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Rational Electrode–Electrolyte Design for Efficient Ammonia Electrosynthesis under Ambient Conditions
Open accessAbstract
Abstract Renewable energy-driven ammonia electrosynthesis by N2 reduction reaction (NRR) at ambient conditions is vital for sustainability of both the global population and energy demand. However, NRR under ambient conditions to date has been plagued with a low yield rate and selectivity (<10%) due to the more favorable hydrogen evolution reaction (HER) in aqueous media. Herein, surface area enhanced α-Fe nanorods grown on carbon fiber paper were used as NRR cathodes in an aprotic fluorinated solvent–ionic liquid mixture. Through this design, significantly enhanced NRR activity with an NH3 yield rate of ∼2.35 × 10–11 mol s–1 cmGSA–2, (3.71 × 10–13 mol s–1 cmECSA–2) and selectivity of ∼32% has been achieved under ambient conditions. This study reveals that the use of hydrophobic fluorinated aprotic electrolyte effectively limits the availability of protons and thus suppresses the competing HER. Therefore, electrode–electrolyte engineering is essential in advancing the NH3 electrosynthesis technology.
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Cites
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Montoya, J. H., Tsai, C., Vojvodic, A., & Nørskov, J. K. (2015) · ChemSusChem · doi:10.1002/cssc.201500322 · Cited by 1,384
Cited by
A roadmap to the ammonia economy
MacFarlane, D. R., Cherepanov, P. V., Choi, J., Suryanto, B. H. R., Hodgetts, R. Y., Bakker, J. M., Ferrero Vallana, F. M., & Simonov, A. N. (2020) · Joule · doi:10.1016/j.joule.2020.04.004 · Cited by 1,926
Self-citationGuo, X., Gu, J., Lin, S., Zhang, S., Chen, Z., & Huang, S. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b13349 · Cited by 1,151
Electrocatalytic Reduction of Nitrogen: From Haber-Bosch to Ammonia Artificial Leaf
Martín, A. J., Shinagawa, T., & Pérez-Ramírez, J. (2019) · Chem · doi:10.1016/j.chempr.2018.10.010 · Cited by 608
Defect engineering in earth-abundant electrocatalysts for CO2 and N2 reduction
Wang, Q., Lei, Y., Wang, D., & Li, Y. (2019) · Energy & Environmental Science · doi:10.1039/c8ee03781g · Cited by 574
Self-citationRen, Y., Yu, C., Tan, X., Huang, H., Wei, Q., & Qiu, J. (2021) · Energy & Environmental Science · doi:10.1039/d0ee03596c · Cited by 565
Metadata
- Authors
- Suryanto, B. H. R., Kang, C. S. M., Wang, D., Xiao, C., Zhou, F., Azofra, L. M., Cavallo, L., Zhang, X., & MacFarlane, D. R.
- Venue
- ACS Energy Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-04-25
- Volume
- 3
- Issue
- 6
- Pages
- 1219-1224
- ISSN
- 2380-8195 (ISSN-L)
- OpenAlex
- W2800270918
- Cited by
- 248
- References
- 2
- FWCI
- 7.59
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Suryanto, B. H. R., Kang, C. S. M., Wang, D., Xiao, C., Zhou, F., Azofra, L. M., Cavallo, L., Zhang, X., & MacFarlane, D. R. (2018). Rational Electrode–Electrolyte Design for Efficient Ammonia Electrosynthesis under Ambient Conditions. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b00487
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