The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Acceptorless, Reversible Dehydrogenation and Hydrogenation of N-Heterocycles with a Cobalt Pincer Catalyst
Abstract
Acceptorless, reversible dehydrogenation and hydrogenation reactions involving N -heterocycles are reported with a well-defined cobalt complex supported by an aminobis(phosphine) [PN(H)P] pincer ligand. Several N -heterocycle substrates have been evaluated under dehydrogenation and hydrogenation conditions. The cobalt-catalyzed amine dehydrogenation step, a key step in the dehydrogenation process, has been independently verified. Control studies with related cycloalkanes suggest that a direct acceptorless alkane dehydrogenation pathway is unlikely. The metal–ligand cooperativity is probed with the related [PN(Me)P] derivative of the cobalt catalyst. These results suggest a bifunctional dehydrogenation pathway and a nonbifunctional hydrogenation mechanism.
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Citations
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Cited by
Faye, O., Szpunar, J., & Eduok, U. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.02.112 · Cited by 689
The Prospect of Hydrogen Storage Using Liquid Organic Hydrogen Carriers
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Dehydrogenation of Alkanes and Aliphatic Groups by Pincer-Ligated Metal Complexes
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Metadata
- Authors
- Xu, R., Chakraborty, S., Yuan, H., & Jones, W. D.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-09-29
- Volume
- 5
- Issue
- 11
- Pages
- 6350-6354
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2343511638
- Cited by
- 266
- References
- 23
- FWCI
- 13.22
- Type
- journal article
- Language
- en
- Open access
- closed
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