Modulating Interfacial Charge Density of NiP 2 –FeP 2 via Coupling with Metallic Cu for Accelerating Alkaline Hydrogen Evolution
Abstract
Exploring earth-abundant electrocatalysts with Pt-like performance toward alkaline hydrogen evolution reaction (HER) is extremely desirable for the hydrogen economy but remains challenging. Herein, density functional theory (DFT) predictions reveal that the electronic structure and localized charge density at the heterointerface of NiP 2 –FeP 2 can be significantly modulated upon coupling with metallic Cu, resulting in optimized proton adsorption energy and reduced barrier for water dissociation, synergistically boosting alkaline HER. Motivated by theoretical predictions, we developed a facile strategy to fabricate interface-rich NiP 2 –FeP 2 coupled with Cu nanowires (Cu NW ) grown on Cu foam (NiP 2 –FeP 2 /Cu NW /Cu f ). Benefiting from the superior intrinsic activity, conductivity, and copious active sites, the obtained catalyst exhibited exceptional alkaline HER activity requiring a low overpotential of 23.6 mV at −10 mA/cm 2, surpassing the state-of-the-art Pt. Additionally, a full electrolyzer required a cell voltage of 1.42/1.4 V at 10 mA/cm 2 in alkaline water/seawater with promising stability. This work highlights a design principle for advanced HER catalysts and beyond.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Cites
Sustainable Hydrogen Production
Turner, J. A. (2004) · Science · doi:10.1126/science.1103197 · Cited by 6,602 · see citing works
Electrolysis of low-grade and saline surface water
Tong, W., Forster, M., Dionigi, F., Dresp, S., Sadeghi Erami, R., Strasser, P., Cowan, A. J., & Farràs, P. (2020) · Nature Energy · doi:10.1038/s41560-020-0550-8 · Cited by 1,299 · see citing works
High-performance bifunctional porous non-noble metal phosphide catalyst for overall water splitting
Fang, Y., Zhou, H., Huang, Y., Sun, J., Qin, F., Bao, J., Goddard, W. A., Chen, S., & Ren, Z. (2018) · Nature Communications · doi:10.1038/s41467-018-04746-z · Cited by 1,165 · see citing works
Chen, Z., Cummins, D., Reinecke, B. N., Clark, E., Sunkara, M. K., & Jaramillo, T. F. (2011) · Nano Letters · doi:10.1021/nl2020476 · Cited by 1,153 · see citing works
Overall electrochemical splitting of water at the heterogeneous interface of nickel and iron oxide
Suryanto, B. H. R., Wang, Y., Hocking, R. K., Adamson, W., & Zhao, C. (2019) · Nature Communications · doi:10.1038/s41467-019-13415-8 · Cited by 745 · see citing works
Dinh, C., Jain, A., de Arquer, F. P. G., Luna, P. D., Li, J., Wang, N., Zheng, X. R., Cai, J., Gregory, B. Z., Voznyy, O., et al. (2018) · Nature Energy · doi:10.1038/s41560-018-0296-8 · Cited by 717 · see citing works
Lu, B., Guo, L., Wu, F., Peng, Y., Lu, J. E., Smart, T. J., Wang, N., Finfrock, Y. Z., Morris, D., Zhang, P., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-08419-3 · Cited by 629 · see citing works
Electronic and optical properties of Cu, CuO and Cu 2 O studied by electron spectroscopy
Tahir, D., & Tougaard, S. (2012) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/24/17/175002 · Cited by 524 · see citing works
Cao, Z., Chen, Q., Zhang, J., Li, H., Jiang, Y., Shen, S., Fu, G., Lu, B., Xie, Z., & Zheng, L. (2017) · Nature Communications · doi:10.1038/ncomms15131 · Cited by 439 · see citing works
Mishra, I. K., Zhou, H., Sun, J., Qin, F., Dahal, K., Bao, J., Chen, S., & Ren, Z. (2018) · Energy & Environmental Science · doi:10.1039/c8ee01270a · Cited by 346 · see citing works
Porous NiFe-Oxide Nanocubes as Bifunctional Electrocatalysts for Efficient Water-Splitting
Kumar, A., & Bhattacharyya, S. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b14096 · Cited by 302 · see citing works
Self-citationRole of Oxalic Acid Overexcretion in Transformations of Toxic Metal Minerals by Beauveria caledonica
Fomina, M., Hillier, S., Charnock, J., Melville, K., Alexander, I. J., & Gadd, G. M. (2005) · Applied and Environmental Microbiology · doi:10.1128/aem.71.1.371-381.2005 · Cited by 292 · see citing works
Hsu, S., Miao, J., Zhang, L., Gao, J., Wang, H., Tao, H. B., Hung, S., Vasileff, A., Qiao, S., & Liu, B. (2018) · Advanced Materials · doi:10.1002/adma.201707261 · Cited by 289 · see citing works
Yu, L., Wu, L., Song, S., McElhenny, B. P., Zhang, F., Chen, S., & Ren, Z. (2020) · ACS Energy Letters · doi:10.1021/acsenergylett.0c01244 · Cited by 288 · see citing works
Zhang, H., Zhou, W., Dong, J., Lu, X. F., & Lou, X. W. (2019) · Energy & Environmental Science · doi:10.1039/c9ee02787d · Cited by 284 · see citing works
He, W., Han, L., Hao, Q., Zheng, X., Li, Y., Zhang, J., Liu, C., Liu, H., & Xin, H. L. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b02316 · Cited by 221 · see citing works
Huang, J., Han, J., Wu, T., Feng, K., Yao, T., Wang, X., Liu, S., Zhong, J., Zhang, Z., Zhang, Y., et al. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b02359 · Cited by 220 · see citing works
Jadhav, A. R., Kumar, A., Lee, J., Yang, T., Na, S., Lee, J., Luo, Y., Liu, X., Hwang, Y., Liu, Y., et al. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta08543j · Cited by 210 · see citing works
Self-citationYu, L., Zhang, J., Dang, Y., He, J., Tobin, Z. M., Kerns, P. M., Dou, Y., Jiang, Y., He, Y., & Suib, S. L. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b00494 · Cited by 173 · see citing works
Lee, J., Kumar, A., Yang, T., Liu, X., Jadhav, A. R., Park, G. H., Hwang, Y., Yu, J., Nguyen, C. T. K., Liu, Y., et al. (2020) · Energy & Environmental Science · doi:10.1039/d0ee03183f · Cited by 160 · see citing works
Self-citationOne-Step Synthesis of a Self-Supported Copper Phosphide Nanobush for Overall Water Splitting
Wei, S., Qi, K., Jin, Z., Cao, J., Zheng, W., Chen, H., & Cui, X. (2016) · ACS Omega · doi:10.1021/acsomega.6b00366 · Cited by 144 · see citing works
Wang, P., Qin, R., Ji, P., Pu, Z., Zhu, J., Lin, C., Zhao, Y., Tang, H., Li, W., & Mu, S. C. (2020) · Small · doi:10.1002/smll.202001642 · Cited by 139 · see citing works
Reversible Lithium Uptake by FeP[sub 2]
Silva, D. C. C., Crosnier, O., Ouvrard, G., Greedan, J. E., Sefat, A. S., & Nazar, L. F. (2003) · Electrochemical and Solid-State Letters · doi:10.1149/1.1588112 · Cited by 122 · see citing works
One-step synthesis of copper compounds on copper foil and their supercapacitive performance
Xu, P., Ye, K., Du, M., Liu, J., Cheng, K., Yin, J., Wang, G., & Cao, D. (2015) · RSC Advances · doi:10.1039/c5ra04889c · Cited by 116 · see citing works
Jothi, V. R., Bose, R., Rajan, H., Jung, C., & Yi, S. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201802615 · Cited by 101 · see citing works
Synthesis of FeP 2 /C nanohybrids and their performance for hydrogen evolution reaction
Jiang, J., Wang, C., Zhang, J., Wang, W., Zhou, X., Pan, B., Tang, K., Zuo, J., & Yang, Q. (2014) · Journal of Materials Chemistry A · doi:10.1039/c4ta04758c · Cited by 99 · see citing works
Zhang, C., Xie, Y., Deng, H., Zhang, C., Su, J., Dong, Y., & Lin, J. (2018) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2018.02.157 · Cited by 92 · see citing works
Kumar, A., Chaudhary, D. K., Parvin, S., & Bhattacharyya, S. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta06946h · Cited by 77 · see citing works
Self-citationParvin, S., Kumar, A., Ghosh, A., & Bhattacharyya, S. (2020) · Chemical Science · doi:10.1039/d0sc00754d · Cited by 71 · see citing works
Self-citationBui, V. Q., Kumar, A., Bui, H. T., Lee, J., Hwang, Y., Le, H. M., Kawazoe, Y., & Lee, H. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.0c03052 · Cited by 51 · see citing works
Self-citationSabhapathy, P., Liao, C.-C., Chen, W., Chou, T., Shown, I., Sabbah, A., Lin, Y., Lee, J., Tsai, M., Chen, K.-H., et al. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta10935d · Cited by 50 · see citing works
Self-citationCao, Q., Wang, C., Chen, S., Xu, X., Liu, F., Geng, X., & Wang, J. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.01.172 · Cited by 44 · see citing works
Debnath, B., Kumar, A., Salunke, H. G., & Bhattacharyya, S. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b09157 · Cited by 30 · see citing works
Self-citationWang, X., Pi, M., Zhang, D., Li, H., Feng, J., Chen, S., & Li, J. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b22114 · Cited by 21 · see citing works
Ortho-Tolidine and Sodium Hypochlorite for the Determination of Carrageenan and Other Ester Sulfates
Graham, H. D. (1972) · Journal of Dairy Science · doi:10.3168/jds.s0022-0302(72)85744-8 · Cited by 14 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Yang, S., Zhu, J., Chen, X., Huang, M., Cai, S.-H., Han, J.-Y., & Li, J.-S. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120914 · Cited by 280 · see citing works
Moving beyond bimetallic-alloy to single-atom dimer atomic-interface for all-pH hydrogen evolution
Kumar, A., Bui, V. Q., Lee, J., Wang, L., Jadhav, A. R., Liu, X., Shao, X., Liu, Y., Yu, J., Hwang, Y., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-27145-3 · Cited by 272 · see citing works
Self-citationComputational chemistry for water-splitting electrocatalysis
Miao, L., Jia, W., Cao, X., & Jiao, L. (2024) · Chemical Society Reviews · doi:10.1039/d2cs01068b · Cited by 241 · see citing works
Qian, G., Chen, J., Yu, T., Liu, J., Luo, L., & Yin, S. (2021) · Nano-Micro Letters · doi:10.1007/s40820-021-00744-x · Cited by 230 · see citing works
Metal nitrides for seawater electrolysis
Hu, H., Wang, X., Attfield, J. P., & Yang, M. (2023) · Chemical Society Reviews · doi:10.1039/d3cs00717k · Cited by 230 · see citing works
Xu, W., Fan, G., Zhu, S., Liang, Y., Cui, Z., Li, Z., Jiang, H., Wu, S., & Cheng, F. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202107333 · Cited by 218 · see citing works
Electrocatalytic seawater splitting: Nice designs, advanced strategies, challenges and perspectives
Liang, J., Li, Z., He, X. J., Luo, Y., Zheng, D., Wang, Y., Li, T., Ying, B., Sun, S., Cai, Z., et al. (2023) · Materials Today · doi:10.1016/j.mattod.2023.08.024 · Cited by 211 · see citing works
Liu, X., Xi, S., Kim, H., Kumar, A., Lee, J., Wang, J., Tran, N. Q., Yang, T., Shao, X., Liang, M., et al. (2021) · Nature Communications · doi:10.1038/s41467-021-26025-0 · Cited by 206 · see citing works
Self-citationWen, S., Huang, J., Li, T., Chen, W., Chen, G., Zhang, Q., Zhang, X., Qian, Q., & Ostrikov, K. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.121678 · Cited by 187 · see citing works
Sun, H., Li, L., Chen, Y., Kim, H., Xu, X., Guan, D., Hu, Z., Zhang, L., Shao, Z., & Jung, W. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.122388 · Cited by 178 · see citing works
Kumar, A., Liu, X., Lee, J., Debnath, B., Jadhav, A. R., Shao, X., Bui, V. Q., Hwang, Y., Liu, Y., Kim, M. G., et al. (2021) · Energy & Environmental Science · doi:10.1039/d1ee02603h · Cited by 172 · see citing works
Self-citationLiu, D., Cai, Y., Wang, X., Zhuo, Y., Sui, X., Pan, H., & Wang, Z. (2024) · Energy & Environmental Science · doi:10.1039/d4ee01693a · Cited by 170 · see citing works
Metal Electrocatalysts for Hydrogen Production in Water Splitting
Kazemi, A., Manteghi, F., & Tehrani, Z. (2024) · ACS Omega · doi:10.1021/acsomega.3c07911 · Cited by 167 · see citing works
Efficient and durable seawater electrolysis with a V 2 O 3 -protected catalyst
Hu, H., Zhang, Z., Liu, L., Che, X., Wang, J., Zhu, Y., Attfield, J. P., & Yang, M. (2024) · Science Advances · doi:10.1126/sciadv.adn7012 · Cited by 161 · see citing works
Liu, S., Yan, W., Wang, M., & Shen, Y. F. (2024) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2024.216190 · Cited by 143 · see citing works
Yu, Q., Liu, X., Liu, G., Wang, X., Li, Z., Li, B., Wu, Z., & Wang, L. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202205767 · Cited by 139 · see citing works
Jeong, S., Kim, U., Lee, S.-J., Zhang, Y., Son, E., Choi, K. J., Han, Y., Baik, J. M., & Park, H. (2024) · ACS Nano · doi:10.1021/acsnano.3c12533 · Cited by 134 · see citing works
Mao, Q., Xu, M., Wang, W., Deng, K., Yu, H., Wang, Z., Xu, Y. P., Wang, L., & Wang, H. (2023) · Nature Communications · doi:10.1038/s41467-023-41423-2 · Cited by 127 · see citing works
Li, R., Li, Y., Yang, P., Ren, P., Wang, D., Lu, X., Xu, R., Li, Y., Xue, J., Zhang, J., et al. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.121834 · Cited by 120 · see citing works
Recent advances in noble metal-free electrocatalysts to achieve efficient alkaline water splitting
Jamesh, M.-I., Hu, D., Wang, J., Naz, F., Feng, J., Yu, L., Cai, Z., Colmenares, J. C., Lee, D., Chu, P. K.-H., et al. (2024) · Journal of Materials Chemistry A · doi:10.1039/d3ta07418h · Cited by 120 · see citing works
Strategies on improving the electrocatalytic hydrogen evolution performances of metal phosphides
Yu, W., Gao, Y., Chen, Z., Zhao, Y., Wu, Z., & Wang, L. (2021) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(21)63855-x · Cited by 118 · see citing works
Lu, Y., Huang, K., Cao, X., Zhang, L., Wang, T., Peng, D., Zhang, B., Liu, Z., Wu, J., Zhang, Y., et al. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202110645 · Cited by 117 · see citing works
Ding, X., Yu, J., Huang, W., Chen, D., Lin, W., & Xie, Z. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.138550 · Cited by 112 · see citing works
Liu, S., Ma, L., & Li, J.-S. (2022) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2022.10.165 · Cited by 111 · see citing works
Xiao, Z., Yang, M., Wang, J., Xu, Z., Zhang, S., Tang, A., Gao, R., & Yang, H. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120913 · Cited by 110 · see citing works
Hao, J., Wu, K., Lyu, C., Yang, Y., Wu, H., Liu, J., Liu, N., Lau, W., & Zheng, J. (2023) · Materials Horizons · doi:10.1039/d3mh00366c · Cited by 108 · see citing works
Kumar, A., Gil‐Sepulcre, M., Lee, J., Bui, V. Q., Wang, Y., Rüdiger, O., Kim, M. G., DeBeer, S., & Tüysüz, H. (2024) · Advanced Materials · doi:10.1002/adma.202401648 · Cited by 108 · see citing works
Self-citationPeng, Y., Zhang, Y., Guo, A., Mao, M., Wang, Y., Long, Y., & Fan, G. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.133648 · Cited by 106 · see citing works
Electrocatalytic seawater splitting for hydrogen production: Recent progress and future prospects
Feng, C., Chen, M., Yang, Z., Xie, Z., Li, X., Li, S., Abudula, A., & Guan, G. (2023) · Journal of Material Science and Technology · doi:10.1016/j.jmst.2023.03.058 · Cited by 105 · see citing works
Liu, Y., Liu, X., Wang, X., Ning, H., Yang, T., Yu, J., Kumar, A., Luo, Y., Wang, H., Wang, L., et al. (2021) · ACS Nano · doi:10.1021/acsnano.1c05324 · Cited by 104 · see citing works
Self-citationSingle-Metal-Atom Dopants Increase the Lewis Acidity of Metal Oxides and Promote Nitrogen Fixation
Lee, J., Kumar, A., Kim, M. G., Yang, T., Shao, X., Liu, X., Liu, Y., Hong, Y., Jadhav, A. R., Liang, M., et al. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c02136 · Cited by 104 · see citing works
Self-citationKumar, A., Gil‐Sepulcre, M., Fandré, J. P., Rüdiger, O., Kim, M. G., DeBeer, S., & Tüysüz, H. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.4c08847 · Cited by 104 · see citing works
Self-citationChang, K., Tran, D. T., Wang, J., Prabhakaran, S., Kim, D. H., Kim, N. H., & Lee, J. H. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202113224 · Cited by 101 · see citing works
Self-citationXie, J., Wang, F., Zhou, Y., Dong, Y., Chai, Y., & Dong, B. (2023) · Nano-Micro Letters · doi:10.1007/s40820-023-01253-9 · Cited by 99 · see citing works
Kumar, A., Lee, J., Kim, M. G., Debnath, B., Liu, X., Hwang, Y., Wang, Y., Shao, X., Jadhav, A. R., Liu, Y., et al. (2022) · ACS Nano · doi:10.1021/acsnano.2c06747 · Cited by 95 · see citing works
Self-citationLi, W., Wang, D., Liu, T., Li, T., Zhang, Y., Huang, Y., Du, S., Dong, C., Kong, Z., Li, Y., et al. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202109244 · Cited by 94 · see citing works
Br-induced P-poor defective nickel phosphide for highly efficient overall water splitting
Xu, T., Jiao, D., Zhang, L., Zhang, H., Zheng, L., Singh, D. J., Zhao, J., Zheng, W., & Cui, X. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.121686 · Cited by 93 · see citing works
Zhang, H., Geng, S., Ouyang, M., Yadegari, H., Xie, F., & Riley, D. J. (2022) · Advanced Science · doi:10.1002/advs.202200146 · Cited by 92 · see citing works
Sun, H., Liu, J., Chen, G., Kim, H., Kim, S., Hu, Z., Chen, J., Haw, S., Francesco Ciucci, A., & Jung, W. (2021) · Small Methods · doi:10.1002/smtd.202101017 · Cited by 90 · see citing works
Hemmati, K., Kumar, A., Jadhav, A. R., Moradlou, O., Moshfegh, A. Z., & Lee, H. (2023) · ACS Catalysis · doi:10.1021/acscatal.3c00510 · Cited by 90 · see citing works
Self-citationCai, S.-H., Chen, X., Huang, M., Han, J.-Y., Zhou, Y., & Li, J.-S. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta08385f · Cited by 87 · see citing works
Zhao, T., Wang, S., Li, Y., Jia, C., Su, Z. B., Hao, D., Ni, B., Zhang, Q., & Zhao, C. (2022) · Small · doi:10.1002/smll.202204758 · Cited by 82 · see citing works
Zhao, T., Wang, S., Jia, C., Rong, C., Su, Z. B., Dastafkan, K., Zhang, Q., & Zhao, C. (2023) · Small · doi:10.1002/smll.202208076 · Cited by 82 · see citing works
Ren, J., Chen, L., Wang, H., Tian, W.-W., Zhai, S., Feng, Y., & Yuan, Z. (2024) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2024.123817 · Cited by 81 · see citing works
Silambarasan, P., Pokhrel, I., Muhammad, U. S. K., Shao, X., Han, Y., Kim, M.-S., & Lee, H. (2024) · ACS Materials Letters · doi:10.1021/acsmaterialslett.4c00587 · Cited by 81 · see citing works
Self-citationLewis acid etched NixCo1-xSe2 derived from ZIF-L on CoO nanowires for hybrid-supercapacitors
Sun, L., Liu, Y., Yan, M., Yang, Q., Liu, X., & Shi, W. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.133472 · Cited by 76 · see citing works
Fe2O3/NiO Interface for the Electrochemical Oxygen Evolution in Seawater and Domestic Sewage
Li, L., Zhang, G., Wang, B., Zhu, D., Liu, D., Liu, Y., & Yang, S. (2021) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.1c09274 · Cited by 72 · see citing works
Cui, Y., Xu, Z., Chen, D., Li, T., Yang, H., Mu, X. Q., Gu, X., Zhou, H., Liu, S. L., & Mu, S. C. (2021) · Nano Energy · doi:10.1016/j.nanoen.2021.106579 · Cited by 72 · see citing works
Review of the Hydrogen Evolution Reaction—A Basic Approach
Ferriday, T. B., Middleton, P. H., & Kolhe, M. L. (2021) · Energies · doi:10.3390/en14248535 · Cited by 72 · see citing works
In-situ surface structural reconstruction of NiMoO4 for efficient overall water splitting
Xiao, Z., Wang, J., Liu, C., Wang, B., Zhang, Q., Xu, Z., Sarwar, M. T., Tang, A., & Yang, H. (2022) · Applied Surface Science · doi:10.1016/j.apsusc.2022.154314 · Cited by 72 · see citing works
Gao, X., Zhang, Y., Yin, S., Mao, Y., Gui, J., Li, J., Zhao, Y., Sun, C., & Guo, S. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202204833 · Cited by 71 · see citing works
Chandrasekaran, S., Li, N., Yang, Z., Sui, L., Xiao, Z., Fan, D., Aravindan, V., Bowen, C., Lu, H., & Liu, Y. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.134073 · Cited by 68 · see citing works
Lu, T., Li, T., Shi, D., Sun, J., Pang, H., Xu, L., Yang, J., & Tang, Y. (2021) · SmartMat · doi:10.1002/smm2.1063 · Cited by 66 · see citing works
Xiao, Z., Qian, Y., Tan, T., Lu, H., Liu, C., Wang, B., Zhang, Q., Sarwar, M. T., Gao, R., Tang, A., et al. (2022) · Journal of Materials Chemistry A · doi:10.1039/d2ta07152e · Cited by 66 · see citing works
Sun, H., Kim, H., Song, S., & Jung, W. (2022) · Materials Reports Energy · doi:10.1016/j.matre.2022.100092 · Cited by 64 · see citing works
Li, J.-S., Huang, M., Zhou, Y., Chen, X., Yang, S., Zhu, J., Liu, G., Ma, L., Cai, S.-H., & Han, J.-Y. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta01868j · Cited by 63 · see citing works
Sun, Z., Sun, L., Koh, S. W., Ge, J., Fei, J., Yao, M., Hong, W. L., Liu, S., Yamauchi, Y., & Li, H. (2022) · Carbon Energy · doi:10.1002/cey2.213 · Cited by 63 · see citing works
Wen, N., Zhang, D., Zhao, X., Jiao, X., Xia, Y., & Chen, D. (2023) · ACS Catalysis · doi:10.1021/acscatal.3c01101 · Cited by 62 · see citing works
Dual interface-reinforced built-in electric field for chlorine-free seawater oxidation
Zhang, S., Wang, Y., Wei, X., Chu, L., Tian, W., Wang, H., & Huang, M. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.122926 · Cited by 60 · see citing works
Coordination structure engineering of Cu-based electrocatalysts for electrocatalytic water splitting
Luo, C., Liu, X., Yang, K., Xu, J., Zhu, Z., Tang, Z., Shen, S., Fan, J., Luo, D., Alshammari, N. A. H., et al. (2024) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2024.215936 · Cited by 59 · see citing works
Ni Center Coordination Reconstructed Nanocorals for Efficient Water Splitting
Xu, T., Jiao, D., Liu, M., Zhang, L., Fan, X., Zheng, L., Zheng, W., & Cui, X. (2022) · Advanced Science · doi:10.1002/advs.202205605 · Cited by 57 · see citing works
Aziz, S. T., Haque, M. A., Saha, S., Mondal, B., Jain, S., & Dutta, A. (2023) · Energy & Fuels · doi:10.1021/acs.energyfuels.3c02773 · Cited by 57 · see citing works
Amorphization of Metal Nanoparticles by 2D Twisted Polymer for Super Hydrogen Evolution Reaction
Shao, X., Liang, M., Kumar, A., Liu, X., Jin, H., Ajmal, S., Bui, V. Q., Bui, H. T., Lee, J., Tran, N. Q., et al. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202102257 · Cited by 56 · see citing works
Self-citationZhang, K., Wang, F., Li, X., Wang, S., Wang, Y., Zha, Q., & Ni, Y. (2023) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2023.169014 · Cited by 52 · see citing works
Ma, F., Wang, S., Han, L., Guo, Y., Wang, Z., Wang, P., Liu, Y., Cheng, H., Dai, Y., Zheng, Z., et al. (2021) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.1c16048 · Cited by 49 · see citing works
Jiang, L., Pan, Y., Zhang, J., Chen, X., Ye, X., Li, Z., Li, C., & Sun, Q. (2022) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2022.04.050 · Cited by 49 · see citing works
Zhao, P., Peng, C., Luo, Y., Cheng, L., Li, Z., & Jiao, Z. (2024) · Chemical Engineering Journal · doi:10.1016/j.cej.2024.149121 · Cited by 48 · see citing works
Quan, Q., Zhang, Y., Wang, F., Bu, X., Wang, W., Meng, Y., Xie, P., Chen, D., Wang, W., Li, D., et al. (2022) · Nano Energy · doi:10.1016/j.nanoen.2022.107566 · Cited by 47 · see citing works
Mo, Y., Ni, Y., Li, X., Pan, R., Tang, Y., Deng, Y., Xiao, B., Tan, Y.-L., & Fang, Y. (2023) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2023.04.240 · Cited by 46 · see citing works
Artificial modulated Lewis pairs for highly efficient alkaline hydrogen production
Xiao, Z., Yang, M., Liu, C., Wang, B., Zhang, S., Liu, J., Xu, Z., Gao, R., Zou, J., Tang, A., et al. (2022) · Nano Energy · doi:10.1016/j.nanoen.2022.107233 · Cited by 46 · see citing works
Jiang, Y., Yu, J., Song, H., Du, L., Sun, W., Cui, Y., Su, Y., Sun, M., Yin, G., & Lu, S. (2024) · Carbon Energy · doi:10.1002/cey2.631 · Cited by 44 · see citing works
Ampere-Level CO2-to-Ethanol Conversion via Boron-Incorporated Copper Electrodes
Wu, G., Zhu, C., Mao, J., Li, G., Li, S., Dong, X., Chen, A., Song, Y., Feng, G., Liu, X., et al. (2023) · ACS Energy Letters · doi:10.1021/acsenergylett.3c01901 · Cited by 43 · see citing works
Recent Advances in the Construction of 2D Heterostructures for Electrocatalytic Water Splitting
Quan, Q., & Ho, J. C. Y. (2022) · Advanced Energy and Sustainability Research · doi:10.1002/aesr.202200059 · Cited by 42 · see citing works
Sun, J., Li, J., Li, Z., Li, C., Ren, G., Zhang, Z., & Meng, X. (2022) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.2c02571 · Cited by 42 · see citing works
Deng, M., Li, M., Jiang, S., Nie, Y., Li, L., & Wei, Z. (2022) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.1c03808 · Cited by 42 · see citing works
Hydrogen evolution electrodes: Materials and mechanisms in alkaline electrolysis
Shi, Y., Xiao, S., Jiao, S., Wang, Y., Jiang, F., Wang, R., Zhang, Y., Liu, J., Qiao, J., Hu, Z., et al. (2024) · Desalination · doi:10.1016/j.desal.2024.117887 · Cited by 41 · see citing works
Lee, J., Liu, X., Kumar, A., Hwang, Y., Lee, E. J., Yu, J., Kim, Y. D., & Lee, H. (2021) · Chemical Science · doi:10.1039/d1sc03223b · Cited by 41 · see citing works
Self-citationFeng, W., Bu, M., Kan, S., Gao, X., Guo, A., Liu, H., Deng, L., & Chen, W. (2021) · Applied Materials Today · doi:10.1016/j.apmt.2021.101175 · Cited by 41 · see citing works
Zhao, B., Xu, C., Shakouri, M., Feng, R., Zhang, Y., Liu, J., Wang, L., Zhang, J. J., Luo, J., & Fu, X. (2022) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2022.121082 · Cited by 41 · see citing works
Zhang, S., Wei, X., Dai, S., Wang, H., & Huang, M. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202311370 · Cited by 39 · see citing works
Nanoscale hetero-interfaces for electrocatalytic and photocatalytic water splitting
Yang, B., Luo, D., Wu, S., Zhang, N., & Ye, J. (2022) · Science and Technology of Advanced Materials · doi:10.1080/14686996.2022.2125827 · Cited by 38 · see citing works
Kirubasankar, B., Kwon, J., Hong, S., Won, Y. S., Choi, S. H., Lee, J., Kim, J. W., Kim, K. K., & Kim, S. M. (2024) · Nano Energy · doi:10.1016/j.nanoen.2024.109805 · Cited by 38 · see citing works
Self-citationRen, K., Xu, W., Li, K., Cao, J., Gu, Z., Liu, D., Dai, D., Li, W., & Wu, X. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202415585 · Cited by 38 · see citing works
Xu, W., Wu, K., Wu, Y., Guo, Q., Fan, F., Li, A., Yang, L., Zheng, F., Fan, Y., & Chen, W. (2022) · Electrochimica Acta · doi:10.1016/j.electacta.2022.141712 · Cited by 37 · see citing works
Yang, J. X., Cao, Y., Zhang, S., Shi, Q., Chen, S., Zhu, S., Li, Y., & Huang, J. (2023) · Small · doi:10.1002/smll.202207295 · Cited by 37 · see citing works
Guo, P., Zhang, P., Cao, S., Huang, W., Lü, X., Zhang, B., Chen, W., Zhang, Y., Wang, Y., Zou, R., et al. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202415375 · Cited by 37 · see citing works
Self-supported electrocatalysts for high-current-density water/seawater electrolysis
Zhao, Y., Sun, Q., Zhang, C. J., Liu, F., Wang, L., & Xu, G. (2023) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2023.172286 · Cited by 36 · see citing works
Li, L., Liu, Y., Jiang, X., Ke, L., Zhao, K., Yan, X., Wang, X., Yang, Y., & Yan, N. (2024) · Nano Energy · doi:10.1016/j.nanoen.2024.110139 · Cited by 37 · see citing works
Design Strategies for Large Current Density Hydrogen Evolution Reaction
Zhang, L., Shi, Z., Lin, Y., Chong, F., & Qi, Y. (2022) · Frontiers in Chemistry · doi:10.3389/fchem.2022.866415 · Cited by 35 · see citing works
Sun, Z., Chu, B., Wang, S., Dong, L., Pang, Q., Fan, M., Zhang, X.-R., He, H., Li, B., & Chen, Z. (2023) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2023.05.006 · Cited by 34 · see citing works
Lu, S., Wang, L., Wu, C., Zhang, J., Dou, W., Hu, T., Wang, R., Liu, Y., Yang, Q., Yi, H., et al. (2024) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.4c00479 · Cited by 34 · see citing works
Behera, S., Ganguly, S., Loha, C., Mondal, B., & Ghosh, S. (2023) · Energy & Fuels · doi:10.1021/acs.energyfuels.3c00732 · Cited by 34 · see citing works
Tailored Ni(OH)2/CuCo/Ni(OH)2 Composite Interfaces for Efficient and Durable Urea Oxidation Reaction
Parvin, S., Aransiola, E. S., Ammar, M. M., Lee, S., Zhang, L., Weber, J., & Baltrušaitis, J. (2024) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.4c14041 · Cited by 33 · see citing works
Zhang, M., Chen, W.-Z., Liu, Z., He, J., & Wang, Y. (2023) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2023.01.238 · Cited by 33 · see citing works
Wang, Z., Yuan, S., Zang, T., Li, T., Zhou, Y., Liu, J., Liu, T., Wang, K., & Wang, Q. (2022) · Journal of Material Science and Technology · doi:10.1016/j.jmst.2022.09.030 · Cited by 32 · see citing works
Navigating Alkaline Hydrogen Evolution Reaction Descriptors for Electrocatalyst Design
Ogunkunle, S. A., Mortier, F., Bouzid, A., Hinsch, J. J., Zhang, L., Wu, Z., Bernard, S., Zhu, Y., & Wang, Y. (2024) · Catalysts · doi:10.3390/catal14090608 · Cited by 32 · see citing works
Electronic Structure Engineering of Transition-Metal-based Electrocatalysts for Water Splitting
Sun, M., & Zhang, N. (2024) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.4c04551 · Cited by 32 · see citing works
Liu, Y., Wang, L., Chen, L., Wang, H., Jadhav, A. R., Yang, T., Wang, Y., Zhang, J., Kumar, A., Lee, J., et al. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202209555 · Cited by 32 · see citing works
Self-citationA review of electrochemical glucose sensing based on transition metal phosphides
Lakshmy, S., Santhosh, S., Kalarikkal, N., Rout, C. S., & Chakraborty, B. (2023) · Journal of Applied Physics · doi:10.1063/5.0111591 · Cited by 32 · see citing works
Self‐Supported Ru‐Incorporated NiSe2 for Ampere‐Level Current Density Hydrogen Evolution
Bai, Y., Zhang, H., Lu, X. F., Wang, L., Zou, Y., Miao, J., Qiao, M., Tang, Y., & Zhu, D. (2023) · Chemistry - A European Journal · doi:10.1002/chem.202300205 · Cited by 32 · see citing works
- Authors
- Kumar, A., Bui, V. Q., Lee, J., Jadhav, A. R., Hwang, Y., Kim, M. G., Kawazoe, Y., & Lee, H.
- Affiliations
- Institute for Basic Science (KR)
- Pohang University of Science and Technology (KR)
- Tohoku University (JP)
- Corresponding author
- Lee, Hyoyoung
- ORCID
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2021-01-04
- Volume
- 6
- Issue
- 2
- Pages
- 354-363
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W3120184380
- Cited by
- 238
- References
- 35
- Citations by year
- 2026: 21 · 2025: 26 · 2024: 53 · 2023: 48 · 2022: 58 · 2021: 32
- FWCI
- 8.96
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- ACS Energy Letters (publishedVersion)
- Funders
- Institute for Basic Science (IBS-R011-D1)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Keywords
- alkaline hydrogen evolution reaction, copper nanowires, heterointerface, interface charge density, water dissociation barrier, earth-abundant electrocatalysts, copper foam, seawater electrolysis
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review