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Unilamellar Metallic MoS2/Graphene Superlattice for Efficient Sodium Storage and Hydrogen Evolution

Xiong, Pan, Ma, Renzhi, Sakai, Nobuyuki, Nurdiwijayanto, Leanddas, Sasaki, Takayoshi·2018·ACS Energy Letters

Abstract

Unilamellar metallic nanosheets possess superiority for electrochemical energy storage and conversion applications compared to the few-layered bulk and semiconducting counterparts. Here, we report the utilization of unilamellar metallic 1T phase MoS 2 nanosheets for efficient sodium storage and hydrogen evolution through a MoS 2 /graphene superlattice. The superlattice-like assembly composed of alternately restacked unilamellar MoS 2 and modified reduced graphene oxide nanosheets was prepared by a facile solution-phase direct restacking method. As an anode for sodium storage, the MoS 2 /graphene superlattice anode exhibited an excellent rate capability of ∼240 mA h g –1 at 51.2 A g –1 and a stable reversible capacity of ∼380 mA h g –1 after 1000 cycles at 10 A g –1 . In addition, a low onset potential of ∼88 mV and a small Tafel slope of 48.7 mV decade –1 were attained for the hydrogen evolution reaction. Our findings are important for further developing the potential of 2D nanosheets for energy storage and conversion.

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Metadata

Authors
Xiong, P., Ma, R., Sakai, N., Nurdiwijayanto, L., & Sasaki, T.
Venue
ACS Energy Letters
Published
2018-03-20
Volume
3
Issue
4
Pages
997-1005
ISSN
2380-8195 (ISSN-L)
OpenAlex
W2790273472
Cited by
222
References
5
FWCI
12.51
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Unilamellar Metallic MoS2/Graphene Superlattice for Efficient Sodium Storage and Hydrogen Evolution. https://app.cochat.ai/papers/10.1021/acsenergylett.8b00110
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Xiong, P., Ma, R., Sakai, N., Nurdiwijayanto, L., & Sasaki, T. (2018). Unilamellar Metallic MoS2/Graphene Superlattice for Efficient Sodium Storage and Hydrogen Evolution. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b00110

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