The DOI matches its Crossref record.
Highly Dispersed Copper over β-Mo2C as an Efficient and Stable Catalyst for the Reverse Water Gas Shift (RWGS) Reaction
Abstract
Cu-oxide catalysts have a tendency to deactivate dramatically in reverse water gas shift (RWGS) reaction, because of the aggregation of supported copper particles at high temperatures. Herein, β-Mo 2 C, which is a typical type of transition-metal carbide, has been demonstrated to be capable of dispersing and stabilizing copper particles. Cu/β-Mo 2 C catalysts exhibit good catalytic activity and stability for the RWGS reaction. Under relatively high weight hourly space velocity (WHSV = 300 000 mL/g/h), the optimized 1 wt % Cu/β-Mo 2 C exhibits superior activity over traditional oxide-supported Pt- and Cu-based catalysts. The activity was well-maintained in a 40 h stability test, and the catalyst shows stable reactivity in a six-cycle start-up cool-down experiment. Detailed structure characterizations demonstrate that the strong interaction between Cu and β-Mo 2 C effectively promotes the dispersion of supported copper and prevents the aggregation of Cu particles, which accounts for the extraordinary activity and stability for the RWGS reaction.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis
Gao, P., Dang, S., Li, S., Bu, X., Liu, Z., Qiu, M., Yang, C., Wang, H., Zhong, L., Han, Y., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b02649 · Cited by 533
Li, S., Xu, Y., Chen, Y., Li, W., Lin, L., Li, M., Deng, Y., Wang, X., Ge, B., Yang, C., et al. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201705002 · Cited by 523
Self-citationSignificant Advances in C1 Catalysis: Highly Efficient Catalysts and Catalytic Reactions
Bao, J., Yang, G., Yoneyama, Y., & Tsubaki, N. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b03924 · Cited by 367
Reinikainen, M., Braunschweiler, A., Korpilo, S., Simell, P., & Alopaeus, V. (2022) · ChemEngineering · doi:10.3390/chemengineering6060096 · Cited by 7
Metadata
- Authors
- Zhang, X., Zhu, X., Lin, L., Yao, S., Zhang, M., Liu, X., Wang, X., Li, Y.-W., Shi, C., & Ma, D.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-12-28
- Volume
- 7
- Issue
- 1
- Pages
- 912-918
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2567550849
- Cited by
- 431
- References
- 0
- FWCI
- 6.58
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Highly Dispersed Copper over β-Mo2C as an Efficient and Stable Catalyst for the Reverse Water Gas Shift (RWGS) Reaction. https://app.cochat.ai/papers/10.1021/acscatal.6b02991
- The paper
- Zhang, X., Zhu, X., Lin, L., Yao, S., Zhang, M., Liu, X., Wang, X., Li, Y.-W., Shi, C., & Ma, D. (2017). Highly Dispersed Copper over β-Mo2C as an Efficient and Stable Catalyst for the Reverse Water Gas Shift (RWGS) Reaction. ACS Catalysis. https://doi.org/10.1021/acscatal.6b02991
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
