Making Plastics from Carbon Dioxide: Salen Metal Complexes as Catalysts for the Production of Polycarbonates from Epoxides and CO 2

Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis

Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824 · see citing works

Asymmetric Catalysis with Water: Efficient Kinetic Resolution of Terminal Epoxides by Means of Catalytic Hydrolysis

Tokunaga, M., Larrow, J. F., Kakiuchi, F., & Jacobsen, E. N. (1997) · Science · doi:10.1126/science.277.5328.936 · Cited by 1,366 · see citing works

Asymmetric Catalysis of Epoxide Ring-Opening Reactions

Jacobsen, E. N. (2000) · Accounts of Chemical Research · doi:10.1021/ar960061v · Cited by 1,261 · see citing works

Discrete Metal‐Based Catalysts for the Copolymerization of CO₂ and Epoxides: Discovery, Reactivity, Optimization, and Mechanism

Coates, G. W., & Moore, D. R. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460442 · Cited by 1,154 · see citing works

Copolymerization of carbon dioxide and epoxide

Inoue, S., Koinuma, H., & Tsuruta, T. (1969) · Journal of Polymer Science Part B Polymer Letters · doi:10.1002/pol.1969.110070408 · Cited by 1,041 · see citing works

Reactive Applications of Cyclic Alkylene Carbonates

Clements, J. H. (2003) · Industrial & Engineering Chemistry Research · doi:10.1021/ie020678i · Cited by 784 · see citing works

Chemical CO2 Fixation: Cr(III) Salen Complexes as Highly Efficient Catalysts for the Coupling of CO2 and Epoxides

Paddock, R. L., & Nguyen, S. T. (2001) · Journal of the American Chemical Society · doi:10.1021/ja0164677 · Cited by 671 · see citing works

Copolymerization of carbon dioxide and epoxide with organometallic compounds

Inoue, S., Koinuma, H., & Tsuruta, T. (1969) · Die Makromolekulare Chemie · doi:10.1002/macp.1969.021300112 · Cited by 576 · see citing works

Cobalt Catalysts for the Alternating Copolymerization of Propylene Oxide and Carbon Dioxide: Combining High Activity and Selectivity

Cohen, C. T., Chu, T., & Coates, G. W. (2005) · Journal of the American Chemical Society · doi:10.1021/ja051744l · Cited by 524 · see citing works

Mechanism of the Alternating Copolymerization of Epoxides and CO₂ Using <i>β</i>-Diiminate Zinc Catalysts:  Evidence for a Bimetallic Epoxide Enchainment

Moore, D. R., Cheng, M., Lobkovsky, E. B., & Coates, G. W. (2003) · Journal of the American Chemical Society · doi:10.1021/ja030085e · Cited by 515 · see citing works

Catalytic Reactions Involving C 1 Feedstocks: New High-Activity Zn(II)-Based Catalysts for the Alternating Copolymerization of Carbon Dioxide and Epoxides

Cheng, M. T., Lobkovsky, E. B., & Coates, G. W. (1998) · Journal of the American Chemical Society · doi:10.1021/ja982601k · Cited by 483 · see citing works

Copolymerization of CO2 and Epoxides Catalyzed by Metal Salen Complexes

Darensbourg, D. J., Mackiewicz, R. M., Phelps, A. L., & Billodeaux, D. R. (2004) · Accounts of Chemical Research · doi:10.1021/ar030240u · Cited by 478 · see citing works

Alternating Copolymerization of Limonene Oxide and Carbon Dioxide

Byrne, C. M., Allen, S. D., Lobkovsky, E. B., & Coates, G. W. (2004) · Journal of the American Chemical Society · doi:10.1021/ja0472580 · Cited by 428 · see citing works

Design of Highly Active Binary Catalyst Systems for CO 2 /Epoxide Copolymerization: Polymer Selectivity, Enantioselectivity, and Stereochemistry Control

Lu, X., Shi, L., Wang, Y., Zhang, R., Ying-ju, Z., Peng, X., Zhang, Z., & Li, B. (2006) · Journal of the American Chemical Society · doi:10.1021/ja056383o · Cited by 427 · see citing works

Cobalt‐Based Complexes for the Copolymerization of Propylene Oxide and CO2: Active and Selective Catalysts for Polycarbonate Synthesis

Qin, Z., Thomas, C. M., Lee, S., & Coates, G. W. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200352605 · Cited by 415 · see citing works

Mechanistic Investigation Leads to a Synthetic Improvement in the Hydrolytic Kinetic Resolution of Terminal Epoxides

Nielsen, L. P. C., Stevenson, C. P., Blackmond, D. G., et al. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038590z · Cited by 394 · see citing works

On the Mechanism of Asymmetric Nucleophilic Ring-Opening of Epoxides Catalyzed by (Salen)CrIII Complexes

Hansen, K. B., Leighton, J. L., & Jacobsen, E. N. (1996) · Journal of the American Chemical Society · doi:10.1021/ja962600x · Cited by 392 · see citing works

Selective Formation of Polycarbonate over Cyclic Carbonate: Copolymerization of Epoxides with Carbon Dioxide Catalyzed by a Cobalt(III) Complex with a Piperidinium End‐Capping Arm

Nakano, K., Kamada, T., & Nozaki, K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200603132 · Cited by 389 · see citing works

Cooperative Asymmetric Catalysis with Dimeric Salen Complexes

Konsler, R. G., Karl, J., & Jacobsen, E. N. (1998) · Journal of the American Chemical Society · doi:10.1021/ja982683c · Cited by 387 · see citing works

Mechanistic Aspects of the Copolymerization Reaction of Carbon Dioxide and Epoxides, Using a Chiral Salen Chromium Chloride Catalyst

Darensbourg, D. J., & Yarbrough, J. C. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012714v · Cited by 382 · see citing works

Metalloporphyrins as Initiators for Living and Immortal Polymerizations

Aida, T., & Inoue, S. (1996) · Accounts of Chemical Research · doi:10.1021/ar950029l · Cited by 370 · see citing works

Coordination Chemistry and Reactivity of Monomeric Alkoxides and Amides of Magnesium and Zinc Supported by the Diiminato Ligand CH(CMeNC 6 H 3 -2,6- i Pr 2 ) 2 . A Comparative Study

Chisholm, M. H., Gallucci, J. C., & Phomphrai, K. (2002) · Inorganic Chemistry · doi:10.1021/ic020148e · Cited by 359 · see citing works

Asymmetric Catalysis with CO2: Direct Synthesis of Optically Active Propylene Carbonate from Racemic Epoxides

Lu, X., Liang, B., Zhang, Y.-J., Tian, Y., Wang, Y., Bai, C., Wang, H., & Zhang, R. (2004) · Journal of the American Chemical Society · doi:10.1021/ja049734s · Cited by 350 · see citing works

Highly Active, Binary Catalyst Systems for the Alternating Copolymerization of CO2 and Epoxides under Mild Conditions

Lu, X., & Wang, Y. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200453998 · Cited by 346 · see citing works

Comparative Kinetic Studies of the Copolymerization of Cyclohexene Oxide and Propylene Oxide with Carbon Dioxide in the Presence of Chromium Salen Derivatives. In Situ FTIR Measurements of Copolymer vs Cyclic Carbonate Production

Darensbourg, D. J., Yarbrough, J. C., Ortíz, C., et al. (2003) · Journal of the American Chemical Society · doi:10.1021/ja034863e · Cited by 341 · see citing works

High-Activity, Single-Site Catalysts for the Alternating Copolymerization of CO2 and Propylene Oxide

Allen, S. D., Moore, D. R., Lobkovsky, E. B., & Coates, G. W. (2002) · Journal of the American Chemical Society · doi:10.1021/ja028071g · Cited by 324 · see citing works

Catalytic Activity of a Series of Zn(II) Phenoxides for the Copolymerization of Epoxides and Carbon Dioxide

Darensbourg, D. J., Holtcamp, M. W., Struck, G. E., Zimmer, M. S., Niezgoda, S. A., Rainey, P., Robertson, J. B., Draper, J. D., & Reibenspies, J. H. (1998) · Journal of the American Chemical Society · doi:10.1021/ja9826284 · Cited by 323 · see citing works

Chemical Fixation of Carbon Dioxide Catalyzed by Binaphthyldiamino Zn, Cu, and Co Salen-Type Complexes

Shen, Y., Duan, W., & Shi, M. J. (2003) · The Journal of Organic Chemistry · doi:10.1021/jo020191j · Cited by 316 · see citing works

Activation of carbon dioxide with aluminum porphyrin and reaction with epoxide. Studies on (tetraphenylporphinato)aluminum alkoxide having a long oxyalkylene chain as the alkoxide group

Aida, T., & Inoue, S. (1983) · Journal of the American Chemical Society · doi:10.1021/ja00343a038 · Cited by 314 · see citing works

Catalytic Formation of Cyclic Carbonates from Epoxides and CO2 with Chromium Metalloporphyrinates

Kruper, W. J., & Dellar, D. D. (1995) · The Journal of Organic Chemistry · doi:10.1021/jo00108a042 · Cited by 309 · see citing works

Catalytic Activity of Zinc(II) Phenoxides Which Possess Readily Accessible Coordination Sites. Copolymerization and Terpolymerization of Epoxides and Carbon Dioxide

Darensbourg, D. J., & Holtcamp, M. W. (1995) · Macromolecules · doi:10.1021/ma00126a043 · Cited by 300 · see citing works

Bis 2,6-difluorophenoxide Dimeric Complexes of Zinc and Cadmium and Their Phosphine Adducts: Lessons Learned Relative to Carbon Dioxide/Cyclohexene Oxide Alternating Copolymerization Processes Catalyzed by Zinc Phenoxides

Darensbourg, D. J., Wildeson, J. R., Yarbrough, J. C., & Reibenspies, J. H. (2000) · Journal of the American Chemical Society · doi:10.1021/ja002855h · Cited by 270 · see citing works

Role of the Cocatalyst in the Copolymerization of CO2 and Cyclohexene Oxide Utilizing Chromium Salen Complexes

Darensbourg, D. J., & Mackiewicz, R. M. (2005) · Journal of the American Chemical Society · doi:10.1021/ja053544f · Cited by 265 · see citing works

Copolymerization of CO2 and 1,2-Cyclohexene Oxide Using a CO2-Soluble Chromium Porphyrin Catalyst

Mang, S., Cooper, A. I., Colclough, M. E., Chauhan, N., & Holmes, A. B. (1999) · Macromolecules · doi:10.1021/ma991162m · Cited by 252 · see citing works

Co(III) porphyrin/DMAP: an efficient catalyst system for the synthesis of cyclic carbonates from CO2 and epoxides

Paddock, R. L., Hiyama, Y., McKay, J. M., et al. (2004) · Tetrahedron Letters · doi:10.1016/j.tetlet.2003.10.101 · Cited by 245 · see citing works

Monomeric metal alkoxides and trialkyl siloxides: (BDI)Mg(OtBu)(THF ) and (BDI)Zn(OSiPh3)(THF ). Comments on single site catalysts for ring-opening polymerization of lactides †

Chisholm, M. H., Huffman, J. C., & Phomphrai, K. (2001) · Journal of the Chemical Society Dalton Transactions · doi:10.1039/b008158m · Cited by 241 · see citing works

Alternating copolymerization of carbon dioxide and epoxide catalyzed by the aluminum porphyrin-quaternary organic salt or -triphenylphosphine system. Synthesis of polycarbonate with well-controlled molecular weight

Aida, T., Ishikawa, M., & Inoue, S. (1986) · Macromolecules · doi:10.1021/ma00155a002 · Cited by 238 · see citing works

New generation polymers: the role of metal alkoxides as catalysts in the production of polyoxygenates

Chisholm, M. H., & Zhou, Z. (2004) · Journal of Materials Chemistry · doi:10.1039/b405489j · Cited by 235 · see citing works

Optically Active Polycarbonates: Asymmetric Alternating Copolymerization of Cyclohexene Oxide and Carbon Dioxide

Nozaki, K., Nakano, K., & Hiyama, T. (1999) · Journal of the American Chemical Society · doi:10.1021/ja992433b · Cited by 234 · see citing works

On the Formation of Aliphatic Polycarbonates from Epoxides with Chromium( III ) and Aluminum( III ) Metal–Salen Complexes

Luinstra, G. A., Haas, G. R., Molnar, F., Bernhart, V., Eberhardt, R., & Rieger, B. (2005) · Chemistry - A European Journal · doi:10.1002/chem.200500356 · Cited by 217 · see citing works

Enantiomerically-enriched organic reagents via polymer synthesis: enantioselective copolymerization of cycloalkene oxides and CO2 using homogeneous, zinc-based catalysts

Cheng, M. T., Darling, N. A., Lobkovsky, E. B., & Coates, G. W. (2000) · Chemical Communications · doi:10.1039/b005537i · Cited by 204 · see citing works

DMAP/Cr(III) Catalyst Ratio: The Decisive Factor for Poly(propylene carbonate) Formation in the Coupling of CO2 and Propylene Oxide

Eberhardt, R., Allmendinger, M., & Rieger, B. (2003) · Macromolecular Rapid Communications · doi:10.1002/marc.200390022 · Cited by 200 · see citing works

Copolymerization of 1,2-Epoxycyclohexane and Carbon Dioxide Using Carbon Dioxide as Both Reactant and Solvent

Super, M., Berluche, E., Costello, C. A., & Beckman, E. J. (1997) · Macromolecules · doi:10.1021/ma960755j · Cited by 195 · see citing works

Asymmetric Alternating Copolymerization of Cyclohexene Oxide and CO2with Dimeric Zinc Complexes

Nakano, K., Nozaki, K., & Hiyama, T. (2003) · Journal of the American Chemical Society · doi:10.1021/ja028666b · Cited by 186 · see citing works

Cyclohexene Oxide/CO2 Copolymerization Catalyzed by Chromium(III) Salen Complexes and N-Methylimidazole: Effects of Varying Salen Ligand Substituents and Relative Cocatalyst Loading

Darensbourg, D. J., Mackiewicz, R. M., Rodgers, J. L., et al. (2004) · Inorganic Chemistry · doi:10.1021/ic049182e · Cited by 182 · see citing works

Synthesis and physical characterization of poly(cyclohexane carbonate), synthesized from CO2 and cyclohexene oxide

Koning, C. E., Wildeson, J. R., Parton, R. F., Plum, B., Steeman, P. A. M., & Darensbourg, D. J. (2001) · Polymer · doi:10.1016/s0032-3861(00)00709-6 · Cited by 180 · see citing works

Intramolecularly Dinuclear Magnesium Complex Catalyzed Copolymerization of Cyclohexene Oxide with CO2 under Ambient CO2 Pressure: Kinetics and Mechanism

Xiao, Y., Wang, Z., & Ding, K. (2005) · Macromolecules · doi:10.1021/ma051859+ · Cited by 177 · see citing works

Chemical fixation of carbon dioxide to cyclic carbonates under extremely mild conditions with highly active bifunctional catalysts

Lu, X., Zhang, Y.-J., Liang, B., et al. (2003) · Journal of Molecular Catalysis A Chemical · doi:10.1016/j.molcata.2003.09.010 · Cited by 173 · see citing works

Isolation of a Pyridinium Alkoxy Ion Bridged Dimeric Zinc Complex for the Coupling Reactions of CO(2) and Epoxides This work was supported by the Ministry of Science and Technology. We thank Dr. Young-A Lee, KIST, for the X-ray crystallographic analysis.

Kim, H., Kim, J., Lee, B. H., et al. (2000) · PubMed · Cited by 164 · see citing works

Aluminum Salen Complexes and Tetrabutylammonium Salts: A Binary Catalytic System for Production of Polycarbonates from CO2 and Cyclohexene Oxide

Darensbourg, D. J., & Billodeaux, D. R. (2005) · Inorganic Chemistry · doi:10.1021/ic048508g · Cited by 163 · see citing works

Concerning the Mechanism of the Ring Opening of Propylene Oxide in the Copolymerization of Propylene Oxide and Carbon Dioxide To Give Poly(propylene carbonate)

Chisholm, M. H., & Zhou, Z. (2004) · Journal of the American Chemical Society · doi:10.1021/ja0394232 · Cited by 159 · see citing works

Metal-catalyzed synthesis of stereoregular polyketones, polyesters, and polycarbonates

Nakano, K., Kosaka, N., Hiyama, T., & Nozaki, K. (2003) · Dalton Transactions · doi:10.1039/b304690g · Cited by 157 · see citing works

Catalytic reaction on both sides of a metalloporphyrin plane. Alternating copolymerization of phthalic anhydride and epoxypropane with an aluminum porphyrin-quaternary salt system

Aida, T., & Inoue, S. (1985) · Journal of the American Chemical Society · doi:10.1021/ja00291a041 · Cited by 152 · see citing works

Asymmetric Alternating Copolymerization and Terpolymerization of Epoxides with Carbon Dioxide at Mild Conditions

Shi, L., Lu, X., Zhang, R., Peng, X., Zhang, C., Li, J., & Peng, X.-M. (2006) · Macromolecules · doi:10.1021/ma060290p · Cited by 151 · see citing works

Highly active electrophile–nucleophile catalyst system for the cycloaddition of CO2 to epoxides at ambient temperature

Lu, X., Ying-ju, Z., Jin, K., et al. (2004) · Journal of Catalysis · doi:10.1016/j.jcat.2004.07.018 · Cited by 148 · see citing works

Alternating copolymerization of propylene oxide and carbon dioxide with highly efficient and selective (salen)Co(III) catalysts: Effect of ligand and cocatalyst variation

Cohen, C. T., & Coates, G. W. (2006) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.21606 · Cited by 148 · see citing works

Fabricating Microarrays of Functional Proteins Using Affinity Contact Printing

Renault, J., Bernard, A., Juncker, D., Michel, B., Bosshard, H. R., & Delamarche, E. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020703)41:13 · Cited by 148 · see citing works

Cationic Aluminum Compounds with Potential Relevance to Lewis Acid Catalysis

Atwood, D. A., Jegier, J. A., & Rutherford, D. N. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00130a018 · Cited by 147 · see citing works

Catalytic Asymmetric Addition of Carbon Dioxide to Propylene Oxide with Unprecedented Enantioselectivity

Berkessel, A., & Brandenburg, M. (2006) · Organic Letters · doi:10.1021/ol061501d · Cited by 144 · see citing works

Catalytic formation of ethylene carbonate from supercritical carbon dioxide/ethylene oxide mixture with tetradentate Schiff-base complexes as catalyst

Lu, X., Feng, X.-J., & He, R. (2002) · Applied Catalysis A General · doi:10.1016/s0926-860x(02)00223-5 · Cited by 144 · see citing works

Copolymerization of cyclohexene oxide and carbon dioxide using (salen)Co( iii ) complexes: synthesis and characterization of syndiotactic poly(cyclohexene carbonate)

Cohen, C. T., Thomas, C. M., Peretti, K. L., Lobkovsky, E. B., & Coates, G. W. (2005) · Dalton Transactions · doi:10.1039/b513107c · Cited by 143 · see citing works

Physical properties of aliphatic polycarbonates made from CO2 and epoxides

Thorat, S. D., Phillips, P. J., Semenov, V. V., et al. (2003) · Journal of Applied Polymer Science · doi:10.1002/app.12355 · Cited by 142 · see citing works

Alternating Copolymerization of CO 2 and Propylene Oxide Catalyzed by Co III (salen)/Lewis Base

Paddock, R. L., & Nguyen, S. T. (2005) · Macromolecules · doi:10.1021/ma047551k · Cited by 140 · see citing works

A Highly Active, Isospecific Cobalt Catalyst for Propylene Oxide Polymerization

Peretti, K. L., Ajiro, H., Cohen, C. T., Lobkovsky, E. B., & Coates, G. W. (2005) · Journal of the American Chemical Society · doi:10.1021/ja053451y · Cited by 139 · see citing works

Alternating Copolymerization of CO2 and Propylene Oxide with the Catalysts Prepared from Zn(OH)2 and Various Dicarboxylic Acids

Soga, K., Imai, E., & Hattori, I. (1981) · Polymer Journal · doi:10.1295/polymj.13.407 · Cited by 134 · see citing works

Pressure Dependence of the Carbon Dioxide/Cyclohexene Oxide Coupling Reaction Catalyzed by Chromium Salen Complexes. Optimization of the Comonomer-Alternating Enchainment Pathway

Darensbourg, D. J., Mackiewicz, R. M., & Billodeaux, D. R. (2004) · Organometallics · doi:10.1021/om049454l · Cited by 132 · see citing works

(Salen)CrIIIX Catalysts for the Copolymerization of Carbon Dioxide and Epoxides: Role of the Initiator and Cocatalyst

Darensbourg, D. J., Mackiewicz, R. M., Rodgers, J. L., et al. (2004) · Inorganic Chemistry · doi:10.1021/ic0352856 · Cited by 121 · see citing works

A New Class of Aluminum Cations Based upon Tetradentate (N 2 O 2 ) Chelating Ligands

Atwood, D. A., Jegier, J. A., & Rutherford, D. N. (1996) · Inorganic Chemistry · doi:10.1021/ic950574i · Cited by 119 · see citing works

CO fixation using recoverable chromium salen catalysts: use of ionic liquids as cosolvent or high-surface-area silicates as supports

Álvaro, M., Baleizão, C., DAS, D., et al. (2004) · Journal of Catalysis · doi:10.1016/j.jcat.2004.08.022 · Cited by 118 · see citing works

Synthesis of ethylene carbonate from supercritical carbon dioxide/ethylene oxide mixture in the presence of bifunctional catalyst

Lu, X., He, R., & Bai, C. (2002) · Journal of Molecular Catalysis A Chemical · doi:10.1016/s1381-1169(01)00442-3 · Cited by 113 · see citing works

New Developments in the Origins of the Homochirality of Biologically Relevant Molecules

Buschmann, H., Thede, R., & Heller, D. (2000) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20001117)39:22 · Cited by 111 · see citing works

Supercritical carbon dioxide as solvent for the copolymerization of carbon dioxide and propylene oxide using a heterogeneous zinc carboxylate catalyst

Darensbourg, D. J., Stafford, N. W., & Katsurao, T. (1995) · Journal of Molecular Catalysis A Chemical · doi:10.1016/1381-1169(95)00142-5 · Cited by 109 · see citing works

Binding of Propylene Oxide to Porphyrin− and Salen−M(III) Cations, Where M = Al, Ga, Cr, and Co

Chen, P., Chisholm, M. H., Gallucci, J. C., Zhang, X., & Zhou, Z. (2005) · Inorganic Chemistry · doi:10.1021/ic048597x · Cited by 92 · see citing works

Polymer-bound aluminium salen complex as reusable catalysts for CO2 insertion into epoxides

Álvaro, M., Baleizão, C., Carbonell, E., Ghoul, M. E., Garcı́a, H., & Gigante, B. (2005) · Tetrahedron · doi:10.1016/j.tet.2005.07.114 · Cited by 91 · see citing works

Preparation of optically active poly(propylene oxide) by asymmetric induction

Inoue, S., Tsuruta, T., & Furukawa, J. (1962) · Die Makromolekulare Chemie · doi:10.1002/macp.1962.020530127 · Cited by 87 · see citing works

Unexpected Side Reactions and Chain Transfer for Zinc-Catalyzed Copolymerization of Cyclohexene Oxide and Carbon Dioxide

van Meerendonk, W. J., Duchateau, R., Koning, C. E., et al. (2005) · Macromolecules · doi:10.1021/ma050797k · Cited by 83 · see citing works

New Mechanistic Insight into the Coupling Reactions of CO2 and Epoxides in the Presence of Zinc Complexes

Kim, H. S., Kim, J. J., Lee, S. D., Lah, M. S., Moon, D., & Jang, H. G. (2003) · Chemistry - A European Journal · doi:10.1002/chem.200390076 · Cited by 83 · see citing works

Photochemistry of diastereomeric 2,4-diphenylpentan-3-ones and related ketones in "super-cage" environments provided by micelles, porous glass, and porous silica: temperature and magnetic field effects

Baretz, B. H., & Turro, N. J. (1983) · Journal of the American Chemical Society · doi:10.1021/ja00343a039 · Cited by 82 · see citing works

Synthesis, structure, and reactivity of zerovalent group 6 metal pentacarbonyl aryl oxide complexes. Reactions with carbon dioxide

Darensbourg, D. J., Sanchez, K. M., Reibenspies, J. H., et al. (1989) · Journal of the American Chemical Society · doi:10.1021/ja00200a031 · Cited by 80 · see citing works

Spectral Assignment of Poly[cyclohexene oxide- a lt -carbon dioxide]

Nakano, K., Nozaki, K., & Hiyama, T. (2001) · Macromolecules · doi:10.1021/ma010732r · Cited by 80 · see citing works

Effective, Selective Coupling of Propylene Oxide and Carbon Dioxide to Poly(Propylene Carbonate) Using (Salen)CrN 3 Catalysts

Darensbourg, D. J., & Phelps, A. L. (2005) · Inorganic Chemistry · doi:10.1021/ic050443+ · Cited by 73 · see citing works

NEXAFS spectroscopy study of the surface properties of zinc glutarate and its reactivity with carbon dioxide and propylene oxide

Kim, J., Ree, M., Lee, S. W., Oh, W., Baek, S., Lee, B., Shin, T. J., Kim, K. J., Kim, B., & Lüning, J. (2003) · Journal of Catalysis · doi:10.1016/s0021-9517(03)00122-2 · Cited by 70 · see citing works

Probing the Cybotactic Region in Gas-Expanded Liquids (GXLs)

Hallett, J. P., Kitchens, C. L., Hernandez, R., et al. (2006) · Accounts of Chemical Research · doi:10.1021/ar0501424 · Cited by 68 · see citing works

Hydrothermal Synthesis of Single-Crystalline Zinc Glutarate and Its Structural Determination

Kim, J., Kim, H., & Ree, M. (2004) · Chemistry of Materials · doi:10.1021/cm035358j · Cited by 66 · see citing works

Investigations into the steric influences on the reaction mechanism of carbon dioxide insertion into metal-oxygen bonds. Carbonyl sulfide activation as a model for CO2

Darensbourg, D. J., Mueller, B. L., Bischoff, C. J., et al. (1991) · Inorganic Chemistry · doi:10.1021/ic00010a035 · Cited by 55 · see citing works

Catalytic Coupling of Carbon Dioxide and 2,3-Epoxy-1,2,3,4-tetrahydronaphthalene in the Presence of a (Salen)CrIIICl Derivative

Darensbourg, D. J., Fang, C. C., & Rodgers, J. L. (2004) · Organometallics · doi:10.1021/om034278m · Cited by 54 · see citing works

Asymmetric amplification in asymmetric alternating copolymerization of cyclohexene oxide and carbon dioxide

Nakano, K., Hiyama, T., & Nozaki, K. (2005) · Chemical Communications · doi:10.1039/b417973k · Cited by 53 · see citing works

Solution and Solid-State Structural Studies of Epoxide Adducts of Cadmium Phenoxides. Chemistry Relevant to Epoxide Activation for Ring-Opening Reactions

Darensbourg, D. J., Wildeson, J. R., Lewis, S. J., et al. (2002) · Journal of the American Chemical Society · doi:10.1021/ja020184c · Cited by 53 · see citing works

NMR Assignments of Regioregular Poly(propylene oxide) at the Triad and Tetrad Level

Chisholm, M. H., & Navarro-Llobet, D. (2002) · Macromolecules · doi:10.1021/ma0119934 · Cited by 52 · see citing works

Probing the mechanistic aspects of the chromium salen catalyzed carbon dioxide/epoxide copolymerization process using in situ ATR/FTIR

Darensbourg, D. J., Rodgers, J. L., Mackiewicz, R. M., et al. (2004) · Catalysis Today · doi:10.1016/j.cattod.2004.09.017 · Cited by 52 · see citing works

Notes - Oxidation of Trialkyl Phosphites by Epoxides

Scott, C. (1957) · The Journal of Organic Chemistry · doi:10.1021/jo01360a613 · Cited by 48 · see citing works

Enantioselective CO2 Fixation Catalyzed by Optically Active Cobalt Complexes

Tanaka, H., Kitaichi, Y., Sato, M., et al. (2004) · Chemistry Letters · doi:10.1246/cl.2004.676 · Cited by 43 · see citing works

Kinetic Study of the Insertion and Deinsertion of Carbon Dioxide into fac-(CO)3(dppe)MnOR Derivatives

Darensbourg, D. J., Lee, W., Phelps, A. L., et al. (2003) · Organometallics · doi:10.1021/om034087j · Cited by 42 · see citing works

The Copolymerization of Carbon Dioxide and [2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane Catalyzed by (Salen)CrCl. Formation of a CO2 Soluble Polycarbonate

Darensbourg, D. J., Rodgers, J. L., & Fang, C. C. (2003) · Inorganic Chemistry · doi:10.1021/ic034363m · Cited by 40 · see citing works

A Dramatic Difference in the Reactivities of Alkoxido‐ and Aryloxidorhenium Complexes in Insertion Reactions

Simpson, R. D., & Bergman, R. G. (1992) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199202201 · Cited by 34 · see citing works

Ester-Functionalized Polycarbonates Obtained by Copolymerization of Ester-Substituted Oxiranes and Carbon Dioxide: A MALDI-ToF-MS Analysis Study

Duchateau, R., van Meerendonk, W. J., Yajjou, L., Staal, B. B. P., Koning, C. E., & Gruter, G. M. (2006) · Macromolecules · doi:10.1021/ma0610313 · Cited by 34 · see citing works

Copolymerization of propene oxide with carbon with carbon dioxide: aselective incorporation of propene oxide into the polycarbonate chains, determined by 100 MHz 13C n.m.r. spectroscopy

Lednor, P. W., & Rol, N. C. (1985) · Journal of the Chemical Society Chemical Communications · doi:10.1039/c39850000598 · Cited by 34 · see citing works

Further studies related to the copolymerization of cyclohexene oxide and carbon dioxide catalyzed by chromium Schiff base complexes. Crystal structures of two μ-hydroxo-bridged Schiff base dimers of chromium(III)

Darensbourg, D. J., Frantz, E. B., & Andreatta, J. R. (2006) · Inorganica Chimica Acta · doi:10.1016/j.ica.2006.07.093 · Cited by 27 · see citing works

Gas-Phase and Solution-Phase Polymerization of Epoxides by Cr(salen) Complexes: Evidence for a Dinuclear Cationic Mechanism

Schön, E., Zhang, X., Zhou, Z., et al. (2004) · Inorganic Chemistry · doi:10.1021/ic049120o · Cited by 24 · see citing works

Structural characterizations of coordination complexes of bis-triphenylphosphine copper(I) dicarboxylates

Darensbourg, D. J., Holtcamp, M. W., & Reibenspies, J. H. (1996) · Polyhedron · doi:10.1016/0277-5387(95)00518-8 · Cited by 22 · see citing works

Phase Behavior of Carbon Dioxide + 1,2-Epoxycyclohexane Mixtures

Super, M. S., Enick, R. M., & Beckman, E. J. (1997) · Journal of Chemical & Engineering Data · doi:10.1021/je960381p · Cited by 18 · see citing works

Role of the Cocatalyst in the Copolymerization of CO2 and Cyclohexene Oxide Utilizing Chromium Salen Complexes [J. Am. Chem. Soc. 2005, 127, 14026−14038].

Darensbourg, D. J., Mackiewicz, & Rodgers, J. L. (2005) · Journal of the American Chemical Society · doi:10.1021/ja059920d · Cited by 17 · see citing works

Precipitation and Crystallization Techniques

Bertucco, A. (1999) · doi:10.1002/9783527613687.ch6 · Cited by 8 · see citing works

A stepwise huisgen cycloaddition process: copper(I)-catalyzed regioselective ligation of azides and terminal alkynes

Rostovtsev, V. V., Green, L. G., Fokin, V. V., & Sharpless, K. B. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020715)41:14

Sustainable polymers from renewable resources

Zhu, Y., Romain, C., & Williams, C. K. (2016) · Nature · doi:10.1038/nature21001 · Cited by 2,762 · see citing works

The synthesis of organic carbonates from carbon dioxide

Sakakura, T., & Kohno, K. (2009) · Chemical Communications · doi:10.1039/b819997c · Cited by 1,067 · see citing works

Catalysis as an Enabling Science for Sustainable Polymers

Zhang, X., Fevre, M., Jones, G. O., & Waymouth, R. M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00329 · Cited by 936 · see citing works

Catalysts for CO ₂ /epoxide copolymerisation

Kember, M. R., Buchard, A., & Williams, C. K. (2011) · Chem. Commun. · doi:10.1039/c0cc02207a · Cited by 797 · see citing works

Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates

Paul, S., Zhu, Y., Romain, C., Brooks, R., Saini, P. K., & Williams, C. K. (2015) · Chemical Communications · doi:10.1039/c4cc10113h · Cited by 593 · see citing works

Controlled Polymerization of Next-Generation Renewable Monomers and Beyond

Yao, K., & Tang, C. (2013) · Macromolecules · doi:10.1021/ma3019574 · Cited by 485 · see citing works

Stereoselective Epoxide Polymerization and Copolymerization

Childers, M. I., Longo, J. M., Van Zee, N. J., LaPointe, A. M., & Coates, G. W. (2014) · Chemical Reviews · doi:10.1021/cr400725x · Cited by 471 · see citing works

Challenges in the catalytic synthesis of cyclic and polymeric carbonates from epoxides and CO2

Pescarmona, P. P., & Taherimehr, M. (2012) · Catalysis Science &amp; Technology · doi:10.1039/c2cy20365k · Cited by 392 · see citing works

Carbon dioxide (CO ₂ ) as sustainable feedstock for polyurethane production

Langanke, J., Wolf, A., Hofmann, J., Böhm, K., Subhani, M. A., Müller, T. E., Leitner, W., & Gürtler, C. (2014) · Green Chem. · doi:10.1039/c3gc41788c · Cited by 361 · see citing works

Synthesis and post-polymerisation modifications of aliphatic poly(carbonate)s prepared by ring-opening polymerisation

Tempelaar, S., Mespouille, L., Coulembier, O., Dubois, P., & Dove, A. P. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35268k · Cited by 345 · see citing works

A Protic Ionic Liquid Catalyzes CO₂ Conversion at Atmospheric Pressure and Room Temperature: Synthesis of Quinazoline‐2,4(1<i>H</i>,3<i>H</i>)‐diones

Zhao, Y., Yu, B., Yang, Z., Zhang, H., Hao, L., Gao, X., & Liu, Z. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201400521 · Cited by 250 · see citing works

Chemoselective Polymerization Control: From Mixed‐Monomer Feedstock to Copolymers

Romain, C., & Williams, C. K. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201309575 · Cited by 238 · see citing works

Catalysts for CO ₂ /epoxide ring-opening copolymerization

Trott, G., Saini, P. K., & Williams, C. K. (2016) · Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences · doi:10.1098/rsta.2015.0085 · Cited by 201 · see citing works

Green polycarbonates prepared by the copolymerization of CO₂ with epoxides

Taherimehr, M., & Pescarmona, P. P. (2014) · Journal of Applied Polymer Science · doi:10.1002/app.41141 · Cited by 194 · see citing works

Immortal CO₂/Propylene Oxide Copolymerization: Precise Control of Molecular Weight and Architecture of Various Block Copolymers

Cyriac, A., Lee, S. H., Varghese, J. K., Park, E. S., Park, J. H., & Lee, B. Y. (2010) · Macromolecules · doi:10.1021/ma101259k · Cited by 161 · see citing works

Transforming polylactide into value‐added materials

Leibfarth, F. A., Moreno, N., Hawker, A. P., & Shand, J. D. (2012) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.26303 · Cited by 139 · see citing works

Efficient and Greener Synthesis of Propylene Carbonate from Carbon Dioxide and Propylene Oxide

Adeleye, A. I., Patel, D., Niyogi, D., & Saha, B. (2014) · Industrial &amp; Engineering Chemistry Research · doi:10.1021/ie500345z · Cited by 108 · see citing works

Redox Switchable Copolymerization of Cyclic Esters and Epoxides by a Zirconium Complex

Quan, S. M., Wang, X., Zhang, R., & Diaconescu, P. L. (2016) · Macromolecules · doi:10.1021/acs.macromol.6b00997 · Cited by 93 · see citing works

Salen, salan and salalen iron( <scp>iii</scp> ) complexes as catalysts for CO ₂ /epoxide reactions and ROP of cyclic esters

Cozzolino, M., Leo, V., Tedesco, C., Mazzeo, M., & Lamberti, M. (2018) · Dalton Transactions · doi:10.1039/c8dt03169j · Cited by 83 · see citing works

Discrete iron-based complexes: Applications in homogeneous coordination-insertion polymerization catalysis

Champouret, Y., Hashmi, O. H., & Visseaux, M. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.03.015 · Cited by 80 · see citing works

Bimetallic salen aluminum complexes: cooperation between reactive centers in the ring-opening polymerization of lactides and epoxides

Isnard, F., Lamberti, M., Lettieri, L., D'auria, I., Press, K., Troiano, R., & Mazzeo, M. (2016) · Dalton Transactions · doi:10.1039/c6dt02592g · Cited by 72 · see citing works

Salen-type aluminum and zinc complexes as two-faced janus compounds: contribution to molecular sensing and polymerization catalysis

Strianese, M., Pappalardo, D., Mazzeo, M., Lamberti, M., & Pellecchia, C. (2020) · Dalton Transactions · doi:10.1039/d0dt02639e · Cited by 68 · see citing works

Mechanistic Basis for High Reactivity of (salen)Co–OTs in the Hydrolytic Kinetic Resolution of Terminal Epoxides

Nielsen, L. P. C., Zuend, S. J., Ford, D. D., & Jacobsen, E. N. (2012) · The Journal of Organic Chemistry · doi:10.1021/jo300181f · Cited by 62 · see citing works

Mechanism studies of terpolymerization of phthalic anhydride, propylene epoxide, and carbon dioxide catalyzed by ZnGA

Liu, Y., Xiao, M., Wang, S., Xia, L., Hang, D., Cui, G., & Meng, Y. (2014) · RSC Adv. · doi:10.1039/c3ra46343e · Cited by 60 · see citing works

Catalytic conversion of carbon dioxide to carboxylic acid derivatives

Liu, A., Yu, B., & He, L. (2015) · Greenhouse Gases Science and Technology · doi:10.1002/ghg.1461 · Cited by 57 · see citing works

Synthesis, characterization and reactivity of single-site aluminium amides bearing benzotriazole phenoxide ligands: catalysis for ring-opening polymerization of lactide and carbon dioxide/propylene oxide coupling

Li, C.-Y., Liu, D.-C., & Ko, B.-T. (2013) · Dalton Transactions · doi:10.1039/c3dt51003d · Cited by 47 · see citing works

Cs ₂ CO ₃ -promoted polycondensation of CO ₂ with diols and dihalides for the synthesis of miscellaneous polycarbonates

Chen, Z., Hadjichristidis, N., Feng, X., & Gnanou, Y. (2016) · Polymer Chemistry · doi:10.1039/c6py00783j · Cited by 44 · see citing works

Facilely synthesized benzotriazole phenolate zirconium complexes as versatile catalysts for copolymerization of carbon dioxide with cyclohexene oxide and lactide polymerization

Chuang, H.-J., & Ko, B.-T. (2015) · Dalton Transactions · doi:10.1039/c4dt02774d · Cited by 38 · see citing works

Synthesis of Polycarbonates and Poly(ether carbonate)s Directly from Carbon Dioxide and Diols Promoted by a Cs2CO3/CH2Cl2 System

Bian, S., Pagan, C., Andrianova “Artemyeva”, A. A., & Du, G. (2016) · ACS Omega · doi:10.1021/acsomega.6b00278 · Cited by 38 · see citing works

Susquehanna Chorale Spring Concert "Roots and Wings"

Hawkins, D. (2017)

STUDY ON COPOLYMERIZATION OF D_3~F, D_4

Ma, C. (2002)

Copolymerization of N-vinylformamid and N-vinylcaprolactam

Shaoqun, J., & Han-jiang, Y. (2006) · Journal of Tongji University

Anionic copolymerization of α,ω-dihydroxyoligodimethylsiloxane with organocyclosiloxanes

Шрагин, Д. И., Копылов, В. М., Ivanov, P. V., et al. (2008) · Polymer Science Series A · doi:10.1134/s0965545x08010069 · Cited by 2 · see citing works

Anionic Copolymerization of α-Methylstyrene and 2, 3-Dimethylbutadiene

Yuki, H., Okamoto, Y., Takano, H., et al. (1972) · Polymer Journal · doi:10.1295/polymj.3.442 · Cited by 2 · see citing works