The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Guidelines for the Rational Design of Ni-Based Double Hydroxide Electrocatalysts for the Oxygen Evolution Reaction
Open accessAbstract
The oxygen evolution reaction (OER) is one of the major bottlenecks hindering the implementation of a global economy based on solar fuels. It is known that Ni-based catalysts exhibit remarkable catalytic activities for the OER in alkaline media. In this joint theoretical–experimental study, we provide a thorough characterization of Ni-based double hydroxides with Cr, Mn, Fe, Co, Cu, and Zn at the atomic scale that not only explains the reasons for their high activity but also provides simple design principles for the enhancement of their electrocatalytic properties. Our approach, based on the local symmetry and composition of the active sites, helps rationalize the effect of dopants on the catalytic activity of Ni(OH) 2 . In particular, NiFe, NiCr, and NiMn double hydroxides (DHs) have superior catalytic activity, which reduce the OER potential to reach 0.5 mA cm –2 by 230, 190, and 160 mV, respectively, in comparison to IrO 2 nanoparticles, the state-of-the-art benchmarking catalysts, with 90% Faradaic efficiency for O 2 generation. The active species in NiFe and NiMn DHs are iron and manganese, while in NiCr DH, nickel is the active species.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Self-citationThe Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Crabtree, G. W., Dresselhaus, M. S., & Buchanan, M. V. (2004) · Physics Today · doi:10.1063/1.1878333 · Cited by 1,610
Cited by
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
A review on fundamentals for designing oxygen evolution electrocatalysts
Song, J., Wei, C., Huang, Z.-F., Liu, C., Zeng, L., Wang, X., & Xu, Z. J. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00607a · Cited by 2,936
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Direct Electrolytic Splitting of Seawater: Opportunities and Challenges
Dresp, S., Dionigi, F., Klingenhof, M., & Strasser, P. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b00220 · Cited by 1,272
Jiang, J., Sun, F., Zhou, S., Hu, W., Zhang, H., Dong, J., Jiang, Z., Zhao, J., Li, J., Yan, W., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-05341-y · Cited by 1,020
Metadata
- Authors
- Diaz-Morales, O., Ledezma-Yanez, I., Koper, M. T. M., & Calle-Vallejo, F.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-08-11
- Volume
- 5
- Issue
- 9
- Pages
- 5380-5387
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2301662868
- Cited by
- 568
- References
- 6
- FWCI
- 16.62
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
