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Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices
Abstract
Polyoxometalates represent a diverse range of molecular clusters with an almost unmatched range of physical properties and the ability to form structures that can bridge several length scales. The new building block principles that have been discovered are beginning to allow the design of complex clusters with desired properties and structures and several structural types and novel physical properties are examined. In this critical review the synthetic and design approaches to the many polyoxometalate cluster types are presented encompassing all the sub-types of polyoxometalates including, isopolyoxometalates, heteropolyoxometalates, and reduced molybdenum blue systems. As well as the fundamental structure and bonding aspects, the final section is devoted to discussing these clusters in the context of contemporary and emerging interdisciplinary interests from areas as diverse as anti-viral agents, biological ion transport models, and materials science.
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Cited by
Ravelli, D., Fagnoni, M., Fukuyama, T., Nishikawa, T., & Ryu, I. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b03354 · Cited by 533
Xiao, J., Liu, P., Wang, C. X., & Yang, G. W. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.02.004 · Cited by 352
Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters
Fang, W.-H., Zhang, L., & Zhang, J. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00511c · Cited by 348
Recent Breakthroughs in Deep Aerobic Oxidative Desulfurization of Petroleum Refinery Products
Shafiq, I., Shafique, S., Akhter, P., Ishaq, M., Yang, W., & Hussain, M. (2021) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2020.125731 · Cited by 121
Liu, P., Liang, Y., Lin, X., Wang, C., & Yang, G. (2011) · ACS Nano · doi:10.1021/nn2007282 · Cited by 84
Metadata
- Authors
- Long, D.-L., Burkholder, E., & Cronin, L.
- Venue
- Chem. Soc. Rev.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2007
- Volume
- 36
- Issue
- 1
- Pages
- 105-121
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2336043143
- Cited by
- 2,174
- References
- 0
- FWCI
- 6.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- Long, D.-L., Burkholder, E., & Cronin, L. (2007). Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices. Chem. Soc. Rev. https://doi.org/10.1039/b502666k
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