The DOI matches its Crossref record; 50 of the 50 references it cites were found in a registry or an index.
Site-Selective C–H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope
Open accessAbstract
Abstract The synergistic control of the SH2 transition states of hydrogen abstraction by polar and steric effects provides a promising strategy in achieving site-selective C(sp3)–H functionalization under decatungstate anion photocatalysis. By using this photocatalytic approach, the C–H bonds of alkanes, alcohols, ethers, ketones, amides, esters, nitriles, and pyridylalkanes were functionalized site-selectively. In the remarkable case of a 2,4-disubstituted cyclohexanone bearing five methyl, five methylene, and three methine C–H bonds, one methine C–H bond in the isoamyl tether was selectively functionalized.
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Catalytic Functionalization of C(sp2)H and C(sp3)H Bonds by Using Bidentate Directing Groups
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Metadata
- Authors
- Ravelli, D., Fagnoni, M., Fukuyama, T., Nishikawa, T., & Ryu, I.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-12-22
- Volume
- 8
- Issue
- 1
- Pages
- 701-713
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2771086842
- Cited by
- 533
- References
- 50
- FWCI
- 10.95
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Ravelli, D., Fagnoni, M., Fukuyama, T., Nishikawa, T., & Ryu, I. (2018). Site-Selective C–H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope. ACS Catalysis. https://doi.org/10.1021/acscatal.7b03354
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