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Determination of the Electron Transfer Number for the Oxygen Reduction Reaction: From Theory to Experiment
Abstract
The forced convection methods on the rotating disk and ring-disk electrodes are carefully analyzed toward their use for calculation of the electron transfer number ( n ) for the oxygen reduction reaction (ORR) on various catalysts. It is shown that the widely used Koutechy–Levich (KL) method is not suitable to determine n for the ORR either theoretically or experimentally. From a theoretical viewpoint, the ORR is neither a single-step nor a one-way reaction and, therefore does not fulfill the assumptions of the KL method. From an experimental viewpoint, n is significantly dependent on the angular velocity of the rotating disk electrode, contradicting the assumption of constant n in the KL theory. An improved model is used to establish the aforementioned relationship between n and angular velocity. The recommended way to determine n for the ORR in alkaline electrolytes is to use the rotating ring-disk electrode with a properly biased Au ring, supplemented by the calibration of the collection efficiency.
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Metadata
- Authors
- Zhou, R., Zheng, Y., Jaroniec, M., & Qiao, S.-Z.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-06-21
- Volume
- 6
- Issue
- 7
- Pages
- 4720-4728
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2412704563
- Cited by
- 668
- References
- 36
- FWCI
- 13.94
- Type
- journal article
- Language
- en
- Open access
- closed
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