The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis
Abstract
Direct conversion of carbon dioxide (CO 2 ) into lower olefins (C 2 = –C 4 = ), generally referring to ethylene, propylene, and butylene, is highly attractive as a sustainable production route for its great significance in greenhouse gas control and fossil fuel substitution, but such a route always tends to be low in selectivity toward olefins. Here we present a bifunctional catalysis process that offers C 2 = –C 4 = selectivity as high as 80% and C 2 –C 4 selectivity around 93% at more than 35% CO 2 conversion. This is achieved by a bifunctional catalyst composed of indium–zirconium composite oxide and SAPO-34 zeolite, which is responsible for CO 2 activation and selective C–C coupling, respectively. We demonstrate that both the precise control of oxygen vacancies on the oxide surface and the integration manner of the components are crucial in the direct production of lower olefins from CO 2 hydrogenation. No obvious deactivation is observed over 150 h, indicating a promising potential for industrial application.
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Cites
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Self-citationOlah, G. A., Goeppert, A., & Prakash, G. K. S. (2009) · The Journal of Organic Chemistry · doi:10.1021/jo801260f · Cited by 1,605
Selective conversion of syngas to light olefins
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Cited by
Industrial carbon dioxide capture and utilization: state of the art and future challenges
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C. Y., Zhu, X., Wang, J., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00025f · Cited by 1,388
Metadata
- Authors
- Gao, P., Dang, S., Li, S., Bu, X., Liu, Z., Qiu, M., Yang, C., Wang, H., Zhong, L., Han, Y., Liu, Q., Wei, W., & Sun, Y.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-12-14
- Volume
- 8
- Issue
- 1
- Pages
- 571-578
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2775247499
- Cited by
- 533
- References
- 39
- FWCI
- 10.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gao, P., Dang, S., Li, S., Bu, X., Liu, Z., Qiu, M., Yang, C., Wang, H., Zhong, L., Han, Y., Liu, Q., Wei, W., & Sun, Y. (2018). Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis. ACS Catalysis. https://doi.org/10.1021/acscatal.7b02649
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