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Cited by 181

The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.

Heteromorphic NiCo2S4/Ni3S2/Ni Foam as a Self-Standing Electrode for Hydrogen Evolution Reaction in Alkaline Solution

Liu, Hui, Ma, Xiao, Rao, Yuan, Liu, Yang, Liu, Jialiang, Wang, Luyang, Wu, Mingbo·2018·ACS Applied Materials & Interfaces

Abstract

Considerable works have been devoted on developing high-efficiency nonplatinum electrocatalysts for hydrogen evolution reaction (HER). Herein, 3D heteromorphic NiCo 2 S 4 /Ni 3 S 2 nanosheets network has been constructed on Ni foam (denoted as NiCo 2 S 4 /Ni 3 S 2 /NF) serving as a self-standing electrocatalyst through directly thermal sulfurization of a single-source NiCo-layered double hydroxide precursor. The resultant NiCo 2 S 4 /Ni 3 S 2 /NF electrode exhibits outstanding electrocatalytic HER performance with an extremely low onset overpotential of 15 mV and long-term durability in alkaline solution. Such enhanced HER performance can be credited to (1) the massive exposed active sites provided by mixed transition metal chalcogenides (NiCo 2 S 4 and Ni 3 S 2 ), (2) the strong interfacial interaction at NiCo 2 S 4 /Ni 3 S 2 heterojunction interfaces with the strengthened H binding, and (3) the porous highly conductive Ni foam substrate with accelerated electron transfer. This work opens up a new direction to fabricate effective and non-noble-metal electrodes for water splitting and hydrogen generation.

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Crossref · 10.1021/acsami.8b00296

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Metadata

Authors
Liu, H., Ma, X., Rao, Y., Liu, Y., Liu, J., Wang, L., & Wu, M.
Venue
ACS Applied Materials & Interfaces
Published
2018-03-19
Volume
10
Issue
13
Pages
10890-10897
ISSN
  • 1944-8244 (ISSN-L)
  • 1944-8252
OpenAlex
W2791213289
Cited by
181
References
8
FWCI
5.20
Type
journal article
Language
en
Open access
closed

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