cites were found in a registry or an index.
MOF-Polymer Hybrid Materials: From Simple Composites to Tailored Architectures
Open accessAbstract
Metal-organic frameworks (MOFs) are inherently crystalline, brittle porous solids. Conversely, polymers are flexible, malleable, and processable solids that are used for a broad range of commonly used technologies. The stark differences between the nature of MOFs and polymers has motivated efforts to hybridize crystalline MOFs and flexible polymers to produce composites that retain the desired properties of these disparate materials. Importantly, studies have shown that MOFs can be used to influence polymer structure, and polymers can be used to modulate MOF growth and characteristics. In this Review, we highlight the development and recent advances in the synthesis of MOF-polymer mixed-matrix membranes (MMMs) and applications of these MMMs in gas and liquid separations and purifications, including aqueous applications such as dye removal, toxic heavy metal sequestration, and desalination. Other elegant ways of synthesizing MOF-polymer hybrid materials, such as grafting polymers to and from MOFs, polymerization of polymers within MOFs, using polymers to template MOFs, and the bottom-up synthesis of polyMOFs and polyMOPs are also discussed. This review highlights recent papers in the advancement of MOF-polymer hybrid materials, as well as seminal reports that significantly advanced the field.
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Cited by
Metal–Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications
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UiO-66 metal–organic frameworks in water treatment: A critical review
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Non-carbon-supported single-atom site catalysts for electrocatalysis
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Metadata
- Authors
- Kalaj, M., Bentz, K. C., Ayala, S., Palomba, J. M., Barcus, K. S., Katayama, Y., & Cohen, S. M.
- Venue
- Chemical Reviews
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-01-02
- Volume
- 120
- Issue
- 16
- Pages
- 8267-8302
- ISSN
- 0009-2665 (ISSN-L)
- 1520-6890
- OpenAlex
- W2998095377
- Cited by
- 906
- References
- 186
- FWCI
- 11.23
- Type
- journal article
- Language
- en
- Open access
- green
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