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Solvent Engineering Improves Efficiency of Lead-Free Tin-Based Hybrid Perovskite Solar Cells beyond 9%

Liu, Xinghua, Yan, Kang, Tan, Dawei, Liang, Xiao, Zhang, Hongmei, Huang, Wei·2018·ACS Energy Letters

Abstract

Here, we report on the effect of different antisolvent dripping on film morphology and charge recombination of mixed formamidinium–methylammonium tin iodide (FA 0.75 MA 0.25 SnI 3 ) as a light absorber in perovskite solar cells. N, N -dimethyl methanamide (DMF) and dimethyl sulfoxide (DMSO) were used as the mixed solvent in the perovskite precursors together with tin fluoride (SnF 2 ) as an additive. Diethyl ether (DE), toluene (TL), and chlorobenzene (CB) were employed as antisolvents for comparison. Our results show that CB as an antisolvent leads to a dense and uniform Sn-based perovskite film. The maximum power conversion efficiency of our Sn-based perovskite solar cell achieves 9.06% (9.02%) under forward (reverse) voltage scan under AM 1.5G 100 mW/cm 2 illumination. The encapsulated cells show good long-term stability with ∼75% of their initial efficiency retained over a period of 30 days of storage. Our work suggests the promising potential to further improve the performance of Pb-free Sn-based perovskite solar cells.

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Metadata

Authors
Liu, X., Yan, K., Tan, D., Liang, X., Zhang, H., & Huang, W.
Venue
ACS Energy Letters
Published
2018-10-09
Volume
3
Issue
11
Pages
2701-2707
ISSN
2380-8195 (ISSN-L)
OpenAlex
W2897191727
Cited by
238
References
1
FWCI
11.10
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Solvent Engineering Improves Efficiency of Lead-Free Tin-Based Hybrid Perovskite Solar Cells beyond 9%. https://app.cochat.ai/papers/10.1021/acsenergylett.8b01588
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Liu, X., Yan, K., Tan, D., Liang, X., Zhang, H., & Huang, W. (2018). Solvent Engineering Improves Efficiency of Lead-Free Tin-Based Hybrid Perovskite Solar Cells beyond 9%. ACS Energy Letters. https://doi.org/10.1021/acsenergylett.8b01588

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