The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Ionic Liquid/Zn-PPh3 Integrated Porous Organic Polymers Featuring Multifunctional Sites: Highly Active Heterogeneous Catalyst for Cooperative Conversion of CO2 to Cyclic Carbonates
Abstract
A series of ionic liquid (IL), zinc halide (ZnX 2 ), and triphenylphosphine (PPh 3 ) integrated porous organic polymers (POPs) featuring multifunctional sites were afforded through solvothermal synthesis for cyclic carbonate synthesis which utilizes epoxides and carbon dioxide (CO 2 ). Owing to the cooperative effect of ionic liquid and homogeneously distributed Zn-PPh 3 specie, which is probably strengthened by the confined microporous structure and flexible frameworks, these POPs catalysts exhibited high CO 2 capture and conversion performance and provided the highest activity (initial turnover frequencies up to 5200 h –1 ) of heterogeneous catalysts reported to date within the context of cyclic carbonate formation. Even more surprising, very favorable turnover numbers (TONs) of 2120 and 720 were attained at 40 and 25 °C, respectively. The effect of reaction parameters (reaction time, temperature, CO 2 pressure) on the catalytic performance as well as other epoxide substrates were also investigated in detail. Furthermore, the catalyst can be easily recovered and reused five times without a significant loss of activity. These ionic liquid and Zn-PPh 3 constructed porous polymers may provide an industrial opportunity for cyclic carbonate products.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Darensbourg, D. J. (2007) · Chemical Reviews · doi:10.1021/cr068363q · Cited by 1,593
Reactive Applications of Cyclic Alkylene Carbonates
Clements, J. H. (2003) · Industrial & Engineering Chemistry Research · doi:10.1021/ie020678i · Cited by 784
Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer
Xie, Y., Wang, T.-T., Liu, X.-H., Zou, K., & Deng, W.-Q. (2013) · Nature Communications · doi:10.1038/ncomms2960 · Cited by 772
Cited by
Shaikh, R. R., Pornpraprom, S., & D’Elia, V. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03580 · Cited by 729
Liang, J., Huang, Y.-B., & Cao, R. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.11.013 · Cited by 444
Zhang, S.-Y., Zhuang, Q., Zhang, M., Wang, H., Gao, Z., Sun, J.-K., & Yuan, J. (2020) · Chemical Society Reviews · doi:10.1039/c8cs00938d · Cited by 384
Metadata
- Authors
- Wang, W., Li, C., Yan, L., Wang, Y., Jiang, M., & Ding, Y.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-08-12
- Volume
- 6
- Issue
- 9
- Pages
- 6091-6100
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2499543034
- Cited by
- 220
- References
- 3
- FWCI
- 10.92
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
