The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Enhanced Catalytic Activity in Nitrogen-Anion Modified Metallic Cobalt Disulfide Porous Nanowire Arrays for Hydrogen Evolution
Abstract
Rational design of cost-effective and non-precious-metal electrocatalysts for the hydrogen evolution reaction (HER) still remains a great challenge for future applications in sustainable energy storage and conversion systems. In this work, we developed a simple nitrogen-anion decoration strategy to realize the synergistic regulation of the catalytically active sites, electronic structure, and reaction dynamics in metallic CoS 2 porous nanowire (NW) arrays. Specifically, the introduction of nitrogen-anion in the CoS 2 system, revealed by the XPS and XANES spectra, not only modified the morphology, offering additional active sites, but also enhanced the electrical conductivity to promote rapid charge transfer for the HER process. Synergistically, density functional theory confirms that the N incorporation results in more optimal free energy of hydrogen adsorption for either S or Co active sites, benefiting the HER kinetics. As expected, the N–CoS 2 NW/carbon cloth (CC) electrode showed significantly enhanced HER performance with a lower overpotential and a larger exchange current density than the pristine one. This work provides a promising idea to the rational design of advanced and highly efficient electrocatalysts for hydrogen production.
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Cites
High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS2) Micro- and Nanostructures
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Plasma-Assisted Synthesis of NiCoP for Efficient Overall Water Splitting
Liang, H., Gandi, A. N., Anjum, D. H., Wang, X., Schwingenschlögl, U., & Alshareef, H. N. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b03803 · Cited by 1,237
Jiao, Y., Zheng, Y., Davey, K., & Qiao, S.-Z. (2016) · Nature Energy · doi:10.1038/nenergy.2016.130 · Cited by 1,196
First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
Kong, D., Cha, J. J., Wang, H., Lee, H. R., & Cui, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42413h · Cited by 1,031
Zou, X., Huang, X., Goswami, A., Silva, R., Sathe, B. R., Mikmeková, E., & Asefa, T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201311111 · Cited by 979
Zhang, J., Qu, L., Shi, G., Liu, J., Chen, J., & Dai, L. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201510495 · Cited by 873
Zhang, Y., Ouyang, B., Xu, J., Jia, G., Chen, S., Rawat, R. S., & Fan, H. J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604372 · Cited by 737
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Al-Doped CoP nanoarray: a durable water-splitting electrocatalyst with superhigh activity
Zhang, R., Tang, C., Kong, R., Du, G., Asiri, A. M., Chen, L., & Sun, X. (2017) · Nanoscale · doi:10.1039/c7nr00740j · Cited by 308
Cited by
Cao, E., Chen, Z., Wu, H., Yu, P., Wang, Y., Xiao, F., Chen, S., Du, S., Xie, Y., Wu, Y., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201915254 · Cited by 337
Self-citationChen, P., Zhang, N., Wang, S., Zhou, T., Tong, Y., Ao, C., Yan, W., Zhang, L., Chu, W., Wu, C., et al. (2019) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1817881116 · Cited by 319
Self-citationOptimized Metal Chalcogenides for Boosting Water Splitting
Yin, J., Jin, J., Lin, H., Yin, Z., Li, J., Lu, M., Guo, L., Xi, P., Tang, Y., & Yan, C. (2020) · Advanced Science · doi:10.1002/advs.201903070 · Cited by 292
Yu, J., Li, Z., Liu, T., Zhao, S., Guan, D., Chen, D., Shao, Z., & Ni, M. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.141674 · Cited by 99
Metadata
- Authors
- Chen, P., Zhou, T., Chen, M., Tong, Y., Zhang, N., Peng, X., Chu, W., Wu, X., Wu, C., & Xie, Y.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-09-29
- Volume
- 7
- Issue
- 11
- Pages
- 7405-7411
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2755250797
- Cited by
- 178
- References
- 9
- FWCI
- 6.69
- Type
- journal article
- Language
- en
- Open access
- closed
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